[Cd(benzilic acid-H)2(1,10-phenanthroline)2] | 936740-70-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 英文名称: [Cd(benzilic acid-H)2(1,10-phenanthroline)2]
• 英文别名: [Cd(DBA)2(1,10-phen)2]
• CAS: 936740-70-4
• 化学式: C₅₂H₃₈CdN₄O₆
• 分子量: 927.307
• InChiKey: OPTMNTCLFSUTKJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 二苯基羟基乙酸 、 aqueous cadmium chloride 在 NaOH 作用下， 以 乙醇 、 水 为溶剂， 以52%的产率得到[Cd(benzilic acid-H)2(1,10-phenanthroline)2]
  参考文献：
  名称：

  Synthesis, characterization and 1D helical chain crystal structure of [Cu(DBA)2(1,10-phen)]n and [Cd(DBA)2(1,10-phen)2] (DBA=benzilic acid)

  摘要：

  Two novel complexes [Cu(DBA)(2)(1,10-phen)](n) (1) and [Cd(DBA)(2)(1,10-phen)(2)] (2) [HDBA = benzilic acid: (C6H5)(2)C(OH)COOH] have been synthesized and characterized by element analysis and fluorescence spectroscopy. The crystal structures of compounds 1, 2 and HDBA (3) were also determined. Complex I is a one-dimensional (ID) helical infinite chain, in which [(1,10)-phen]Cu-(II) units were bridged by benzilic acid. Complex 2 is a mononuclear structure, and is self-assembled through pi-pi stacking interactions to form a ID helical chain. Compound 3 is self-assembled to form a ID helical chain through hydrogen bonds interactions. Thermal analyses indicate that complexes 1 and 2 are stable under 200 and 254 degrees C in solid state, respectively. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.09.027