bis(pyridin-3-ylmethylene)naphthalene-1,5-diamine | 293761-35-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis(pyridin-3-ylmethylene)naphthalene-1,5-diamine
• 英文别名: N,N'-bis-pyridin-3-ylmethylele-naphthalene-1,5-diamine；(3-py)-CH=N-C10H6-N=CH(3-py)；Naphtalene-1,5-diamine, N,N'-bis(3-pyridylmethylene)-；1-pyridin-3-yl-N-[5-(pyridin-3-ylmethylideneamino)naphthalen-1-yl]methanimine
• CAS: 293761-35-0
• 化学式: C₂₂H₁₆N₄
• 分子量: 336.396
• InChiKey: XTPBVZXLXSSIKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  26
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis(pyridin-3-ylmethylene)naphthalene-1,5-diamine 在 sodium tetrahydroborate 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 12.0h， 以43%的产率得到(3-py)-CH2-NH-C10H6-NH-CH2-(3-py)
  参考文献：
  名称：

  Relative Coordinating Abilities of Bis(pyridine)-Type Ligands When Forming Mixed-Ligand Coordination Polymers: Preparation and Structure of [Cd₂(L1

  摘要：

  DOI：

  10.5012/bkcs.2010.31.9.2668
• 作为产物：
  描述：

  3-吡啶甲醛 、 1,5-萘二胺 以 二氯甲烷 为溶剂， 生成 bis(pyridin-3-ylmethylene)naphthalene-1,5-diamine
  参考文献：
  名称：

  镉的离散分子和一维配位聚合物：[Cd（L1）2（NO3）2（CH3OH）]和{[Cd（L2）（CH3COO）2]·（CH3OH）的制备，结构和性质）}∞（L1 =（4-Py）–CH = N–C10H6-NH2； L2 =（3-Py）–CH = N–C10H6–N = CH–（3-Py））

  摘要：

  由4-吡啶甲醛和1,5-二氨基萘制备了不对称配体（4-py）–CH = NC– H 10 H 6 -NH 2（L 1）。配体L 1与Cd（NO 3）2 ·4H 2 O在甲醇中反应，得到离散的分子络合物，[Cd（L 1）2（NO 3）2（CH 3 OH）]（1）。此外，具有一个分子的甲醇一维镉配位聚合物，{[CD（L 2）（CH 3 COO）2 ]·（CH 3 OH）} ∞（2）是由对称配体（L 2 =（3-py）–CH = N–C 10 H 6 –N = CH–（3-py））和Cd（OAc）2 ·2H 2 O制备的。

  DOI：

  10.1002/bkcs.11853

文献信息

• Cd(II) coordination polymers based on expanded N,N′-heteroaromatic donor ligands
  作者：Mansoureh Zahedi、Behrouz Shaabani、Ulli Englert、Negar Rad-yousefnia、Graeme R. Blake、Canan Kazak

  DOI：10.1016/j.poly.2017.05.023

  日期：2017.9

  subtending Cd⋯Cd distances consistent with their N donor arrangement. The co-ligands control the coordination number of the Cd(II) cations and interchain connectivity: The acetate moieties either adopt bridging and chelating or exclusively bridging modes and crosslink essentially linear chains based on octahedral metal centers; in the former case, the ladder-like one-dimensional ribbon 1 is generated, whereas

  摘要异构N供体连接基双（吡啶-4-基亚甲基）萘-1,5-二胺（L1）和双（吡啶-3-基亚甲基）萘-1,5-二胺（L2）已与乙酸盐和碘化物一起使用作为共配体生成四种新的镉（II）配位聚合物。[CdL1（OAc）2] n（1），[CdL1（I）2] n（2），[CdL2（OAc）2] n（3）和[CdL2（I）2] n（4）的特征在于元素分析，粉末X射线衍射，红外光谱，热分析和单晶X射线衍射。与晶体工程学的概念一致，它们的结构具有相同的图案：杂芳族连接基团产生链，其Cd⋯Cd距离与它们的N供体排列一致。共配体控制Cd（II）阳离子的配位数和链间连接性：乙酸酯部分采用桥接和螯合或仅桥接的方式，并基于八面体金属中心交联基本为线性的链。在前一种情况下，生成梯形一维带状结构1，而在后一种连通性下，则生成二维层结构3。相反，碘化物充当四面体Cd（II）的末端配体，因此2和4是单链1D之字形聚合物。与未配
• Novel long bipyridine-type linking ligands containing an intervening naphthalene fragment: [Zn(L1)(NO3)2], [Zn(L2)(NO3)2], and [Cd(L1)1.5(NO3)2] (L1=(4-py)–CHN–C10H6–NCH–(4-py); L2=(3-py)–CHN–C10H6–NCH–(3-py))
  作者：Dongwon Min、Bo-Yeun Cho、Soon W. Lee

  DOI：10.1016/j.ica.2005.09.041

  日期：2006.1

  Novel bipyridine-type linking ligands L-1 ((4-py)-CH=N-C10H6-N=CH-(4-py)) and L-2 ((3-py)-CH=N-C10H6-N=CH-(3-py)), a pair of isomers due to possessing different pairs of terminal pyridyl groups, were prepared by the Schiff-base condensation. In ligand L-1, the (NN)-N-... separation between the terminal pyridyl groups is 16.0 angstrom, with their nitrogen donor atoms at the para positions (4,4'). The corresponding (NN)-N-... separation in ligand L-2 is 14.2 angstrom, with the nitrogen donor atoms at the meta positions (3,3'). 1-D zigzag-chain coordination polymers [Zn(L-1)(NO3)(2)] (1) and [Zn(L-2)(NO3)(2)] (2) were prepared by reactions of Zn(NO3)(2) (.) 6H(2)O with ligands L-1 and L-2, respectively, by solution diffusion. Polymer 3, [Cd(L-1)(1.5)(NO3)(2)], prepared from Cd(NO3)(2) (.) 4H(2)O and L-1, exhibits a 1-D ladder structure, whose repeating ladder unit consists of four Cd metals and four L-1 ligands to create a large 76-membered ring with dimensions of 20.8 x 20.8 angstrom. All products were structurally characterized by X-ray diffraction. (c) 2005 Elsevier B.V. All rights reserved.
• Coordination polymers formed by sharing rectangular units: [M(L1)2(NO3)2]∞ {M=Cd, Co; L1=(3-py)CHNC10H6NCH(3-py)}
  作者：Yeong-Min Jung、Soon W. Lee

  DOI：10.1016/j.molstruc.2009.03.014

  日期：2009.6

  Two coordination polymers [Cd(L-1)(2)(NO3)(2)](infinity) (1) and [Co(L-1)(2)(NO3)(2)](infinity) (2) were prepared from the long 3,3'-bispyridine-type ligand L-1 (3-py)-CH=N-C10H6-N=CH-(3-py)} and the corresponding metal nitrate. These polymers have different rectangular units: Cd4L41 and Co2L21. Whereas the Cd4L41 units are linked by edge-sharing to give a 2-dimensional polymer (1), the Co2L21 units are linked by vertex-sharing to produce a double-bridged 1-D chain polymer (2). (C) 2009 Elsevier B.V. All rights reserved.