2-methyl-amino-8-hydroxynaphtalene-3,6-disulfonic acid | 110929-06-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-methyl-amino-8-hydroxynaphtalene-3,6-disulfonic acid
• 英文别名: 2-N-methylamino-8-hydroxynaphthalene-3,6-disulfonic acid；2-methyl-amino-8-hydroxynaphthalene-3,6-disulfonic acid；5-Hydroxy-3-(methylamino)naphthalene-2,7-disulfonic acid
• CAS: 110929-06-1
• 化学式: C₁₁H₁₁NO₇S₂
• 分子量: 333.343
• InChiKey: JYANZFITQJUSJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  158
• 氢给体数：
  4
• 氢受体数：
  8

文献信息

• Fiber-reactive monoazo compound having 7-substituted amino-1-naphthol-sulfonic acid as coupling component
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0241104A1

  公开（公告）日：1987-10-14

  A monoazo compound of the following formula in a free acid form, wherein R,, R2 and R4 are independently hydrogen or lower alkyl, R3 is lower alkyl, acyl or (sulfo)phenyl, Rs is hydrogen or sulfo, B is (sulfo)phenylene or sulfonaphthylmethylene, X is chlorine, fluorine, phenoxy or (substituted)amino, A is (substituted)phenylene or (substituted)naphthylene, and Z is -SO2CH = CH2 or -SO2CH2CH2Y in which Y is a splittable group by the action of an alkali, which meets requirements of high degree in a dye industry with respect to dyeing properties such as build-up property and fastness properties such as formalin fastness, formalin-light fastness and the like.

  一种游离酸形式的下式单偶氮化合物，其中 R、R2 和 R4 独立地为氢或低级烷基，R3 为低级烷基、酰基或（磺）苯基，Rs 为氢或磺基，B 为（磺）亚苯基或磺萘基亚甲基，X 为氯、氟、苯氧基或（取代）氨基，A 为（取代）亚苯基或（取代）亚萘基，Z 为-SO2CH = CH2 或-SO2 Y，其中 Y 为在碱作用下可拆分的基团，该化合物在染色性能（如上色性能）和牢度性能（如福尔马林牢度、福尔马林-耐光牢度等）方面满足染料工业的高要求。
• Water-soluble monoazodyes containing a ureido group and two sulfonyl fiber-reactive groups, process for their preparation and their use
  申请人：HOECHST CELANESE CORPORATION

  公开号：EP0265857A1

  公开（公告）日：1988-05-04

  Water-soluble monoazo dyes of the general formula X - SO₂ - A - N = N - W - - CO - NH - Z - SO₂ - Y       (1) wherein: X and Y are independently selected from vinyl, β-thiosulfatoethyl, β-bromoethyl, β-acetyloxyethyl, β-hydroxyethyl, β-phosphatoethyl, β-methylsulfonyloxyethyl, β-phenoxyethyl, β-sulfatoethyl, β-chlorethyl, β-phenylsulfonyloxy-ethyl and a group of the formula -CH₂-CH₂-NR¹R², in which R¹ and R² are independently selected from hydrogen, lower alkyl and sulfo-substituted lower alkyl; R is hydrogen, lower alkyl or sulfo-substituted lower alkyl; A is a phenylene or naphthylene radical optionally substituted with hydroxy, halogen, lower alkyl, lower alkoxy, carboxy or sulfo; W is a phenylene or naphthylene radical optionally substituted with carboxy, sulfo, amino, carbamoyl unsubstituted or substituted, sulfamoyl unsubstituted or substituted, lower alkyl, lower alkoxy, hydroxy or halogen; Z is a phenylene radical optionally substituted with halogen, lower alkoxy or lower alkyl; and the copper, chromium, cobalt and nickel metallized complex-dyes of said metal-free dyestuffs. These novel dyes yield on cellulose textiles dyeings with high tinctorial strength and purity of shade and with good light and wash fastnesses, particularly a good chlorine wash fastness. They are particularly useful in high temperature dyeing operations and can be prepared into stable aqueous solutions for use in continous dyeing operations. They provide a full range of shades and exhibit superior color yield and leveling in chemical pad steaming dyeing. They build strongly with superior fixation and have superior stability in acidic and alkaline environments.

  通式为 X - SO₂ - A - N = N - W - - CO - NH - Z - SO₂ - Y 的水溶性单偶氮染料 (1) 其中 X 和 Y 分别独立地选自乙烯基、β-硫代磺酸基乙基、β-溴乙基、β-乙酰氧基乙基、β-羟基乙基、β-膦酰氧基乙基、β-甲基磺酰氧基乙基、β-苯氧基乙基、β-磺酸基乙基、β-氯乙基、β-苯磺酰氧基乙基和式 -CH₂-CH₂-NR¹R² 的基团、 其中 R¹ 和 R² 独立地选自氢、低级烷基和磺基取代的低级烷基； R 是氢、低级烷基或磺基取代的低级烷基； A 是任选被羟基、卤素、低级烷基、低级烷氧基、羧基或磺基取代的亚苯基或亚萘基； W 是任选被羧基、磺基、氨基、未取代或取代的氨基甲酰基、未取代或取代 的氨基磺酰基、低级烷基、低级烷氧基、羟基或卤素取代的亚苯基或亚萘基； Z 是任选被卤素、低级烷氧基或低级烷基取代的亚苯基； 以及上述无金属染料的铜、铬、钴和镍金属化络合染料。 这些新型染料在纤维素纺织品上的染色效果具有很高的锡宽容度和色光纯度，并具有良好的耐光和耐洗牢度，尤其是良好的氯洗牢度。它们特别适用于高温染色操作，并可配制成稳定的水溶液，用于连续染色操作。在化学轧蒸染色中，它们能提供各种色调，并表现出优异的得色率和匀染性。它们的固着力强，在酸性和碱性环境中都具有出色的稳定性。
• Monoazo reactive red dyestuff
  申请人：Everlight USA, Inc.

  公开号：EP1411090B1

  公开（公告）日：2009-11-25
• US4837310A
  申请人：——

  公开号：US4837310A

  公开（公告）日：1989-06-06
• US4855411A
  申请人：——

  公开号：US4855411A

  公开（公告）日：1989-08-08