bis-1,2-(carbamoylmethylsulfanyl)ethane | 14848-15-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 甲亚胺酸及其衍生物
• 英文名称: bis-1,2-(carbamoylmethylsulfanyl)ethane
• 英文别名: 3,6-dithia-octanedioic acid diamide；Aethylen-bis-thioglykolsaeureamid；3,6-Dithia-octandisaeure-diamid；Acetamide, 2,2'-[1,2-ethanediylbis(thio)]bis-；2-[2-(2-amino-2-oxoethyl)sulfanylethylsulfanyl]acetamide
• CAS: 14848-15-8
• 化学式: C₆H₁₂N₂O₂S₂
• mdl: MFCD24387980
• 分子量: 208.305
• InChiKey: FSQNKULQNRHAOT-UHFFFAOYSA-N

物化性质

• 沸点：
  497.4±35.0 °C(Predicted)
• 密度：
  1.325±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.6
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.666
• 拓扑面积：
  137
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3,6-dithia-octanedioic acid diethyl ester 在 氨 、 水 作用下， 生成 bis-1,2-(carbamoylmethylsulfanyl)ethane
  参考文献：
  名称：

  Tiberg, Chemische Berichte, 1916, vol. 49, p. 2027

  摘要：

  DOI：

文献信息

• Synthesis and antimycobacterial activity of pyridinium compounds with sulfonylacetamide substituent in N-alkyl chain
  作者：Marina M. Shulaeva、Marionella A. Kravchenko、Vyacheslav E. Semenov

  DOI：10.1007/s10593-018-2362-3

  日期：2018.9

  Pyridines containing amine, amide, or hydrazide substituent were quaternized with (ω-haloalkyl)sulfonylacetamides, resulting in new pyridinium compounds that exhibited tuberculostatic activity against the strain H37Rv of Mycobacterium tuberculosis.

  将含有胺，酰胺或酰肼取代基的吡啶与（ω-卤代烷基）磺酰基乙酰胺进行季铵化反应，制得新的吡啶鎓化合物，该化合物对结核分枝杆菌H37Rv菌株具有抑菌活性。
• SEPARATION REAGENT OF PLATINUM GROUP METAL, METHOD FOR SEPARATING AND RECOVERING PLATINUM GROUP METAL, AND AMIDE-CONTAINING TERTIARY AMINE COMPOUND
  申请人：NARITA Hirokazu

  公开号：US20100095807A1

  公开（公告）日：2010-04-22

  The present invention provides a novel separation reagent capable of obtaining a high extraction % of rhodium in a chlorine-based acid solution, which has never existed heretofore, and a method for separating and recovering a platinum group metal using the same. An organic phase composed of an amide-containing tertiary amine separation reagent represented by the structural formula shown below is brought into contact with an acid solution containing a platinum group metal, thereby extracting rhodium, platinum and palladium with the organic phase. Among the metals extracted with the organic phase, rhodium is selectively back-extracted with a highly-concentrated hydrochloric acid solution, while palladium and platinum are back-extracted with a highly-concentrated nitric acid solution: wherein at least one of R 1 , R 2 and R 3 represents an amide group represented by: R 1 to R 3 other than the amide group and R 4 to R 6 represent a group selected from an optionally branched chain hydrocarbon group of 1 to 18 carbon atoms, an alicyclic hydrocarbon group of 1 to 10 carbon atoms, and an aromatic hydrocarbon group of 1 to 14 carbon atoms.

  本发明提供了一种新型分离试剂，能够在含氯酸溶液中获得高萃取率的铑，此前从未存在过，以及使用该试剂分离和回收铂族金属的方法。将由下式表示的含酰胺的三级胺分离试剂组成的有机相与含铂族金属的酸性溶液接触，从而用有机相萃取铑、铂和钯。在从有机相中萃取的金属中，铑选择性地被高浓度盐酸溶液回萃，而钯和铂则被高浓度硝酸溶液回萃：其中，R1、R2和R3中的至少一个表示由下式表示的酰胺基：R1到R3除了酰胺基外，R4到R6表示选自1到18个碳原子的可选支链烃基、1到10个碳原子的脂环烃基和1到14个碳原子的芳香烃基的基团。
• Synthesis and Antimicrobial Activity of Amines Containing Carbamoylmethylsulfonyl Fragments
  作者：M. M. Shulaeva、A. D. Voloshina、A. S. Sapunova、N. V. Kulik、V. E. Semenov

  DOI：10.1134/s107036321811004x

  日期：2018.11

  A series of amines containing long hydrocarbon substituents and carbamoylmethylsulfonyl fragments have been synthesized. Antimicrobial activity of the prepared amines and their hydrochlorides against several test microorganisms has been investigated.
• US8609898B2
  申请人：——

  公开号：US8609898B2

  公开（公告）日：2013-12-17
• Tiberg, Chemische Berichte, 1916, vol. 49, p. 2027
  作者：Tiberg

  DOI：——

  日期：——