4-acryloyloxy-2,2,6,6-tetramethylpiperidine | 26275-87-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 4-acryloyloxy-2,2,6,6-tetramethylpiperidine
• 英文别名: 2,2,6,6-tetramethylpiperidin-4-yl acrylate；2,2,6,6-tetramethyl-4-piperidinyl acrylate；2,2,6,6-Tetramethylpiperid-4-yl acrylate；4-Acryloyloxy-2,2,6,6-tetramethyl-piperidin；2,2,6,6-Tetramethyl-4-piperidyl acrylate；(2,2,6,6-tetramethylpiperidin-4-yl) prop-2-enoate
• CAS: 26275-87-6
• 化学式: C₁₂H₂₁NO₂
• 分子量: 211.304
• InChiKey: BUFCQVRLKYIQJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-acryloyloxy-2,2,6,6-tetramethylpiperidine 、 丙炔酸乙酯 以 乙醇 为溶剂， 生成 1-(β-methoxycarbonylvinyl)-2,2,6,6-tetramethyl-4-piperidinyl acrylate
  参考文献：
  名称：

  N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine

  摘要：

  N-(.beta.-羰基和.beta.-氰基乙烯基)-2,2,6,6-四甲基哌啶衍生物的结构式I ##STR1##其中R.sup.1为COOR.sup.3、COR.sup.4、CONR.sup.4 R.sup.5或CN，R.sup.2具有R.sup.1的含义或是C.sub.1 -C.sub.12 -烷基或氢，R.sup.3为氢、C.sub.1 -C.sub.8 -烷基、C.sub.5 -C.sub.8 -环烷基、C.sub.3 -C.sub.5 -烯基或苯基，可由C.sub.1 -C.sub.4 -烷基、C.sub.1 -C.sub.4 -烷氧基、C.sub.1 -C.sub.4 -烷氧羰基、卤素、羟基、苯氧基、苯基、甲苯基或二甲苯基单取代至三取代，R.sup.4和R.sup.5分别为氢、C.sub.1 -C.sub.12 -烷基、C.sub.5 -C.sub.8 -环烷基或苯基，可由C.sub.1 -C.sub.4 -烷基、C.sub.1 -C.sub.4 -烷氧基、C.sub.1 -C.sub.4 -烷氧羰基、卤素、羟基、苯氧基、苯基、甲苯基或二甲苯基单取代至三取代，n为1-4，X和A对于每个n已在说明书中定义。

  公开号：

  US05434202A1
• 作为产物：
  描述：

  四甲基哌啶醇 、 丙烯酸酐 在 4-二甲氨基吡啶 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以30%的产率得到4-acryloyloxy-2,2,6,6-tetramethylpiperidine
  参考文献：
  名称：

  通过RAFT聚合和其他受控自由基技术聚合游离的带有仲胺的单体

  摘要：

  这项工作描述了通过不同的受控自由基聚合技术（ATRP，RAFT，NMP）聚合带有游离仲胺的单体2,2,6,6-四甲基哌啶-4-甲基丙烯酸甲酯（TMPMA）。特别是，可逆的加成-断裂链转移（RAFT）聚合可以在高转化率下实现良好的控制，并且多分散指数低于1.3，从而可以制备定义明确的聚合物。显着地，带有仲胺的甲基丙烯酸酯单体的聚合不受通常引起RAFT试剂降解的游离胺的存在的阻碍。随后聚合物的氧化产生了多自由基聚（2,2,6,6-四甲基哌啶基氧基-4-甲基丙烯酸丁酯），它代表了催化以及现代电池中的一种有价值的材料。10,000–20,000 g / mol的M n）用于通过喷墨印刷制造清晰的，带有自由基的聚合物薄膜。©2012 Wiley Periodicals，Inc. J Polym Sci A部分：Polym Chem，2012年

  DOI：

  10.1002/pola.25907

文献信息

• Process for the preparation of 1-diorganocarbamoyl-polyalkylpiperidines
  申请人：Ciba-Geigy Corporation

  公开号：US04590268A1

  公开（公告）日：1986-05-20

  Compounds containing a group of the formula I ##STR1## in which R is H or C.sub.1 -C.sub.4 -alkyl, R.sup.1 is H, CN, an acyloxy group or a free valency and R.sup.2 and R.sup.3 are organic radicals can be prepared in a simple manner from the corresponding compounds containing a group of the formula Ia ##STR2## by stepwise reaction with phosgene and a secondary amine R.sup.2 --NH--R.sup.3 in the presence of a molar amount of a base. The N-diorganocarbamoyl compounds containing the group I are outstanding light stabilizers, in particular for organic polymers. They can be converted by secondary reactions into other compounds which contain the group I and which are not accessible by direct phosgenation. Many of the products thus obtainable by phosgenation or conversion are novel compounds.

  含有公式I（##STR1##）的化合物的R是H或C.sub.1-C.sub.4-烷基，R.sup.1是H，CN，一个酰氧基团或一个自由价，R.sup.2和R.sup.3是有机基团，可以通过与光气（phosgene）和次级胺R.sup.2 --NH--R.sup.3以摩尔量的碱存在下逐步反应，从相应的含有公式Ia（##STR2##）的化合物中以简单方式制备。含有I基团的N-二有机碳酰胺化合物是杰出的光稳定剂，特别是对于有机聚合物。它们可以通过次级反应转化为其他含有I基团的化合物，这些化合物通过直接光气化无法获得。通过光气化或转化获得的许多产品都是新颖的化合物。
• MODIFIED ZNO NANOPARTICLES
  申请人：Riggs Richard

  公开号：US20120097068A1

  公开（公告）日：2012-04-26

  Process for the preparation of modified zinc oxide nanoparticles, which comprises reacting zinc oxide nanoparticles, which are dissolved in a solvent, in the presence of ammonia or amines with a tetraalkyl orthosilicate and optionally with an organosilane, with the proviso that the reaction takes place at a content of less than 5% by weight of water, based on the total amount of solvent and water. Modified zinc oxide nanoparticles which have Si—O-alkyl groups and are soluble in organic solvents, obtainable by this process for the preparation. Liquid or solid formulations which comprise modified ZnO nanoparticles. Inanimate organic materials, for example plastics or coatings, which comprise modified ZnO nanoparticles. Method of stabilizing inanimate organic materials against the effect of light, free radicals or heat, where modified ZnO nanoparticles, which optionally comprise UV absorbers and/or stabilizers as further additives, are added to the materials.

  制备改性氧化锌纳米颗粒的过程包括在溶剂中溶解的氧化锌纳米颗粒与氨或胺在场的情况下，与四烷基正硅酸酯和可选的有机硅烷反应，但反应需在溶剂和水的总量中水含量低于5%的条件下进行。通过该制备过程可获得具有Si-O-烷基基团且可溶于有机溶剂的改性氧化锌纳米颗粒。包含改性ZnO纳米颗粒的液体或固体配方。包含改性ZnO纳米颗粒的无机有机材料，例如塑料或涂料。一种稳定无机有机材料抵抗光线、自由基或热效应的方法，其中将改性ZnO纳米颗粒添加到材料中，这些纳米颗粒可包含紫外吸收剂和/或稳定剂作为进一步添加剂。
• Stabilization of iodine biocides
  申请人：Uhr Hermann

  公开号：US20090036555A1

  公开（公告）日：2009-02-05

  2-(2-Hydroxyphenyl)benzotriazoles are outstandingly suitable for stabilizing iodine-containing biocides in industrial materials, more particularly in paints based on alkyd resin.

  2-(2-羟基苯基)苯并三唑在工业材料中稳定含碘生物杀菌剂方面特别适用，尤其是在基于醇酸树脂的油性漆中。
• COPOLYMERS INCLUDING A TRIAZINE GROUP AND COMPOSITIONS INCLUDING THEM
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20170198119A1

  公开（公告）日：2017-07-13

  An ultraviolet light-absorbing oligomer that includes a first divalent unit represented by formula (I): and a second divalent unit represented by formula (II): Each R 1 is independently hydrogen or methyl; V is O or NH; X is bond or X is alkylene or alkyleneoxy group having from 1 to 10 carbon atoms and optionally interrupted by one or more —O— groups and optionally substituted by a hydroxyl group; and R2 is alkyl having from 1 to 22 carbon atoms. Compositions that include fluoropolymers and the oligomers are disclosed. The composition can be an extruded film. Compositions that include pressure sensitive adhesives and these oligomers are disclosed.

  一种包括由式(I)表示的第一二价单元和由式(II)表示的第二二价单元的紫外光吸收寡聚物：每个R1独立地是氢或甲基；V为O或NH；X为键或X为含有1至10个碳原子的烷基或烷氧基团，并且可以被一个或多个—O—基团中断，并且可以被一个羟基取代；R2是具有1到22个碳原子的烷基。公开了包括氟聚合物和这些寡聚物的组合物。该组合物可以是挤压薄膜。公开了包括压敏胶粘剂和这些寡聚物的组合物。
• STABLE COMPOSITIONS OF THIABENDAZOLE AND IODINE-CONTAINING FUNGICIDES
  申请人：LANXESS Deutschland GmbH

  公开号：US20150051279A1

  公开（公告）日：2015-02-19

  The present invention relates to stable compositions for the fungicidal equipment of thermoplastic polymers, in particular PVC, comprising thiabendazole, at least one iodine-containing fungicide and at least one epoxide and optionally further fungicidally active compounds, and also to methods for preparing these formulations and to uses thereof for the protection of thermoplastic polymers against attack and destruction by microorganisms. Moreover, the invention relates to mold-resistant PVC materials equipped with the compositions according to the invention.

  本发明涉及用于热塑性聚合物的抗真菌设备的稳定组合物，特别是PVC，包括噻苯唑、至少一种含碘真菌剂和至少一种环氧化物，以及可选的其他具有抗真菌活性的化合物，以及制备这些配方的方法和用途，用于保护热塑性聚合物免受微生物的侵害和破坏。此外，该发明涉及配备了根据本发明的组合物的耐霉PVC材料。