1,4,7,10,13,16-hexaoxacyclooctadecyl[2,3:11,12]bis-dipyrido[3,2-a:2',3'-c]phenazine | 1156463-76-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 1,4,7,10,13,16-hexaoxacyclooctadecyl[2,3:11,12]bis-dipyrido[3,2-a:2',3'-c]phenazine
• 英文别名: 2,5,8,31,34,37-Hexaoxa-12,18,21,27,41,47,50,56-octazaundecacyclo[36.20.0.09,30.011,28.013,26.014,19.020,25.040,57.042,55.043,48.049,54]octapentaconta-1(38),9(30),10,12,14(19),15,17,20(25),21,23,26,28,39,41,43(48),44,46,49(54),50,52,55,57-docosaene
• CAS: 1156463-76-1
• 化学式: C₄₄H₃₂N₈O₆
• 分子量: 768.788
• InChiKey: SEODROMQIDVVBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  58
• 可旋转键数：
  0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  159
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 1,4,7,10,13,16-hexaoxacyclooctadecyl[2,3:11,12]bis-dipyrido[3,2-a:2',3'-c]phenazine 、 hexafluorophosphate anion 以 乙二醇 为溶剂， 以80%的产率得到[(1,4,7,10,13,16-hexaoxacyclooctadecyl[2,3:11,12]bis-dipyrido[3,2-a:2',3'-c]phenazine)bis(bis(2,2'-bipydine)ruthenium(II))] hexafluorophosphate
  参考文献：
  名称：

  Synthesis, photophysical, and electrochemical properties of three novel Ru(II) polypyridyl complexes containing dibenzo-18-crown-6

  摘要：

  Three polypyridyl bridging ligands cis-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6 (BL(1)), trans-di(4,5-diazafluoren-9-ylimino)dibenzo-18-crown-6 (BL(2)), and 1,4,7,10,13,16-hexaoxacycloctadecyl[2,3:11,12]bis-dipyrido[3,2-a:2'3'-c]phenazine (BL(3)), and corresponding dinuclear Ru(II) complexes [(bpy)(2)-RuBL(1-3) Ru(bpy)(2)](PF(6))(4) (1, 2, and 3) have been synthesized. Cyclic voltammetry of the complexes are consistent with one Ru(II)-centered oxidation and three ligand-centered reductions. Photophysical behaviors are investigated by UV-Vis absorption and fluorescence spectrometry. The three complexes show metal-to-ligand charge transfer absorption at 445-453 nm and emission at 571-593 nm. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2008.03.011