2-氰基-3-[4-[4-(2,2-二苯乙烯基)苯基]-1,2,3,3a,4,8b-六氢环戊[b]吲哚-7-基]丙烯酸 | 652145-29-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 中文名称: 2-氰基-3-[4-[4-(2,2-二苯乙烯基)苯基]-1,2,3,3a,4,8b-六氢环戊[b]吲哚-7-基]丙烯酸
• 英文名称: 2-Cyano-3-(4-(4-(2,2-diphenylvinyl)phenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indol-7-yl)acrylic acid
• 英文别名: (E)-2-cyano-3-[4-[4-(2,2-diphenylethenyl)phenyl]-2,3,3a,8b-tetrahydro-1H-cyclopenta[b]indol-7-yl]prop-2-enoic acid
• CAS: 652145-29-4
• 化学式: C₃₅H₂₈N₂O₂
• 分子量: 508.6
• InChiKey: GOTRYMLNXIJMCB-VFCFBJKWSA-N

物化性质

• 沸点：
  690.6±55.0 °C(Predicted)
• 密度：
  1.262±0.06 g/cm3(Predicted)
• 最大波长(λmax)：
  464nm(CHCl3)(lit.)

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  39
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  64.3
• 氢给体数：
  1
• 氢受体数：
  4

文献信息

• [EN] METHINE DYES WITH LARGE ORGANIC COUNTER ANION FOR DYE SENSITIZED SOLAR CELLS<br/>[FR] COLORANTS À BASE DE MÉTHINE COMPRENANT UN CONTRE-ANION ORGANIQUE DE GRANDE TAILLE POUR CELLULES SOLAIRES À PIGMENT PHOTOSENSIBLE
  申请人：BASF SE

  公开号：WO2015011638A1

  公开（公告）日：2015-01-29

  The present invention relates to an electrode layer comprising a porous film made of oxide semiconductor fine particles sensitized with a methine dye having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm. Moreover the present invention relates to a photoelectric conversion device comprising said electrode layer, a dye sensitized solar cell comprising said photoelectric conversion device, an organic electronic device comprising said photoelectric conversion device and to novel methine dyes having a counter anion capable of absorbing electromagnetic radiation having a wavelength in the range of from 400 nm to 1000 nm.

  本发明涉及一种电极层，该电极层包括由氧化物半导体细颗粒制成的多孔薄膜，该薄膜被一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的反离子敏化的偏亚甲基染料。此外，本发明涉及一种包括所述电极层的光电转换装置，一种包括所述光电转换装置的染料敏化太阳能电池，一种包括所述光电转换装置的有机电子器件，以及一种具有能够吸收波长在400纳米至1000纳米范围内电磁辐射的新型偏亚甲基染料。
• Organic dye, photoelectric transducing material, semiconductor electrode, and photoelectric transducing device
  申请人：Mitsubishi Paper Mills Limited

  公开号：EP1997855A2

  公开（公告）日：2008-12-03

  Disclosed are an organic dye having a specific structure, a photoelectric conversion material containing the dye, a semiconductor electrode formed of a substrate having an electrically conductive surface, a semiconductor layer coated on the electrically conductive surface and the above dye adsorbed on the surface, and a photoelectric conversion device to which the above dye is applied. The present invention uses the above dye and can therefore provide a photoelectric conversion device excellent in photoelectric conversion efficiency, and the photoelectric conversion device is suitable for use in a solar cell or the like.

  本发明公开了一种具有特定结构的有机染料，一种含有该染料的光电转换材料，一种由具有导电表面的基板、涂覆在导电表面上的半导体层和吸附在该表面上的上述染料构成的半导体电极，以及一种应用了上述染料的光电转换装置。 本发明使用了上述染料，因此可以提供一种光电转换效率极佳的光电转换装置，该光电转换装置适用于太阳能电池等。
• DYE FOR DYE-SENSITIZED SOLAR CELL, SEMICONDUCTOR ELECTRODE, AND DYE-SENSITIZED SOLAR CELL
  申请人：Mitsubishi Paper Mills Limited

  公开号：EP2309584A1

  公开（公告）日：2011-04-13

  The dye for a dye-sensitized solar cell, which dye is a compound classified into melocyanine dyes and has a structure in which an electron donor unit and an electron acceptor unit are connected with conjugated double bonds, provided by this invention, has excellent photoelectric conversion efficiency and excellent durability, and according to this invention, there can be provided a semiconductor electrode sensitized by the dye and a dye-sensitized solar cell using the semiconductor electrode.

  本发明提供的用于染料敏化太阳能电池的染料是一种化合物，属于三聚氰胺染料，具有电子供体单元和电子受体单元用共轭双键连接的结构，具有优异的光电转换效率和出色的耐久性，根据本发明，可以提供由该染料敏化的半导体电极和使用该半导体电极的染料敏化太阳能电池。
• PIGMENT SENSITIZATION SOLAR CELL
  申请人：Toppan Printing Co., Ltd.

  公开号：EP2738864A1

  公开（公告）日：2014-06-04

  A dye-sensitized solar cell includes, a semiconductor layer holding a photosensitizing dye, an electrolyte layer and a pair of electrodes, wherein the photosensitizing dye includes a dye A having a carboxyl group or a phosphono group as a fixing group with the semiconductor layer, and a dye B having a nitrogen-containing aromatic heterocyclic compound as a fixing group with the semiconductor layer.

  一种染料敏化太阳能电池包括：容纳光敏染料的半导体层、电解质层和一对电极，其中光敏染料包括以羧基或膦基为固定基团与半导体层固定的染料A，以及以含氮芳香杂环化合物为固定基团与半导体层固定的染料B。
• PHOTOELECTRIC CONVERSION ELEMENT
  申请人：Sharp Kabushiki Kaisha

  公开号：EP2933874A1

  公开（公告）日：2015-10-21

  In a photoelectric conversion element (10), a conductive layer (2), a photoelectric conversion layer (3), and a counter electrode (8) are disposed, and at least the photoelectric conversion layer (3) is filled with an electrolyte. In the photoelectric conversion layer (3), at least one of a dye formed of a compound having one thiocyanate group and a dye formed of a compound not having a thiocyanate group is adsorbed onto a porous semiconductor layer formed of a semiconductor material. The electrolyte includes at least one of pyrazole and a pyrazole derivative.

  在光电转换元件 (10) 中，设置了导电层 (2)、光电转换层 (3) 和对电极 (8)，并且至少在光电转换层 (3) 中填充了电解质。在光电转换层（3）中，由具有一个硫氰酸基的化合物形成的染料和由不具有硫氰酸基的化合物形成的染料中的至少一种被吸附在由半导体材料形成的多孔半导体层上。电解质包括吡唑和吡唑衍生物中的至少一种。