1,2-dichloro-1,2-bis(diethylamino)dimethyldisilane | 186352-66-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-dichloro-1,2-bis(diethylamino)dimethyldisilane
• 英文别名: 1,2-Dichloro-1,2-bis-(diethylamino)di-methyldisilane；N-[chloro-[chloro-(diethylamino)-methylsilyl]-methylsilyl]-N-ethylethanamine
• CAS: 186352-66-9
• 化学式: C₁₀H₂₆Cl₂N₂Si₂
• 分子量: 301.407
• InChiKey: ZWUUVMOTJXGMEK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.37
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-dichloro-1,2-bis(diethylamino)dimethyldisilane 、 烯丙基溴化镁 以 乙醚 为溶剂， 反应 12.0h， 以61%的产率得到
  参考文献：
  名称：

  New olefinic functionalized disilanes. Synthesis and NMR spectroscopical investigations

  摘要：

  The new olefinic substituted aminodisilanes, which are obtained from the reaction of organometallic reagents with aminochlorodisilanes, are converted into the chlorodisilanes by equilibration reactions or treatment with HCl. The resulting olefinic functionalized disilanes are identified by means of Si-29, C-13, H-1 NMR and GC MS measurements. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00109-5
• 作为产物：
  描述：

  1,2-二甲基-1,1,2,2-四氯二硅烷 、 二乙胺 以 正己烷 为溶剂， 反应 25.0h， 生成 1,1,2-trichloro-diethylaminodimethyldisilane 、 1,2-dichloro-1,2-bis(diethylamino)dimethyldisilane 、 1-chloro-1,2,2-tris-(diethylamino)dimethyldisilane
  参考文献：
  名称：

  NMR spectroscopic investigation of the Reaction between Tetrachlorodimethyldisilane and Diethylamine for the synthesis of chloro- and amino-functionalized methyldisilanes

  摘要：

  DOI：

  10.1002/prac.19973390114

文献信息

• New olefinic functionalized disilanes. Synthesis and NMR spectroscopical investigations
  作者：K. Trommer、U. Herzog、G. Roewer

  DOI：10.1016/s0022-328x(97)00109-5

  日期：1997.8

  The new olefinic substituted aminodisilanes, which are obtained from the reaction of organometallic reagents with aminochlorodisilanes, are converted into the chlorodisilanes by equilibration reactions or treatment with HCl. The resulting olefinic functionalized disilanes are identified by means of Si-29, C-13, H-1 NMR and GC MS measurements. (C) 1997 Elsevier Science S.A.
• NMR spectroscopic investigation of the Reaction between Tetrachlorodimethyldisilane and Diethylamine for the synthesis of chloro- and amino-functionalized methyldisilanes
  作者：K. Trommer、G. Roewer、E. Brendler

  DOI：10.1002/prac.19973390114

  日期：——