bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonate | 134164-40-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonate
• 英文别名: ethyl-bis(naphthalen-1-ylmethyl)sulfanium;hexafluoroantimony(1-)
• CAS: 134164-40-2
• 化学式: C₂₄H₂₃S*F₆Sb
• 分子量: 579.253
• InChiKey: QFPQFAUWEGFXGQ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  8.47
• 重原子数：
  32
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  Bis-<1>naphthylmethyl-sulfid 、 Triethyloxonium hexafluoroantimonate 以 二氯甲烷 为溶剂， 以to give 9.07 g (98% of theory) of bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonate in the form of white crystals of melting point 101°-105° C.的产率得到bis(1-naphthylmethyl)ethylsulfonium hexafluoroantimonate
  参考文献：
  名称：

  Araliphatic sulfonium salts and their use

  摘要：

  公式I至IV的磺鎵鹽##STR1##其中A是C.sub.1-C.sub.12烷基，C.sub.3-C.sub.8环烷基，C.sub.4-C.sub.10环烷基烷基，苯基，其未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中，Ar，Ar.sup.1和Ar.sup.2，独立于彼此，均为未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中的苯基，或未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中的萘基，且每个芳基均未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中，Q.sup..crclbar.是SbF.sub.6--，AsF.sub.6--或SbF.sub.5OH--在阳离子聚合化合物的热固化中是有价值的固化剂和固化加速剂，优选为环氧树脂。

  公开号：

  US05013814A1

文献信息

• Araliphatic sulfonium and their use
  申请人：Ciba-Geigy Corporation

  公开号：US05247113A1

  公开（公告）日：1993-09-21

  Sulfonium salts of the formulae I to IV ##STR1## in which A is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.4 -C.sub.10 cycloalkylalkyl, phenyl which is unsubstituted or mono- or polysubstituted by C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, phenyl, phenoxy, alkoxycarbonyl having 1-4 C atoms in the alkoxy radical or acyl having 1-12 C atoms, Ar, Ar.sup.1 and Ar.sup.2, independently of one another, are each unsubstituted or mono- or polysubstituted phenyl, or naphthyl which is unsubstituted or mono- or polysubstituted each arylene is an unsubstituted or mono- or polysubstituted phenylene or unsubstituted or mono- or polysubstituted naphthylene and Q.sup..crclbar. is SbF.sub.6.sup.-, AsF.sub.6.sup.- or SbF.sub.5 OH.sup.- are valuable curing agents and curing accelerators in the heat-curing of cationically polymerizable compounds, preferably epoxy resins.

  Sulfonium盐的化学式I至IV ##STR1##其中A是C.sub.1-C.sub.12烷基，C.sub.3-C.sub.8环烷基，C.sub.4-C.sub.10环烷基烷基，苯基未取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，在烷氧基中有1-4个C原子或酰基中有1-12个C原子，Ar，Ar.sup.1和Ar.sup.2，彼此独立地，每个未取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基或酰基取代的苯基，或者naphthyl未取代或经单个或多个取代的每个芳基是未取代或经单个或多个取代的苯基或未取代或经单个或多个取代的naphthylene和Q.sup..crclbar.是SbF.sub.6.sup.-，AsF.sub.6.sup.-或SbF.sub.5 OH.sup.-是在阳离子聚合化合物的热固化中有价值的固化剂和固化促进剂，最好是环氧树脂。
• Araliphatic sulfonium salts and their use
  申请人：Ciba-Geigy Corporation

  公开号：US05013814A1

  公开（公告）日：1991-05-07

  Sulfonium salts of the formulae I to IV ##STR1## in which A is C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.4 -C.sub.10 cycloalkylalkyl, phenyl which is unsubstituted or mono- or polysubstituted by C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, nitro, phenyl, phenoxy, alkoxycarbonyl having 1-4 C atoms in the alkoxy radical or acyl having 1-12 C atoms, Ar, Ar.sup.1 and Ar.sup.2, independently of one another, are each unsubstituted or mono- or polysubstituted phenyl, or naphthyl which is unsubstituted or mono- or polysubstituted each arylene is an unsubstituted or mono- or polysubstituted phenylene or unsubstituted or mono- or polysubstituted naphthylene and Q.sup..crclbar. is SbF.sub.6 --, AsF.sub.6 -- or SbF.sub.5 OH-- are valuable curing agents and curing accelerators in the heat-curing of cationically polymerizable compounds, preferably epoxy resins.

  公式I至IV的磺鎵鹽##STR1##其中A是C.sub.1-C.sub.12烷基，C.sub.3-C.sub.8环烷基，C.sub.4-C.sub.10环烷基烷基，苯基，其未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中，Ar，Ar.sup.1和Ar.sup.2，独立于彼此，均为未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中的苯基，或未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中的萘基，且每个芳基均未经取代或经C.sub.1-C.sub.8烷基，C.sub.1-C.sub.4烷氧基，卤素，硝基，苯基，苯氧基，烷氧羰基在烷氧基基团中具有1-4个C原子或酰基在1-12个C原子中，Q.sup..crclbar.是SbF.sub.6--，AsF.sub.6--或SbF.sub.5OH--在阳离子聚合化合物的热固化中是有价值的固化剂和固化加速剂，优选为环氧树脂。