tris(piperidine-1-carbodithioato)iron(III) | 20487-62-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: tris(piperidine-1-carbodithioato)iron(III)
• 英文别名: Iron(3+);piperidine-1-carbodithioate
• CAS: 20487-62-1
• 化学式: C₁₈H₃₀FeN₃S₆
• 分子量: 536.699
• InChiKey: QLHDAXSAEPBKIM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  3.91
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  109
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  三氯化铁 、 sodium piperidinedithiocarbamate 以 水 为溶剂， 以85%的产率得到tris(piperidine-1-carbodithioato)iron(III)
  参考文献：
  名称：

  Substituent Effect on Carbodithioate Ligand Field Strength in Iron(III) Carbodithioates: Synthesis and Characterization

  摘要：

  DOI：

  10.1080/00945710009351786

文献信息

• Infrared spectral, variable-temperature magnetic susceptibility and Mössbauer spectral investigations on tris(carbodithioato) iron(III) complexes
  作者：Baldev Singh Manhas、Shashi Bala

  DOI：10.1016/s0277-5387(00)83860-7

  日期：1988.1

  Two types of iron(III) carbodithioate complexes, (i) normal complexes, Fe(R2NCS2)3 with R2N = 4-methyl-, 4-phenyl-, or 2-methyl-piperazyl, piperidyl and thiomorpholyl and (ii) zwitterionic complexes, Fe(R2NCS2H)3X3 with R2N = 4-methyl- or 4-phenyl-piperazyl and X = Cl or Br have been synthesized. The complexes have been characterized by elemental analyses, IR spectral studies, variable-temperature

  两种类型的二硫代铁（III）碳配合物，（i）正常配合物，具有R2N的Fe（R2NCS2）3 = 4-甲基，4-苯基或2-甲基-哌嗪基，哌啶基和硫代吗啉基，以及（ii）两性离子配合物合成了具有R 2N ＝ 4-甲基或4-苯基哌嗪基且X ＝ Cl或Br的Fe（R 2 NCS 2 H）3 X 3。通过元素分析，红外光谱研究，可变温度磁化率和三种情况下的可变温度Mossbauer光谱研究对复合物进行了表征。所有配合物均表现出2T2（低自旋，S = 12）⇌6A1（高自旋，S = 52）自旋平衡过程。两性离子碳二硫代盐配体比其正常的配体类似物具有弱的配体场强。
• Heterocyclic dithiocarbamato-iron(<scp>iii</scp>) complexes: single-source precursors for aerosol-assisted chemical vapour deposition (AACVD) of iron sulfide thin films
  作者：Sixberth Mlowe、David J. Lewis、Mohammad Azad Malik、James Raftery、Egid B. Mubofu、Paul O'Brien、Neerish Revaprasadu

  DOI：10.1039/c5dt03881b

  日期：——

  single-source precursors for the deposition of iron sulfide thin films by aerosol-assisted chemical vapour deposition (AACVD). Energy-dispersive X-ray (EDX) spectroscopy confirmed the formation of iron sulfide films. The addition of tert-butyl thiol almost doubled the sulfur content in the deposited films. Scanning electron microscopy (SEM) images of the iron sulfide films from both complexes showed flakes/leaves/sheets

  合成了Tris-（哌啶二硫代氨基甲酸酯）铁（III）（1）和Tris-（四氢喹啉二硫代氨基甲酸酯）铁（III）（2）配合物，并确定了它们的单晶X射线结构。配合物的热重分析（TGA）显示分解为硫化铁。然后将这两种络合物用作通过气溶胶辅助化学气相沉积（AACVD）沉积硫化铁薄膜的单源前驱体。能量色散X射线（EDX）光谱证实了硫化铁膜的形成。叔叔的加法丁基硫醇几乎使沉积膜中的硫含量增加了一倍。两种复合物的硫化铁膜的扫描电子显微镜（SEM）图像均显示为片状/片状/片状，球形颗粒和纳米纤维。这些微晶的尺寸和形状取决于前体的性质，温度，溶剂和所用叔丁基硫醇的量。观察到的光学性质取决于反应参数如温度和溶剂的变化。粉末X射线衍射（p-XRD）研究表明，磁黄铁矿，六方相（Fe 0.975 S），镁铁矿相和菱锰矿（Fe 3 S 4）相的沉积方式不同。
• Mixed ugand complexes of iron(III) derived from its dithiocarbamato complexes
  作者：Bhagwan S. Garg、Ranjana Dixit、Asha L. Singh

  DOI：10.1007/bf01913654

  日期：1990.11

  Three different types of iron(III) complexes, Fe(A)3, Fe(A)2(A') and Fe(A)(A')2, where A is either piperidyldithiocarbamate or morpholyl dithiocarbamate and A' is glycine(oxine) acetylacetone have been prepared by reacting Fe(III) salt with sodium salt of piperidinedithiocarbamic acid or morpholine-dithiocarbamic acid and acetylacetone(oxine)-glycine in different ratios. The mixed ligand complexes have been characterised by elemental analysis, magnetic susceptibility measurements, infrared, electronic spectral techniques and by thermal analysis. Electronic spectral studies suggests that all the complexes possess distorted octahedral geometry. The magnetic moment of the high spin iron(III) complexes lies in the range of 5.88-6.00 and for low spin lies in the range of 3.36-4.34 B.M. TG studies show one step decomposition of complexes and formation of Fe2O3 at the end of the step.