Synthesis and 31P NMR spectra of some diene complexes of iron(O) and ruthenium(O) containing phosphine ligands
作者:Abdul-Razzak Al-Ohaly、John F. Nixon
DOI:10.1016/s0022-328x(00)92678-0
日期:1980.12
The preparation of the η4-butadiene complexes of zerovalent iron and ruthenium Ru(η4-C4H6)(PPh3)(L)2, (L P(OCH2)3CMe, P(OMe)3, PF2NMe2, PF3); Fe(η4-C4H6)(CO)(L)2, (L P(OMe)3, P(OCH2)3CMe), and the cyclohexadiene complexes Ru(η4-C6H8)L3 (L P(OMe)3, P(OCH2)3CMe and PF3,) is described and some variable temperature 31P NMR studies are reported.
的η的制备4 -丁二烯络合物零价铁和钌的Ru(η的4 -C 4 H ^ 6)(PPH 3)(L)2,(LP(OCH 2)3 CME,P(OME)3, PF 2 NMe 2,PF 3);的Fe(η 4 -C 4 H ^ 6)(CO)(L)2,(LP(OME)3,P(OCH 2)3 CME),和环己二烯配合物的Ru(η 4 -C 6 H ^ 8)大号3描述了(LP(OMe)3,P(OCH 2)3 CMe和PF 3,),并报道了一些可变温度31 P NMR研究。