A process for preparing a dialkylester of a naphthalenedicarboxylic acid comprising directing a liquid phase reaction mixture comprising a low molecular weight alcohol, a naphthalenedicarboxylic acid, a dialkylester of a naphthalenedicarboxylic acid, and a polyethylene naphthalate containing material, at a given temperature and pressure through series arranged reaction zones and subsequently removing a product comprising a dialkylester formed by the reaction of the naphthalenedicarboxylic acid and the polyethylene naphthalate containing material with the low molecular weight alcohol from a reaction zone. This invention is also directed to a process for preparing a purified dialkylester of a naphthalenedicarboxylic acid comprising a series of crystallization and distillation steps, and combinations thereof.
一种制备
萘二
羧酸二酯的方法,包括将低分子量醇、
萘二
羧酸、
萘二
羧酸二酯和聚
乙烯萘含物的液相反应混合物,在一定的温度和压力下通过系列排列的反应区域,并从反应区中去除由
萘二
羧酸和聚
乙烯萘含物与低分子量醇反应形成的
萘二
羧酸二酯产物。本发明还涉及一种制备纯化的
萘二
羧酸二酯的方法,包括一系列结晶和蒸馏步骤,以及其组合。