butoxymethyl-urea | 98275-84-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: butoxymethyl-urea
• 英文别名: Butoxymethyl-harnstoff；Butyloxymethyl-harnstoff；Butoxymethylurea
• CAS: 98275-84-4
• 化学式: C₆H₁₄N₂O₂
• 分子量: 146.189
• InChiKey: WYSGYXOFKRUIFW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  64.4
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 butoxymethyl-urea 在 水 作用下， 生成 N-butoxymethyl-N'-hydroxymethyl-urea
  参考文献：
  名称：

  GG对AG种植的动力学研究表明，顺铂的双水合衍生物是真正的DNA结合物种。

  摘要：

  使发夹稳定的双链寡核苷酸d（TATGGTATT4ATACCATA）（I）和d（TATAGTATT4ATACTATA）（II）与抗癌药物顺铂的三种水合形式（cis- [PtCl2（NH3）2]，1）反应可能是DNA结合的候选物，即顺式[PtC1（NH3）2（H2O）] +（2），顺式[Pt（NH3）2（H2O）2] 2+（3）及其结合物碱式-[Pt（OH）（NH3）2（H2O）] +（4）。为了比较，还研究了I与[Pt（NH3）3（H2O）] 2+（5）之间的反应。通过HPLC监测所有反应。I和II的铂化反应在293 K的NaClO4（0.1M）中，在4.5 +/- 0.1的恒定pH下进行2、3和5进行。在接近中性的起始pH值的无缓冲NaClO4溶液（0.1M）中溶解，其中3和4处于平衡状态。在这种情况下，通过描述pH时间曲线的拟合函数，可以确定3、4和二羟基配合物的实际浓度。分别确定表征I

  DOI：

  10.1002/1521-3765(20000602)6:11<2002::aid-chem2002>3.0.co;2-h
• 作为产物：
  描述：

  羟甲基脲 、 正丁醇 在 盐酸 作用下， 生成 butoxymethyl-urea
  参考文献：
  名称：

  Methylol urea ethers and process for making same

  摘要：

  公开号：

  US02201927A1

文献信息

• Coating composition
  申请人：Ford Motor Company Limited

  公开号：EP0029339A1

  公开（公告）日：1981-05-27

  A fast curing, coating composition that is adapted for use as an automotive topcoat and which upon curing forms a hard, glossy, durable coating exhibiting excellent resistance to solvents and water. The coating composition which may contain greater than about 55 percent by weight of nonvolatile solids and, exclusive of pigments, solvents and other nonreactive components, consists essentially of: (A) a bifunctional copolymer bearing hydroxy functionality and pendent epoxy functionality, having a number average molecular weight (Mn) of between about 1500 to about 10.000 and a glass transition temperature (Tg) of between about -25° to about 70°; (B) a reactive catalyst comprising at least one phosphonic acid derivative; (C) an amino resin crosslinking agent; and (D) optionally, a hydrcxy functional additive. The phosphonic acid derivative catalyst is ncluded in the composition in an amount sufficient to provide between about 8 to about 1.4 equivalents of acid functionality in copolymer (A), and the amino resin crosslinking agent is Included in the composition in an amount sufficient to provide at least about .4 equivalents of nitrogen crosslinking functionality for each equivalent of hydroxy functionality included in the composition.

  一种快速固化的涂料组合物，可用作汽车面漆，固化后可形成坚硬、光亮、耐久的涂层，具有优异的耐溶剂性和抗水性。该涂料组合物的非挥发性固体含量按重量计可超过 55%，除颜料、溶剂和其他非反应性成分外，主要由以下成分组成： (A) 含有羟基官能团和下垂环氧官能团的双官能团共聚物，其平均分子量 (Mn) 在约 1500 到约 10.000 之间，玻璃化温度 (Tg) 在约 -25° 到约 70° 之间； (B) 由至少一种膦酸衍生物组成的活性催化剂； (C) 一种氨基树脂交联剂；以及 (D) 可选的水合官能添加剂。 膦酸衍生物催化剂在组合物中的用量足以在共聚物（A）中提供约 8 至约 1.4 个当量的酸官能度，氨基树脂交联剂在组合物中的用量足以为组合物中的每一个当量的羟基官能度提供至少约 0.4 个当量的氮交联官能度。
• Thermosetting composition
  申请人：FORD MOTOR COMPANY LIMITED

  公开号：EP0032053A1

  公开（公告）日：1981-07-15

  A thermosetting composition particularly suitable as a high solids coating composition for automotive applications. Exclusive of pigments, solvents and ether non-reactive components, the composition consists essentially of: (A) an oligomeric hydroxy functional phosphate ester having a number average molecular weight of between about 500 and about 5000 and being prepared by reaction of a polyepoxide and an acid phosphate ester; (B) up to 50 weight percent of a hydroxy functional compound; and (C) between about 1 and about 50 weight percent of an amine aldehyde crosslinking agent.

  一种热固性组合物，特别适合用作汽车应用的高固体份涂料组合物。除颜料、溶剂和醚类非反应性成分外，该组合物主要由以下成分组成：(A) 低聚羟基官能磷酸酯，其平均分子量在约 500 到约 5000 之间，由聚环氧化物和酸性磷酸酯反应制备；(B) 高达 50 重量百分比的羟基官能化合物；以及 (C) 约 1 到约 50 重量百分比的胺醛交联剂。
• Coating compositions and polyhydroxy oligomer precursors therefor
  申请人：FORD MOTOR COMPANY LIMITED

  公开号：EP0086308A1

  公开（公告）日：1983-08-24

  A novel polyhydroxy oligomer crosslinkable with aminoplast resins to form a coating composition adapted for use as an automotive topcoat which upon curing forms a hard, glossy, durable coating with outstanding durability and excellent resistance to solvents and water. The coating composition comprises: (A) a polyhydroxy oligomer having a number average (Mn) molecular weight of between about 250-2000 and being the reaction produce of: (i) an ester having pendant hydroxyl and carboxyl functionality and being made by reacting (a) a C3-Clo aliphatic branched diol, and (b) an alkyl hexahydrophthalic anhydride, wherein (a) and (b) are combined in the reactant mixture in an amount sufficient to allow reaction in at least about a 1:1 molar ratio; and (ii) a C2-C10 monomer, having reactive functionality capable of esterifying said carboxyl functionalilty of said ester, said C2-C10 monomer being selected from the group consisting of: (a) a monomer wherein said reactive functionality reacts with said carboxyl functionality to form an hydroxy in addition to an ester linkage; (b) a monomer bearing hydroxyl functionality in addition to said reactive functionality and wherein said reactive functionality does not generate an hydroxy in addition to an ester linkage; and (c) a monomer bearing hydroxyl functionality in addition to said reactive functionality wherein said reactive functionality reacts with said carboxyl functionality to form a hydroxyl in addition to an ester linkage, wherein said ester and said C.-C1o monomer are combined in the reactant mixture in an amount sufficient to allow reaction in about a 1:1 molar ratio; (B) an amine-aldehyde or polyisocyanate crosslinking agent; and (C) 0-50 weight percent based on the total weight of (A), (B) and (C) of hydroxy functional additive having a number average molecular weight (Mn) of between about 150-6000, In addition, the coating composition of this invention may include conventional additives such as catalysts, antioxidants, U.V. absorbers, flow control or wetting agents, antistatic agents, pigments, plasticiers, solvents, etc. The oligomers of this composition are also compatible with non- agueous dispersions (NAD's).

  一种可与氨基树脂交联的新型聚羟基低聚物，可形成一种用作汽车面漆的涂料组合物，固化后可形成坚硬、有光泽、耐用的涂层，具有出色的耐久性和优异的耐溶剂和耐水性。该涂料组合物包括 (A) 聚羟基低聚物，其平均（Mn）分子量在 250-2000 之间，是下列物质的反应产物： (B) 聚羟基低聚物，其平均（Mn）分子量在 250-2000 之间： (i) 具有羟基和羧基官能团的酯，由以下物质反应生成 (a) C3-Clo 脂肪族支链二元醇，和 (b) 烷基六氢邻苯二甲酸酐，其中(a)和(b)在反应物混合物中的结合量足以使反应至少以大约 1:1 的摩尔比进行；以及 (ii) C2-C10 单体，具有可将所述酯的羧基官能团酯化的反应性官能团，所述 C2-C10 单体选自以下组成的组： (a) 单体，其中所述活性官能团与所述羧基官能团反应，除形成酯连接外，还形成羟基； (b) 除所述反应性官能团外还含有羟基官能团的单体，其中所述反应性官能团除 酯键外不产生羟基；及 (c) 除所述反应性官能团外还含有羟基官能团的单体，其中所述反应性官能团与所述羧基官能团反应以形成除酯连接外的羟基，其中所述酯和所述 C.-C1o 单体在反应物混合物中的结合量足以使反应以约 1:1 的摩尔比进行； (B) 一种胺-醛或多异氰酸酯交联剂；以及 (C) 以(A)、(B)和(C)的总重量为基准，0-50%、 (B)和(C)总重量的 0-50%的羟基官能团添加剂，其平均分子量(Mn)约为 150-6000、 此外，本发明的涂料组合物还可包括常规添加剂，如催化剂、抗氧化剂、紫外线吸收剂、流动控制剂或润湿剂、抗静电剂、颜料、增塑剂、溶剂等。本组合物的低聚物还可与非琼脂分散体（NAD）相容。
• Polyester film for decorative plate or decorative sheet
  申请人：Diafoil Hoechst Co., Ltd.

  公开号：EP0839856A2

  公开（公告）日：1998-05-06

  The present invention relates to a polyester film for decorative plate or decorative sheet, which comprises a base polyester film and a coating layer formed on at least one surface of said base film, and which has an optical density of 0.1 to 5.0 and longitudinal and transverse heat shrinkage percentages of not less than -10.0 % and not more than +10.0 % after said film is heat-treated at 180°C for 5 minutes.

  本发明涉及一种用于装饰板或装饰片材的聚酯薄膜，它包括聚酯薄膜基材和形成在所述基材薄膜至少一个表面上的涂层，在所述薄膜于 180°C 热处理 5 分钟后，其光学密度为 0.1 至 5.0，纵向和横向热收缩百分比不小于 -10.0 % 且不大于 +10.0%。
• PROCESS FOR SEMICONDUCTOR DEVICE PRODUCTION USING UNDER-RESIST FILM CURED BY PHOTOCROSSLINKING
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP2085822A1

  公开（公告）日：2009-08-05

  There is provided a resist underlayer film forming composition used in a lithography process for producing semiconductor devices. A method of producing a semiconductor device comprising: forming a coating film by applying a resist underlayer film forming composition containing a polymer, a crosslinker and a photoacid generator on a semiconductor substrate; forming an underlayer film by irradiating light to the coating film; and forming a photoresist by applying a photoresist composition on the underlayer film and heating the resultant layer. The polymer polymer is a polymer having a benzene ring or a hetero ring in a main chain or a side chain bonded to the main chain, and the content rate of a benzene ring in the polymer is 30 to 70% by mass. The polymer may be a polymer containing a lactone structure.

  本发明提供了一种抗蚀剂底层成膜组合物，用于生产半导体器件的光刻工艺中。一种生产半导体器件的方法包括：通过在半导体衬底上涂敷含有聚合物、交联剂和光酸发生器的抗蚀剂底层成膜组合物形成涂膜；通过向涂膜照射光形成底层膜；以及通过在底层膜上涂敷光致抗蚀剂组合物并加热所形成的层形成光致抗蚀剂。聚合物 聚合物是在主链或与主链结合的侧链中具有苯环或杂环的聚合物，聚合物中苯环的含量为 30% 至 70%（按质量计）。聚合物可以是含有内酯结构的聚合物。