bis(trimethyl-l5-phosphaneyl)aluminum(V) chloride | 21640-13-1

• 分子结构分类: 有机化合物 - 乙炔化物
• 英文名称: bis(trimethyl-l5-phosphaneyl)aluminum(V) chloride
• CAS: 21640-13-1
• 化学式: C₆H₁₈AlCl₃P₂
• 分子量: 285.497
• InChiKey: BYUZHBZXYNZLLA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  12.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  aluminum (III) chloride 、 三甲基膦 以 二氯甲烷 为溶剂， 反应 1.5h， 以67%的产率得到bis(trimethyl-l5-phosphaneyl)aluminum(V) chloride
  参考文献：
  名称：

  （（iii）卤化物的膦配合物–制备以及结构和光谱学系统†

  摘要：

  六坐标拟八面体反式-[AlX 2（L–L）2 ] [AlX 4 ]（X = Cl，Br或I； L–L = o -C 6 H 4（PMe 2）2，Me 2 P（CH 2）2 PMe 2）是由AlX 3与二膦在CH 2 Cl 2（X = Cl）或甲苯（X = Br或I）溶液中反应制得的。四坐标二聚体[Cl 3 Al（μ-L'–L'）AlCl 3 ]（L'–L'= Me 2 P（CH 2）2 PMe如图2所示，还获得了Cy 2 P（CH 2） 2 PCy 2）和四面体阳离子[AlCl 2 { o -C 6 H 4（PPh 2） 2 }] [AlCl 4 ]。取决于所用试剂的比例，可以用PMe 3分离四配位配合物和五配位配合物[AlX 3（PMe 3）]和[AlX 3（PMe 3） 2 ]。这些对水分极为敏感的络合物已通过微分析，IR和多核NMR（ 1 H，31 P { 1 H}和27 Al）光谱。报告了[AlCl

  DOI：

  10.1039/c4dt02051k

文献信息

• A solid-state NMR study of aluminum Lewis acid adducts with trimethylphosphine in zeolite Y: magic angle spinning sideband analysis of dipolar and J-coupled multiplet system
  作者：Po Jen Chu、A. De Mallmann、Jack H. Lunsford

  DOI：10.1021/j100172a047

  日期：1991.9

  The adsorption of trimethylphosphine (TMP) on a mixture consisting of a H-Y zeolite and aluminum chloride results in AlCl3-P(CH3)3 coordination complexes which exists as a family of structures with different stoichiometries. These complexes have been characterized by Al-27 and P-31 solid-state NMR. Two significant phases are formed with AlCl3:(CH3)3P ratios of 1:1 and 1:2. In the 1:1 adduct the aluminum is tetrahedrally coordinated and is directly bonded to phosphorus. The 1:2 adduct involves P-Al-P type bonding as suggested by the P-31 NMR sideband line shape and multiplet structure. Here aluminum is likely to be fivefold coordinated with trigonal-bipyramidal geometry (D3h). The two trimethylphosphine molecules are believed to be trans axial. From an analysis of the sample spinning sidebands multiplet, the Al-P distances were found to be 2.58 +/- 0.02 angstrom for the 1:1 complex and 2.96 +/- 0.02 angstrom for the 1:2 complex. These values are in good agreement with values obtained from crystal structure studies of the individual phases. From a comparison of samples with different TMP loadings, it is concluded that an equilibrium can be established between these two major phases in the presence of a H-Y zeolite, in a manner similar to that which occurs in the solution phase or in the solid state.