rutheniumdichloridetricarbonyl | 61003-62-1

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: rutheniumdichloridetricarbonyl
• 英文别名: tricarbonyldichlororuthenium (II)；[ruthenium(II)(tricarbonyl)dichloride]；carbon monoxide;dichlororuthenium
• CAS: 61003-62-1
• 化学式: C₃Cl₂O₃Ru
• 分子量: 256.007
• InChiKey: NMBWHCRPDMRPEZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -6.11
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  rutheniumdichloridetricarbonyl 、 2-苯胺基吡啶 以 乙二醇甲醚 为溶剂， 以5%的产率得到
  参考文献：
  名称：

  Ruthenium(II) complexes of 2-(p.Toluidino)pyridine and rhodium(III) complexes of N,N′-di(2-pyridyl)-1,3-diamino-s-chlorobenzene

  摘要：

  DOI：

  10.1016/s0277-5387(00)86695-4
• 作为产物：
  描述：

  水合三氯化钌 在 一氧化碳 作用下， 以 乙醇 为溶剂， 生成 rutheniumdichloridetricarbonyl
  参考文献：
  名称：

  The carbonylation of RuCl3·3H2O in ethanol: an infrared spectroscopic study

  摘要：

  DOI：

  10.1016/s0020-1693(00)85928-9
• 作为试剂：
  描述：

  1,2,2-三甲基-二环{1.1.0}丁烷 在 rutheniumdichloridetricarbonyl 作用下， 以 氯仿 为溶剂， 生成 3,4-Dimethyl-1,3-pentadiene
  参考文献：
  名称：

  Transition Metal Complex Promoted Rearrangements. The Effect of the Metal and of the Attached Ligands on the Mode of Cleavage of Methylated Bicyclo[1.1.0]butanes

  摘要：

  DOI：

  10.1021/ja00777a602

文献信息

• Catalytic hydrogenation of N-benzylideneaniline using a new complex of ruthenium(II) derived from 2-ferrocenyl-1,8-naphthyridine
  作者：C. Zúñiga、S.A. Moya、M. Fuentealba、B. Aranda、P. Aguirre

  DOI：10.1016/j.inoche.2011.03.043

  日期：2011.6

  cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) complex (2) have been synthesized and characterized by IR, 1H-NMR spectroscopy and elemental analysis. The structure of the compounds was determined by X-ray analysis. The complex (2) showed catalytic activity in the hydrogenation reaction of N-benzylideneaniline by hydrogen transfer with conversions between 89% and 33% for catalyst/substrate

  摘要 2-Ferrocenyl-1,8-naphthyridine (1) 和cis,cis,cis-dicarbonyl-dichloro-bis (2-ferrocenyl-1,8-naphthyridine) ruthenium(II) 配合物 (2) 已被合成并表征为IR、1H-NMR光谱和元素分析。通过X-射线分析确定化合物的结构。配合物 (2) 在 N-亚苄基苯胺通过氢转移的氢化反应中显示出催化活性，对于催化剂/底物关系 200/1 和 400/1，转化率在 89% 和 33% 之间。
• Cyclometallation of N,N-dimethyl-furan-2(and 3)-carboselenoamide with palladium(II), rhodium(III) and ruthenium(II)
  作者：Matsuo Nonoyama、Kiyoko Nonoyama

  DOI：10.1016/s0277-5387(00)86150-1

  日期：1991.1

  trichlorobis(tri-n-butylphosphine)rhodium(III) in refluxing toluene to give RhCl2(C-E)(PBu3)2. The bromo analogues are similarly obtained. Hbfs is similarly cycloruthenated with dichlorotricarbonylruthenium(II) in refluxing 2-methoxyethanol to afford RuCl(bfs)(CO)2, but Hafs is not cycloruthenated under the same conditions. This fact suggests that Hbfs is more reactive towards cyclometallation than Hafs.

  用甲醇中的四氯钯酸锂将新鲜制备的N，N-二甲基呋喃2（和3）-碳烯酰胺（分别缩写为H（CE）或Hafs和Hbfs）环钯制成PdCl（CE），与三氯甲烷反应-正丁基膦（PBu 3）和4-叔丁基吡啶（tbp）得到加合物PdCl（CE）（PBu 3）和PdCl（CE）（tbp）。还制备了碘类似物。光谱表征表明，H（CE）的呋喃环是环钯的，硒代酰胺基团的硒原子配位形成五元的palladaselenaheterocycle。Hbfs的环palpalpalation只发生在呋喃环的位置2。在回流的甲苯中，用三氯双（三正丁基膦）铑（III）将两种硒代酰胺环化，得到RhCl 2（CE）（PBu 3）2。类似地获得了溴代类似物。类似地，在回流的2-甲氧基乙醇中，用二氯三羰基钌（II）环化Hbfs，得到RuCl（bfs）（CO）2，但在相同条件下，Hafs不会被环化。这一事实表明，Hbfs对环金属化的反应性强于Hafs。
• Organotransition-metal metallacarboranes. 12. Arene-metal-carborane triple-decker sandwiches. Designed synthesis of homo- and heterobimetallic complexes of cobalt, iron, ruthenium, and osmium
  作者：James H. Davis、Ekk Sinn、Russell N. Grimes

  DOI：10.1021/ja00195a034

  日期：1989.6

  2}Bsub 3}Hsub 3})FeCp was prepared via treatment of (eta}sup 6}-Csub 8}Hsub 10})Fe(Etsub 2}Csub 2}Bsub 3}Hsub 4})sup minus}} with Nasup +}Cpsup minus}} and CoClsub 2} followed by air oxidation. The reaction of (CO)sub 3}RuClsub 2} with (Csub 5}mesub 5})Co(Etsub 2}Csub 2}Bsub 3}Hsub 3})sup 2minus}} gave the pseudo-triple-decker complex (Csub 5}Mesub 5})Co(Etsub 2}Csub 2}Bsub

  本文描述了包含形式环 Etsub 2}Csub 2}Bsub 3}Hsub 3}sup 4minus}} 桥连配体的三层夹心复合物新家族的系统制备和表征，包括此类的第一个物种，包含第二或第三行过渡金属。通式 (L)M(Etsub 2}Csub 2}Bsub 3}Hsub 3})Mprime}(L) (M = Ru, Os; Mprime} = Co ，Ru；L = 伞花烃（对异丙基甲苯）、Cp 或 Csub 5}Mesub 5}）通过 (1) Closo-(L)M(Etsub 2}C) 的合成逐步获得sub 2}Bsub 4}Hsub 4}) 金属碳硼烷，(2) 这些配合物的斩首（去除顶点 BH）得到 nido-(L)M(Etsub 2}Csub 2}B sub 3}Hsub 5}), (3) 桥去质子化形成相应的单阴离子或双阴离子，(4)阴离子
• Synthesis and evaluation of the catalytic properties of homo- and hetero-bimetallic complexes containing bridging diphenylphosphido ligands
  作者：Zhongli He、Noël Lugan、Denis Neibecker、René Mathieu、Jean-Jacques Bonnet

  DOI：10.1016/0022-328x(92)83047-l

  日期：1992.3

  The bimetallic complex [(CO)3Ru(mu-PPh2)2Ru(CO)3] (1) has been prepared in 42% yield by the reaction of [Ru3(CO)12] with tetraphenyldiphosphine in refluxing THF. Other new heterobimetallic complexes containing bridging diphenylphosphido ligands, e.g., [(CO)3Ru(mu-PPh2)2Fe(CO)3] (2), [(CO)3Ru(mu-PPh2)2M(CO)4](4: M = Cr; 5: M = Mo; 6: M = W) and [(PPh3)M'(mu-PPh2)2M(CO)4](7: M' = Pd, M = Cr; 8: M' = Pd, M = Mo; 10: M' = Pt, M = Mo) have been synthesized by the "bridge-assisted" synthetic method. The X-ray structure of [(PPh3)Pd(mu-PPh2)2 Mo(CO)4] (8) is reported. These complexes, along with [(CO)3Fe(mu-PPh2)2Fe(CO)3], [(PPh3)Pd(mu-PPh2)2W(CO)4], and [(PPh3)Pt(mu-PPh2)2W(CO)4] have been screened as catalyst precursors for (i) the hydroformylation of styrene (120-degrees-C, 20 bar, CO/H-2 = 1), and (ii) the hydrogenation of cyclohexanone (140-degrees-C, 40 bar H-2). The most efficient precursor for the first catalytic reaction was found to be the RuFe complex 2: a synergistic effect between iron and ruthenium has been observed, the turn-over frequency (TOF) increasing from 0.4 h-1 for the RuRu complex 1 and 0.9 h-1 for the FeFe complex 3, to 4.0 h-1 for the FeRu compound 2. The three complexes were recovered at the end of the catalytic reaction. In the catalytic hydrogenation of cyclohexanone, the most active was found to be the RuMo complex 5 but it was not recovered at the end of the reaction.
• Ruthenium(II) complexes derived from 2-(methylamino)pyridine
  作者：Matsuo Nonoyama

  DOI：10.1016/s0020-1693(00)84409-6

  日期：1986.5