2-(Prop-1-en-2-yl)-5,6-dihydro-4H-1,3-oxazine | 27888-99-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 甲亚胺酸及其衍生物
• 英文名称: 2-(Prop-1-en-2-yl)-5,6-dihydro-4H-1,3-oxazine
• 英文别名: 2-prop-1-en-2-yl-5,6-dihydro-4H-1,3-oxazine
• CAS: 27888-99-9
• 化学式: C₇H₁₁NO
• 分子量: 125.17
• InChiKey: LLRNYKKVBIRYRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  21.6
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Ungesättigte Esterisocyanate, ein Verfahren zu ihrer Herstellung und ihre Verwendung bei der Herstellung von olefinisch ungesättigten Oligourethanen
  申请人：BAYER AG

  公开号：EP0141295A1

  公开（公告）日：1985-05-15

  Gegebenenfalls als Isomerengemische vorliegende Isocyanatopentyl- bzw. Isocyanatomethyl-cycloalkyl-acrylate oder -methacrylate, ein Verfahren zu ihrer Herstellung durch Umsetzung der ihnen zugrundeliegenden Dihydrooxazine mit Phosgen bei -20 bis +20°C in einem mit Wasser nicht mischbaren Lösungsmittel in Gegenwart einer wäßrigen Lösung einer Base, sowie ihre Verwendung als Ausgangsmaterial bei der Herstellung von olefinisch ungesättigten Oligourethanen durch Umsetzung mit Verbindungen mit mindestens zwei alkoholischen Hydroxylgruppen.

  异氰基戊基或异氰基甲基环烷基丙烯酸酯或甲基丙烯酸酯（可选择以异构体混合物的形式存在），其制备方法是在-20 至 +20°C，在水不溶性溶剂中，在碱的水溶液存在下，使其所基于的二氢噁嗪与光气反应，并将其用作起始原料，通过与至少有两个醇羟基的化合物反应，制备烯烃不饱和低聚氨酯。
• Graft-modified substance, process for preparing same, and thermoplastic resin composition using the graft-modified substance
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0412832A2

  公开（公告）日：1991-02-13

  A modified thermoplastic resin composition superior in adhesive property and mechanical strength is obtained by treating a thermoplastic resin (A) and/or a rubbery substance (B) with at least one kind of a monomer (D) containing at least one functional group selected from the following (D1) to (D6) in the presence of at least one compound as a modifying agent (C) selected from the following (C1) to (C4): C1: a dihydroaromatic compound or a polymer thereof C2: an ether compound C3: a tetrahydroaromatic compound C4: a cyclopentane compound D1: carbonyl group D2: cyclic iminoether group D3: epoxy group D4: hydroxyl group D5: amino group D6: nitrile group

  将热塑性树脂（A）和/或橡胶物质（B）与至少一种含有至少一个选自以下（D1）至（D6）的官能团的单体（D）在至少一种选自以下（C1）至（C4）的化合物作为改性剂（C）的存在下进行处理，可获得粘合性能和机械强度更优的改性热塑性树脂组合物： C1：二氢芳香族化合物或其聚合物 C2：一种醚类化合物 C3：一种四氢芳烃化合物 C4：环戊烷化合物 D1：羰基 D2：环状亚胺醚基团 D3： 环氧基 D4：羟基 D5：氨基 D6: 腈基
• SURFACE ACTIVATION OF THERMOPLASTIC RESIN MOLDING
  申请人：Japan as represented by Director-General, Agency of Industrial Science and Technology

  公开号：EP0465664A1

  公开（公告）日：1992-01-15

  A method of improving the surface characteristics of a molded article made from a composition comprising at least two engineering plastics and a functionalized polyolefin resin containing at least one member selected from among a monomer containing a carboxyl, carboxylic ester, or acid anhydride group, an epoxidized monomer, a hydroxylated monomer, an aminated monomer, an alkenyl cyclic imino ether derivative and a polyfunctional monomer, said composition optionally containing an inorganic filler or a rubbery substance, without detriment to the excellent properties thereof, such as rigidity, impact resistance, heat resistance, dimensional stability and processability, said method comprising applying an ultraviolet radiation with a wavelength of 300 nm or less thereto.

  一种改善模塑制品表面特性的方法，该模塑制品由一种组合物制成，该组合物包含至少两种工程塑料和一种功能化聚烯烃树脂，其中至少含有一种选自以下单体的成员：含有羧基、羧酸酯或酸酐基团的单体、环氧化单体、羟基化单体、胺化单体、烯基环亚胺醚衍生物和多官能团单体、烯基环亚胺醚衍生物和多官能团单体，所述组合物可选择含有无机填料或橡胶物质，但不影响其优异性能，如刚性、抗冲击性、耐热性、尺寸稳定性和可加工性。
• SURFACE TREATMENT OF THERMOPLASTIC RESIN MOLDING
  申请人：Japan as represented by Director-General, Agency of Industrial Science and Technology

  公开号：EP0466930A1

  公开（公告）日：1992-01-22

  A method of improving the surface characteristics of a molded article made from a composition comprising a thermoplastic resin and a functionalized polyolefin resin containing at least one member, selected from among a monomer containing a carboxyl, carboxylic ester, or acid anhydride group, an epoxidized monomer, a hydroxylated monomer, an aminated monomer, an alkenyl cyclic imino ether derivative and a poly-functional monomer, said composition optionally containing an inorganic filler or a rubbery substance, without detriment to the excellent properties thereof, such as rigidity, impact resistance, heat resistance, dimensional stability and processability, said method comprising applying an ultraviolet radiation with a wavelength of 300 nm or less thereto.

  一种改善模塑制品表面特性的方法，该模塑制品由一种组合物制成，该组合物包括热塑性树脂和功能化聚烯烃树脂，其中至少含有一种成员，该成员选自含有羧基、羧酸酯或酸酐基团的单体、环氧化单体、羟基化单体、胺化单体、烯基环亚胺醚衍生物和多官能团单体、烯基环亚胺醚衍生物和多官能团单体，所述组合物可选择含有无机填料或橡胶物质，但不影响其优异性能，如刚性、抗冲击性、耐热性、尺寸稳定性和可加工性，所述方法包括对其进行波长为 300 纳米或以下的紫外线辐射。
• A mat film or sheet and method for preparing the same
  申请人：Nippon Petrochemicals Company, Limited

  公开号：EP0508415A2

  公开（公告）日：1992-10-14

  A polyolefin-based mat film or sheet can be preared from a polymeric blend of the preset invention comprising a propylene polymer or copolymer as component (A) and a specific ethylene-α-olefin copolymer (VLDPE, so-called "super low-density polyethylene") as component (B). The polymeric blend may further comprise a high-pressure radical polymerization process ethylene polymer or copolymer and /or a modified polyolefin-based resin as component (C). The above blend of the present invention may further comprise an inorganic filler as component (D) and a flame retardant as component (E). The mat films or sheets prepared from these polymeric blends are excellent in tensile modulus, flexibility, impact resistance, thermal resistance, laminating properties, flame resistance, chalking resistance, covering power, scratch resistance, and widely used for fabricating adhesive tapes, covers or cases for stationeries, fashion bags, sheets for interior finish work in construction and automobile industries, and sheets for dressing steel plates.

  聚烯烃基垫层薄膜或片材可以由本发明的聚合物混合物预制而成，该聚合物混合物由丙烯聚合物或共聚物作为组分（A）和特定的乙烯-α-烯烃共聚物（VLDPE，即所谓的 "超低密度聚乙烯"）作为组分（B）组成。聚合物混合物可进一步包括高压自由基聚合工艺乙烯聚合物或共聚物和/或改性聚烯烃基树脂作为组分（C）。本发明的上述混合物还可进一步包括作为组分（D）的无机填料和作为组分（E）的阻燃剂。用这些聚合物混合物制备的毡膜或薄片具有优异的拉伸模量、柔韧性、抗冲击性、耐热性、层压性、阻燃性、抗粉化性、遮盖力和抗划伤性，可广泛用于制造胶带、文具封面或包装盒、时装包、建筑和汽车工业内部装修用薄片以及钢板修整用薄片。