8,21-didodecyl-5,24:12,17-diimino-7,10:19,22-dinitrilo-8H,21H-dibenzo{f,p}{1,2,4,9,11,12,14,19}octaazacycloeicosinate(2-)-N(25),N(26),N(27),N(28) Ni(II) | 155708-35-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 8,21-didodecyl-5,24:12,17-diimino-7,10:19,22-dinitrilo-8H,21H-dibenzo{f,p}{1,2,4,9,11,12,14,19}octaazacycloeicosinate(2-)-N(25),N(26),N(27),N(28) Ni(II)
• CAS: 155708-35-3
• 化学式: C₄₄H₅₈N₁₂Ni
• 分子量: 813.715
• InChiKey: NVVLSJGYUPMUAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  nickel diacetate 、 4,18-Didodecyl-2,4,5,7,16,18,19,21,29,30,31,32-dodecazaheptacyclo[20.6.1.13,6.18,15.117,20.09,14.023,28]dotriaconta-1,3(32),6,8(31),9,11,13,15,17(30),20,22(29),23,25,27-tetradecaene 、 8,17-didodecyl-8,17-dihydrodibenzo-5,7,8,10,15,17,18,20-octa-azaporphyrin 以 cellosolve=2-ethoxyethanol 为溶剂， 生成 8,20-didodecyl-5,24:12,17-diimino-7,10:19,22-dinitrilo-8H,20H-dibenzo{f,p}{1,2,4,9,11,12,14,19}octaazacycloeicosinate(2-)-N(25),N(26),N(27),N(28) Ni(II) 、 8,21-didodecyl-5,24:12,17-diimino-7,10:19,22-dinitrilo-8H,21H-dibenzo{f,p}{1,2,4,9,11,12,14,19}octaazacycloeicosinate(2-)-N(25),N(26),N(27),N(28) Ni(II)
  参考文献：
  名称：

  Third-Order Nonlinear Optical Properties of Soluble Metallotriazolylhemiporphyrazines

  摘要：

  Soluble lipophilic-substituted metallotriazolohemiporphyrazines (MThp), structurally related to metallophthalocyanines, have been synthesized for the first time. The real part of their third-order molecular hyperpolarizabilities gamma has been determined by third-harmonic generation in chloroform solutions. Two fundamental wavelengths (lambda = 1340 and 1904 nm) have been used to investigate the dispersive behavior of gamma. Values between 10(-34) and 10(-33) esu have been found, depending on excitation wavelength and metal substitution. In fact, unfilled d-shell transition ions markedly enhance the molecular hyperpolarizability, the highest values being measured for the Fe2+- and Co2+-substituted molecules.

  DOI：

  10.1021/j100068a003

文献信息

• Novel tribenzhexaazaporphyrins as unsymmetric phthalocyanine analogues
  作者：Fernando Fernández-Lázaro、Angela Sastre、Tomas Torres

  DOI：10.1039/c39940001525

  日期：——

  The formal substitution of one isonindole subunit of a phthalocyanine by a 1,2,4-triazole moiety afforded a new family of unsymmetric azaporphyrins—of which compounds 1 and 2 are representative—with potential nonlinear optical properties.

  将酞菁中的一个异喹啉子单元正式替换为1,2,4-三唑基团，得到了一种新的不对称氮杂卟啉家族——其中化合物1和2为代表——具有潜在的非线性光学性质。