4-[[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]diazenyl]aniline | 150956-61-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4-[[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]diazenyl]aniline
• CAS: 150956-61-9
• 化学式: C₂₀H₁₀F₁₇N₃
• 分子量: 615.292
• InChiKey: DVEDFTIFXROTIJ-UHFFFAOYSA-N

物化性质

• 沸点：
  413.6±45.0 °C(predicted)
• 密度：
  1.55±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9.15
• 重原子数：
  40.0
• 可旋转键数：
  9.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  50.74
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  N,N-二乙基苯胺 、 4-[[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]diazenyl]aniline 在 盐酸 、 sodium nitrite 作用下， 以 水 为溶剂， 生成 N,N-diethyl-4-[[4-[[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]diazenyl]phenyl]diazenyl]aniline
  参考文献：
  名称：

  Functionality of fluorine-containing dyes

  摘要：

  The introduction of a perfluoroalkyl moiety into dye molecules changes the properties of the compounds. The 4-perfluoroalkyl disazo dyes were more soluble in hexane and showed a better dichroism than the alkyl analogs. A novel methacrylate copolymer with a pendant naphthylene disazo dye containing a perfluorobutylsulfonyl group showed a slow relaxation behavior after corona poling. 7-Diethylamino-4-methyl-3-(perfluoroalkyl)coumarins were more stable than the non-perfluoroalkylated derivatives to UV irradiation. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-1139(98)00323-6
• 作为产物：
  描述：

  1-硝基-4-亚硝基苯 在 sodium sulfide 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 生成 4-[[4-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)phenyl]diazenyl]aniline
  参考文献：
  名称：

  Functionality of fluorine-containing dyes

  摘要：

  The introduction of a perfluoroalkyl moiety into dye molecules changes the properties of the compounds. The 4-perfluoroalkyl disazo dyes were more soluble in hexane and showed a better dichroism than the alkyl analogs. A novel methacrylate copolymer with a pendant naphthylene disazo dye containing a perfluorobutylsulfonyl group showed a slow relaxation behavior after corona poling. 7-Diethylamino-4-methyl-3-(perfluoroalkyl)coumarins were more stable than the non-perfluoroalkylated derivatives to UV irradiation. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-1139(98)00323-6