O-propyl thiophosphorodichloridate | 2523-96-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: O-propyl thiophosphorodichloridate
• 英文别名: O-n-propyl phosphorodichlorothioate；n-Propylthiophosphorodichloridat；O-n-Propyl-phosphordichlorthionat；Propyldichlorothiophosphat；thiophosphorodichloridic acid O-propyl ester；dichlorothiophosphoric acid O-propyl ester；Dichlorothiophosphorsaeure-O-propylester；Thiophosphorsaeure-O-propylester-dichlorid；O-Propyl-dichlorothiophosphat；Phosphorodichloridothioic acid, o-propyl ester；dichloro-propoxy-sulfanylidene-λ5-phosphane
• CAS: 2523-96-8
• 化学式: C₃H₇Cl₂OPS
• 分子量: 193.034
• InChiKey: BWTFGQULKVIPAH-UHFFFAOYSA-N

物化性质

• 沸点：
  201.4±9.0 °C(Predicted)
• 密度：
  1.386±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  41.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  O-propyl thiophosphorodichloridate 在 tetraphosphorus decasulfide 、 甲基三苯基溴化膦 作用下， 生成 二氯二硫代磷酸丙酯
  参考文献：
  名称：

  Synthesis op alkyldichlorodithiophosphates

  摘要：

  DOI：

  10.1007/bf00959898
• 作为产物：
  描述：

  丙醇 在 吡啶 、 三氯氧磷 作用下， 反应 0.5h， 以80%的产率得到O-propyl thiophosphorodichloridate
  参考文献：
  名称：

  Patra, Dipankar; Gupta, Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1999, vol. 38, # 9, p. 1086 - 1089

  摘要：

  DOI：

文献信息

• THE ISOMERIZATION/CHLORINATION OF O,O-DIALLYL THIOPHOSPHORO (-NO)THIONATES WITH PHOSPHORUS OXYCHLORIDE — A NEW CONVENIENT METHOD FOR SYNTHESIS OF S-ALLYL THIOPHOSPHORIC(-NIC) ACID DERIVATIVES
  作者：ZHENG JIE HE、JU XIANG LIU、ZHENG HONG ZHOU、CHU CHI TANG

  DOI：10.1080/10426509808545475

  日期：1998.2.1

  gave S-allyl thiophosphoro(-no)chloride, which reacted with subsitituted phenol in chloroform in the presence of triethylamine to afford eighteen new S-allyl thiophosphoric(-nic) acid derivatives. Thus, a new convenient method has been provided for synthesis of the title compounds.

  O,O-二烯丙基硫代磷酸（-no）硫代磷酸盐与三氯氧化磷的异构化/氯化得到 S-烯丙基硫代磷酸（-no）氯化物，在三乙胺的存在下，它与取代的苯酚在氯仿中反应，得到十八种新的 S-烯丙基硫代磷酸(-nic) 酸衍生物。因此，为标题化合物的合成提供了一种新的方便的方法。
• Lebedev, N. N.; Kiryushatova, T. V.; Savel'yanov, V. P., Journal of general chemistry of the USSR, 1983, vol. 53, # 5, p. 939 - 942
  作者：Lebedev, N. N.、Kiryushatova, T. V.、Savel'yanov, V. P.

  DOI：——

  日期：——
• Mel'nikow et al., Zhurnal Obshchei Khimii, 1959, vol. 29, p. 522,524,525;engl.Ausg.S.520-522
  作者：Mel'nikow et al.

  DOI：——

  日期：——
• STUDIES ON CHIRAL THIOPHOSPHORIC ACIDS AND THEIR DERIVATIVES 14. THE ASYMMETRIC CYCLIZATION OF (+)-CIS-1,2,2-TRIMETHYL-1,3- DIAMINOCYCLOPENTANE WITH THIOPHOSPHORODICHLORIDATES AND O-(4-NITROPHENYL)THIOPHOSPHOROCHLORIDATES
  作者：Chu-Chi Tang、Hui-Fang Lang、Zheng-Jie He、Ru-Yu Chen

  DOI：10.1080/10426509608046418

  日期：1996.7.1

  The cyclization of (+)-cis-1,2,2-trimethyl-1,3-diaminocyclopentane 1 with thiophosphorodichloridates 2 or O-(4-nitrophenyl)thiophosphorochloridates 4 forms (+)-2,4,5-diazaphosphabicyclo[3.2.1]octane 3 and 3', respectively, but the stereoselectivity arising from the condensation of (+)-1 with 4 is less than that of (+)-1 with 2. The distinction between the two product distributions might be due to the significance of different mechanistic routes. In the light of a trigonal bipyramid (TBP) intermediate and Berry pseudorotation (BPR) concept their mechanism are discussed.
• Mandel'baum,Ya.A. et al., Journal of general chemistry of the USSR, 1968, vol. 38, p. 1709 - 1711
  作者：Mandel'baum,Ya.A. et al.

  DOI：——

  日期：——

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