COPOLYMER FORMED BY RING-OPENING POLYMERIZATION, PRODUCT OF HYDROGENATION OF COPOLYMER FORMED BY RING-OPENING POLYMERIZATION, AND PROCESSES FOR PRODUCING THESE
申请人:Zeon Corporation
公开号:EP1275675A1
公开(公告)日:2003-01-15
A ring-opened metathesis copolymer formed by the ring-opening metathesis copolymerization of a cycloolefin monomer having a carboxylic anhydride group selected from bicycloheptene derivatives, tetracyclododecene derivatives and hexacycloheptadecene derivatives with a cycloolefin monomer selected from bicycloheptene derivatives, tetracycloheptene derivatives and hexacycloheptene derivatives; and a hydrogenation product of the copolymer. This copolymer is produced by using a polymerization catalyst comprises an organoruthenium compound having a heterocyclic carbene compound as a ligand. The ring-opened metathesis copolymer and the hydrogenation product thereof have a low dielectric constant, a low water absorption, a high adhesion to metals and a high heat resistance.
由具有选自双环庚烯衍生物、四环十二烯衍生物和六环十七烯衍生物的羧酸酐基团的环烯烃单体与选自双环庚烯衍生物、四环庚烯衍生物和六环庚烯衍生物的环烯烃单体开环共聚形成的开环共聚物;以及该共聚物的氢化产物。这种共聚物是通过使用一种聚合催化剂生产的,该催化剂包括一种以杂环碳烯化合物为配体的有机钌化合物。开环偏聚共聚物及其氢化产物具有低介电常数、低吸水性、高金属粘附性和高耐热性。