| 1005758-66-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1005758-66-6
• 化学式: C₂₈H₂₆O₆*C₄₈H₄₈N₃₂O₁₆
• 分子量: 1787.62
• InChiKey: MQDYVQPOVXUIQR-KPUQLQGFSA-N

反应信息

• 作为反应物：
  描述：

  以 水 为溶剂， 反应 0.25h， 生成
  参考文献：
  名称：

  Highly Efficient Cucurbit[8]uril-Templated Intramolecular Photocycloaddition of 2-Naphthalene-Labeled Poly(ethylene glycol) in Aqueous Solution

  摘要：

  [GRAPHICS]The photodimerization of water-insoluble 2-naphthalene-labeled poly(ethyl glycol) (N-P-n-N) in cucurbit[8]uril (CB[8]) aqueous solution was investigated. UV-vis, fluorescence, and H-1 NMR analysis reveal that CB[8] can encapsulate N-P-n-N to make a stable 1:1 inclusion complex N-P-n-N@CB[8] in aqueous solution. Irradiation of N-P-n-N in the CB[8] aqueous solution results in intramolecular photocycloaddition with remarkable selectivity and efficiency, whereas no photodimer could be detected in host-free solution.

  DOI：

  10.1021/jo701998e