9-oxo-9H-thioxanthene-2-carboxylic acid 2-hydroxy-3-(2-methyl-acryloyl oxy)-propyl ester | 736141-94-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: 9-oxo-9H-thioxanthene-2-carboxylic acid 2-hydroxy-3-(2-methyl-acryloyl oxy)-propyl ester
• 英文别名: [2-hydroxy-3-(2-methylprop-2-enoyloxy)propyl] 9-oxothioxanthene-2-carboxylate
• CAS: 736141-94-9
• 化学式: C₂₁H₁₈O₆S
• 分子量: 398.436
• InChiKey: YHYJNWOARJADMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  28
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  115
• 氢给体数：
  1
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-碘苯甲酸 在 2,6-二叔丁基-4-甲基苯酚 、 硫酸 、 四丁基溴化铵 、 铜 、 sodium hydroxide 、 锌 作用下， 以 N,N-二甲基乙酰胺 、 硫酸 、 水 、 乙腈 为溶剂， 反应 47.0h， 生成 9-oxo-9H-thioxanthene-2-carboxylic acid 2-hydroxy-3-(2-methyl-acryloyl oxy)-propyl ester
  参考文献：
  名称：

  Radiation curable compositions

  摘要：

  根据公式(I)的可聚合的Norrish II型光引发剂：含有公式(I)的可聚合Norrish II型光引发剂的辐射固化组合物和喷墨墨水表现出与辐射固化组合物和喷墨墨水的更好兼容性和溶解性，并且在固化后显示出光引发剂及其残留物的可萃取量较低。

  公开号：

  US08536217B2

文献信息

• RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110159203A1

  公开（公告）日：2011-06-30

  A polymerizable Norrish Type II photoinitiator according to Formula (I): . Radiation curable compositions and inkjet inks containing the polymerizable Norrish Type II photoinitiator of Formula (I) exhibit improved compatibility with and solubility in radiation curable compositions and inkjet inks, and exhibit low extractable amounts of the photoinitiator and its residues after curing.

  根据公式（I）的聚合性诺里希II型光引发剂： . 含有公式（I）的聚合性诺里希II型光引发剂的辐射固化组合物和喷墨油墨在辐射固化组合物和喷墨油墨中表现出优异的相容性和溶解性，并且在固化后光引发剂及其残留物的可提取量较低。
• Polymerizable photoinitiators and radiation curable compositions
  申请人：AGFA NV

  公开号：EP2199273B1

  公开（公告）日：2018-02-21
• POLYMERIZABLE PHOTOINITIATORS AND RADIATION CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110224324A1

  公开（公告）日：2011-09-15

  A polymerizable photoinitiator is represented by Formula (I): wherein R1, R2 and R3 are independently selected from the group consisting of a hydrogen, an optionally substituted alkyl group and an optionally substituted aryl group or R1 and R3 represent the necessary atoms to form a five to eight membered ring; p, w, y and z are all integers with y representing a value 1 to 6; p representing the sum of w and z; p representing a value of 1 to 6; w=1 to (p−z) and z=0 to (p−w); L represents an optionally substituted (p+y)-valent linking group comprising 1 to 14 carbon atoms; A represents a radically polymerizable group selected from the group consisting of an acrylate group, a methacrylate group, a styrene group, an acryl amide group, a methacryl amide group, a maleate group, a fumarate group, an itaconate group, a vinyl ether group, an allyl ether group, an allyl ester group and a vinyl ester group; and X represents a photoinitiating moiety including at least one group capable of initiating a free radical polymerization reaction upon exposure to actinic radiation.
• US8492452B2
  申请人：——

  公开号：US8492452B2

  公开（公告）日：2013-07-23
• US8536217B2
  申请人：——

  公开号：US8536217B2

  公开（公告）日：2013-09-17