The characterization of alkali arsenites and antimonites: The IR spectra of matrix-isolated MAsO2 and MSbO2 molecules
作者:L. Bencivenni、K.A. Gingerich
DOI:10.1016/0022-2860(83)90156-4
日期:1983.5
Abstract IR matrix-isolation experiments indicate the existence of gaseous alkali arsenites and antimonites. These molecules have been studied and characterized in detail by 18 O enrichment measurements. For these species, a C 2v ring structure with OAsO and OSbO angles of 115° ± 5 and 106° ± 5, respectively, has been proposed.
摘要 IR 基质分离实验表明存在气态碱金属亚砷酸盐和锑矿。这些分子已通过 18 O 富集测量进行了详细研究和表征。对于这些物种,已经提出了具有 OAsO 和 OSbO 角分别为 115°±5 和 106°±5 的 C 2v 环结构。