bis(benzil)ethylenediamine | 104729-82-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: bis(benzil)ethylenediamine
• 英文别名: bis(benzyl)ethylenediamine；2-[2-[(2-oxo-1,2-diphenylethylidene)amino]ethylimino]-1,2-diphenylethanone
• CAS: 104729-82-0
• 化学式: C₃₀H₂₄N₂O₂
• 分子量: 444.533
• InChiKey: UKRDMUVIUYLUDR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.73
• 重原子数：
  34.0
• 可旋转键数：
  9.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  58.86
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  cobalt(II) chloride hexahydrate 、 bis(benzil)ethylenediamine 、 四亚甲基二胺 以 甲醇 为溶剂， 以22%的产率得到
  参考文献：
  名称：

  Radhakrishna Reddy; Mohana Raju; Hussain Reddy, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1996, vol. 35, # 8, p. 677 - 680

  摘要：

  DOI：

文献信息

• SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF BIVALENT LEAD MACROCYCLIC COMPLEXES
  作者：Anil Bansal、Sudhir Kumar、R. V. Singh

  DOI：10.1081/sim-100105263

  日期：2001.6.30

  Lead(II) macrocyclic complexes of some 12- and 13-membered tetraazamacrocycles have been synthesized by the template process using bis(benzil)ethylenediamine as precursor. The change in ring size has been achieved solely by varying the number of methylene carbon that link adjacent benzil nitrogen atoms. Bis(benzil)ethylenediamine (L) reacts with PbCl2 or Pb(OAc)(2) and primary diamines, i.e., 1,2-diaminoethane (1,2-en) or 1,3-diaminopropane (1,3-pn) in a 1: 1: 1 molar ratio in methanol to give several solid complexes of the general composition [Pb(L)X-2] (L = macrocyclic ligand, X = Cl or OAc). The precursor and the metal complexes of the macrocycles have been characterized by elemental analyses, molecular weight determinations, molar conductances, IR, H-1 NMR, C-13 NMR, electronic and mass spectral studies. On the basis of the IR and NMR spectral data the involvement of amido nitrogen in coordination to the central metal ion has been confirmed. An octahedral geometry around the metal ion is suggested for the complexes. Based on molecular weights and conductivity measurements, their monomeric and non-electrolytic nature has been confirmed.