dithiophosphoric acid O,O'-bis-decyl ester | 2253-59-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机二硫代磷酸及其衍生物
• 英文名称: dithiophosphoric acid O,O'-bis-decyl ester
• 英文别名: dithiophosphoric acid O,O'-didecyl ester；Dithiophosphorsaeure-O,O'-didecylester；O,O'-Didecyl-hydrohendithiophosphat；O,O'-Bis-decyl-dithiophosphorsaeure；Didecyldithiophosphat；O,O'-di(decyl)dithiophosphoric acid；didecoxy-sulfanyl-sulfanylidene-λ5-phosphane
• CAS: 2253-59-0
• 化学式: C₂₀H₄₃O₂PS₂
• 分子量: 410.666
• InChiKey: GQCQJECYDYZWHI-UHFFFAOYSA-N

物化性质

• 熔点：
  158-158.5 °C
• 沸点：
  478.2±14.0 °C(Predicted)
• 密度：
  0.983±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  25
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dithiophosphoric acid O,O'-bis-decyl ester 在 ammonium hydroxide 作用下， 以 水 为溶剂， 反应 0.03h， 生成 didecyldithiophosphate ammonium
  参考文献：
  名称：

  Characterization of Dialkyldithiophosphates as Slow Hydrogen Sulfide Releasing Chemicals and Their Effect on the Growth of Maize

  摘要：

  Hydrogen sulfide is a key gasotransmitter for plants and has been shown to greatly increase their growth and survival in the presence of environmental stressors. Current methods for slowly releasing hydrogen sulfide use chemicals, such as GYY-4137, but these result in the release of chemicals not found in the environment, and chemicals used may lack structures that can be readily tuned to affect the rate of release of hydrogen sulfide. In this article, we describe the synthesis and slow release of hydrogen sulfide from dialkyldithiophosphates, which are a new set of hydrogen sulfide releasing chemicals that can be used in agriculture. The rates of hydrolysis of dibutyldithiophosphate and GYY-4137 were measured in water at 85 degrees C and compared with each other to investigate their differences. GYY-4137 is widely used as a chemical that slowly releases H2S, but its rate of release was not previously quantified. The release of hydrogen sulfide in water at room temperature was measured for a series of dialkyldithiophosphates using a hydrogen sulfide electrode. It was shown that the structure of the dialkyldithiophosphate affected the amount of hydrogen sulfide released. The final degradation products of dibutyldithiophosphate were shown to be phosphoric acid and butanol, which are chemicals found in the environment. This result was notable because it demonstrated that dialkyldithiophosphates degrade to safe, natural chemicals that will not pollute the environment. To demonstrate that dialkyldithiophosphates have potential applications in agriculture, maize was grown for 4.5 weeks after exposure to 1-200 mg of dibutyldithiophosphate, and the weight of corn plants increased by up to 39% at low loadings of dibutyldithiophosphate.

  DOI：

  10.1021/acs.jafc.9b04398
• 作为产物：
  描述：

  癸醇 在 tetraphosphorus decasulfide 作用下， 以 苯 为溶剂， 生成 dithiophosphoric acid O,O'-bis-decyl ester
  参考文献：
  名称：

  Bolotova,G.I. et al., Journal of applied chemistry of the USSR, 1965, vol. 38, p. 1541 - 1546

  摘要：

  DOI：

文献信息

• Catalyst and process for the polymerization of alpha-olefins and a process for preparing an alpha-olefin polymerization catalyst component
  申请人：Standard Oil Company

  公开号：EP0013744A1

  公开（公告）日：1980-08-06

  High activity alpha-olefin polymerization catalysts comprising an organometallic promoter and a component prepared from at least one compound of a Group IVB, VB, or VIB metal, at least one support material which is a divalent metal salt of a phosphorus acid ester having at least one phosphorus acid ester group bonded to metal through oxygen or sulfur, and at least one alkylaluminium halide.

  高活性α-烯烃聚合催化剂，包括有机金属促进剂和由至少一种 IVB、VB 或 VIB 族金属化合物制备的组分，至少一种支撑材料，该支撑材料是磷酸酯的二价金属盐，其中至少有一个磷酸酯基团通过氧或硫与金属键合，以及至少一种烷基卤化铝。
• Use of sulfur-containing acid phosphoric ester as internal release agent
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0553801A1

  公开（公告）日：1993-08-04

  An internal release agent comprises a sulfur-containing acid phosphoric esters selected from the group consisting of thiophosphoric acid esters and dithiophosphoric acid esters of the formula, where X and Y are independently selected from the group consisting of an oxygen atom and a sulfur atom, at least one of X and Y is a sulfur atom, and R₁ and R₂ are independently alkyl groups.

  内脱模剂包括从硫代磷酸酯和二硫代磷酸酯组成的组中选出的含硫酸性磷酸酯，其式为 其中，X 和 Y 独立地选自由氧原子和硫原子组成的组，X 和 Y 中至少有一个是硫原子，R₁ 和 R₂ 独立地为烷基。
• Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
  申请人：TAYCA CORPORATION

  公开号：US10208160B2

  公开（公告）日：2019-02-19

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.

  本发明提供了一种用于生产导电聚合物的氧化剂掺杂剂及其溶液，它们能够生产导电聚合物，适用于生产泄漏电流较低的电解质电容器。此外，还提供了使用其中任一种制备的导电聚合物。还提供了一种具有低泄漏电流的电解质电容器。氧化剂掺杂剂包括：有机铁磺酸盐；以及至少一种选自磷酸、磷酸盐、磷酸、亚磷酸盐、硼酸、硼酸盐、硫代磷酸、硫代磷酸、二硫代磷酸和二硫代磷酸组成的组。溶液包括溶解在水、醇或水与醇混合物中的氧化剂掺杂剂。导电聚合物是通过单体（如噻吩或其衍生物）的氧化聚合而制备的。导电聚合物用作电解质，以提供电解质电容器。
• Method for preparing an electrolyte capacitor
  申请人：TAYCA CORPORATION

  公开号：US10336859B2

  公开（公告）日：2019-07-02

  The method for preparing an electrolyte capacitor includes: providing an oxidant dopant agent for preparing the conductive polymer including: ferric naphthalenesulfonate; and at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate. The method also includes preparing a conductive polymer by using the oxidant dopant agent to obtain an electrolyte comprising the conductive polymer.

  制备电解质电容器的方法包括：提供用于制备导电聚合物的氧化剂掺杂剂，包括：萘磺酸铁；以及至少一种选自磷酸盐、亚磷酸盐、硼酸盐、硫代磷酸盐和二硫代磷酸盐的化合物。该方法还包括使用氧化剂掺杂剂制备导电聚合物，以获得包含导电聚合物的电解液。
• Mazitova, F. N.; Khairullin, V. K., Journal of general chemistry of the USSR, 1980, vol. 50, # 8, p. 1393 - 1396
  作者：Mazitova, F. N.、Khairullin, V. K.

  DOI：——

  日期：——