Ni((2-(1-(pyridin-2-yl)ethylimino)methyl)phenolate)(N3) | 1264267-30-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: Ni((2-(1-(pyridin-2-yl)ethylimino)methyl)phenolate)(N3)
• CAS: 1264267-30-2
• 化学式: C₁₄H₁₃N₅NiO
• 分子量: 325.98
• InChiKey: PFRGWXCREGHVKW-CNSDMJOKSA-M

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 2-((1-(2-pyridyl)ethylimino)methyl)phenol 、 sodium azide 在 Et₃N 作用下， 以 甲醇 为溶剂， 以78%的产率得到Ni((2-(1-(pyridin-2-yl)ethylimino)methyl)phenolate)(N3)
  参考文献：
  名称：

  Molecular structures of nickel(II) monochelates of a racemic tridentate ligand and co-ligand induced structural variations

  摘要：

  Using a racemic mixture of the tridentate ligand, (((2-pyridyl)ethylamine)methyl)phenolate ion (L ) and N-3(-), NCS , (NC)(2)N , OAc as coligands, complexes having the formula [Ni(L)(N-3)](1), [Ni(L)(NCS)](2) (2), [Ni-2(L)(2)(OAc)(N(CN)(2))](n) (3)were prepared and structurally characterized. In 1, Ni(II) has a square planar geometry and phenolate oxygen is involved in dipolar O-P(delta-)center dot center dot center dot N delta+ interaction with electrophilic central nitrogen atom of coordinated azide ion. Complex 2 is dimeric in nature and nickel(II)is penta-coordinated. Compounds 1 and 2 exist as centrosymmetric dimers made up of a pair of R and S enantiomers of L. In 3, an acetate and phenoxo bridged dinickel complex is present which is further linked to a zig-zag coordination polymer by the dicyanamide ion. In a given chain of 3, both L have same enantiomeric form and either RR or SS dimers are repeated along the chain. The magnetic properties are described. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.09.007