[3-N-(2-aminoethyl)aminopropyl]tris(trimethylsiloxy)silane | 17909-29-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: [3-N-(2-aminoethyl)aminopropyl]tris(trimethylsiloxy)silane
• 英文别名: N'-[3-tris(trimethylsilyloxy)silylpropyl]ethane-1,2-diamine
• CAS: 17909-29-4
• 化学式: C₁₄H₄₀N₂O₃Si₄
• 分子量: 396.825
• InChiKey: DZSLWXQEBDTKTQ-UHFFFAOYSA-N

物化性质

• 沸点：
  146-147 °C(Press: 4 Torr)
• 密度：
  0.9036 g/cm3(Temp: 25 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.42
• 重原子数：
  23
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  65.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  [3-N-(2-aminoethyl)aminopropyl]tris(trimethylsiloxy)silane 以 氘代甲醇-d 为溶剂， 生成
  参考文献：
  名称：

  Adsorption and Aggregation Behaviors of Tetrasiloxane-Tailed Gemini Surfactants with (EO)_m Spacers

  摘要：

  Adsorption and aggregation behaviors of novel tetrasiloxane-tailed gemini surfactants N,N'-ditetrasiloxane-N,N'-digluconamide oligo ethylene glycol diglycidyl (Si-m-Si, where m is the number of ethylene glycol of 1, 2, and 3) were investigasted using surface tension, bromophenol blue encapsulation, dynamic light scattering (DLS), and transmission electron microscope (TEM) methods. The static surface tension of the aqueous Si-m-Si solutions measured at the critical aggregate concentration (CAC) was observed to be lower than that of traditional hydrocarbon gemini surfactants. This suggests that these newly synthesized gemini surfactants are capable of forming a closely packed monolayer film at the air/aqueous solution interface. With a combination of DLS data, TEM measurements, and bromophenol blue entrapment studies, formations of vesicles in Si-m-Si solutions appear to occur at a concentration well above the CAC. Moreover, the size of vesicles depended on their m values.

  DOI：

  10.1021/jp310063d
• 作为产物：
  描述：

  三甲基硅醇 、 N-[3-(三甲氧基硅基)丙基]乙二胺 以68.5%的产率得到[3-N-(2-aminoethyl)aminopropyl]tris(trimethylsiloxy)silane
  参考文献：
  名称：

  Transetherification of Organosilicon Amines with Cellosolve and Trimethylsilanol

  摘要：

  Kinetics of transetherification of (3-aminopropyl)trimethoxysilane, [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane and (3-aminopropyl)triethoxysilana with Cellosolve and trimethylsilanol were studied. The example of [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane was used to show that the activation energies of the direct and reverse reactions are equal to each other both in the first and in the second stages, which points to independence of the equilibrium constant on temperature (DeltaHapproximate to0). With methoxysilanes, the rate constant of the reverse reaction in the second stage of the transetherification with Cellosolve is higher than that of the direct reaction.

  DOI：

  10.1023/b:rugc.0000015983.75580.9c

文献信息

• Synthesis and properties of new dicephalic tetrasiloxane surfactants containing sugar
  作者：Dianlong Zhang、Yan Qiao

  DOI：10.1007/s11164-013-1414-7

  日期：2015.5

  A series of dicephalic tetrasiloxane surfactants containing sugar were synthesized. Their structure was confirmed by infrared spectroscopy and 1H nuclear magnetic resonance spectroscopy. Their surface activity and wetting ability on low energy substrates were also investigated. The results showed that the target surfactants exhibited excellent surface activity, which could reduce the surface tension of water to a minimum value of 20–21 mN m−1, and excellent wetting ability, which could completely wet parafilm.

  合成了一系列含糖的双头四硅氧烷表面活性剂。红外光谱和 1H 核磁共振光谱证实了它们的结构。此外，还研究了它们在低能基底上的表面活性和润湿能力。结果表明，目标表面活性剂具有优异的表面活性，可将水的表面张力降至最低值 20-21 mN m-1 ，并且润湿性极佳，可完全润湿对位薄膜。
• Adsorption and Aggregation Behavior of Tetrasiloxane-Tailed Surfactants Containing Oligo(ethylene oxide) Methyl Ether and a Sugar Moiety
  作者：Guoyong Wang、Wenshan Qu、Zhiping Du、Qianyong Cao、Qiuxiao Li

  DOI：10.1021/jp110578u

  日期：2011.4.14

  Three novel amphiphilic dicephalic (double-headed) surfactants containing oligo(ethylene-oxide)methyl-ether and a sugar moiety TGA-m (m = 1, 2, and 3) that incorporate a tetrasiloxane at the terminus of a hydrocarbon chain were designed and synthesized. Their surface activity and aggregation behavior in aqueous solution were systematically investigated by surface tension, dynamic light scattering (DLS), and transmission electron microscopy (TEM) techniques at 298 K. The surface tension measurements provided the critical aggregation concentration (CAC) and the surface tension at the CAC (gamma(cac)). In addition, with application of the Gibbs adsorption isotherm, the maximum surface excess concentration (Gamma(max)) and the minimum surface area/molecule (A(min)) at the air-water interface were estimated. The effect of EO chain length on the surface activity and aggregation behavior was also investigated. It was found that both the gamma(cac) and the CAC were lower than those for reported traditional hydrocarbon surfactants. Aggregates of three surfactants, TGA-m (m = 1, 2, and 3), formed in aqueous solutions could be assigned as spherical vesicles as suggested by analysis using DLS and TEM. Moreover the formation of vesicles can be confirmed by the encapsulation of bromophenol blue. These results indicate that these three surfactants have excellent efficiencies of vesicle formation and surface tension reduction in the aqueous phase.
• Transetherification of Organosilicon Amines with Cellosolve and Trimethylsilanol
  作者：V. A. Kovyazin、A. V. Nikitin、V. M. Kopylov、I. B. Sokol'skaya

  DOI：10.1023/b:rugc.0000015983.75580.9c

  日期：2003.9

  Kinetics of transetherification of (3-aminopropyl)trimethoxysilane, [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane and (3-aminopropyl)triethoxysilana with Cellosolve and trimethylsilanol were studied. The example of [3-N-(2-aminoethyl)aminopropyl]trimethoxysilane was used to show that the activation energies of the direct and reverse reactions are equal to each other both in the first and in the second stages, which points to independence of the equilibrium constant on temperature (DeltaHapproximate to0). With methoxysilanes, the rate constant of the reverse reaction in the second stage of the transetherification with Cellosolve is higher than that of the direct reaction.
• Adsorption and Aggregation Behaviors of Tetrasiloxane-Tailed Gemini Surfactants with (EO)_<i>m</i> Spacers
  作者：Wang Guoyong、Qu Wenshan、Du Zhiping、Wang Wanxu、Li Qiuxiao

  DOI：10.1021/jp310063d

  日期：2013.3.21

  Adsorption and aggregation behaviors of novel tetrasiloxane-tailed gemini surfactants N,N'-ditetrasiloxane-N,N'-digluconamide oligo ethylene glycol diglycidyl (Si-m-Si, where m is the number of ethylene glycol of 1, 2, and 3) were investigasted using surface tension, bromophenol blue encapsulation, dynamic light scattering (DLS), and transmission electron microscope (TEM) methods. The static surface tension of the aqueous Si-m-Si solutions measured at the critical aggregate concentration (CAC) was observed to be lower than that of traditional hydrocarbon gemini surfactants. This suggests that these newly synthesized gemini surfactants are capable of forming a closely packed monolayer film at the air/aqueous solution interface. With a combination of DLS data, TEM measurements, and bromophenol blue entrapment studies, formations of vesicles in Si-m-Si solutions appear to occur at a concentration well above the CAC. Moreover, the size of vesicles depended on their m values.