4-(phenylthio)naphthalen-1-ol | 19133-53-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-(phenylthio)naphthalen-1-ol
• 英文别名: 4-phenylthio-1-naphtol；4-Phenylthio-naphthol-(1)；4-Phenylsulfanylnaphthalen-1-ol
• CAS: 19133-53-0
• 化学式: C₁₆H₁₂OS
• 分子量: 252.337
• InChiKey: QOUZSBCXVDCQAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-(phenylthio)naphthalen-1-ol 在 potassium nitrososulfonate 作用下， 以 甲醇 为溶剂， 生成 4-Phenylmercapto-naphthochinon-(1,2)
  参考文献：
  名称：

  Ukai,S.; Hirose,K., Chemical and pharmaceutical bulletin, 1968, vol. 16, # 4, p. 606 - 612

  摘要：

  DOI：
• 作为产物：
  描述：

  Methyl-phenyl-4-hydroxy-naphthyl-sulfonium-perchlorat 以 吡啶 为溶剂， 生成 4-(phenylthio)naphthalen-1-ol
  参考文献：
  名称：

  Ukai,S.; Hirose,K., Chemical and pharmaceutical bulletin, 1968, vol. 16, # 4, p. 606 - 612

  摘要：

  DOI：

文献信息

• Copper-Catalyzed Three-Component One-Pot Synthesis of Aryl Sulfides with Sulfur Powder under Aqueous Conditions
  作者：Fuhong Xiao、Shuqing Chen、Cheng Li、Huawen Huang、Guo-Jun Deng

  DOI：10.1002/adsc.201600642

  日期：2016.12.7

  A copper‐catalyzed three‐component (arenes, iodohydrocarbon, and sulfur powder) synthesis of substituted aryl sulfides has been developed. Water is used as the green solvent in a simple and environmentally friendly procedure. Various functional groups attached to the substrates were well tolerated in this process to afford the corresponding products in moderate to good yields.

  已开发了铜催化的三组分（芳烃，碘代烃和硫粉）合成取代的芳基硫化物。在简单且环保的过程中，水被用作绿色溶剂。在该过程中，与底物相连的各种官能团均具有良好的耐受性，从而以中等至良好的产率提供了相应的产物。
• TBATB mediated debenzylative cross-coupling of aryl benzyl sulfides with electron rich compounds: synthesis of diaryl sulfides
  作者：Sukanya Hazarika、Prasanta Gogoi、Pranjit Barman

  DOI：10.1039/c5ra00677e

  日期：——

  An efficient TBATB mediated debenzylative cross coupling of aryl benzyl sulfides with electron rich compounds provides diaryl sulfides in moderate to excellent yield. The salient features of the present protocol are simplicity, high efficiency and compatibility of the reaction with various electron rich compounds.

  芳基苄基硫醚与富电子化合物的高效TBATB介导的脱苄基交叉偶联以中等至优异的产率提供了二芳基硫醚。本方案的显着特征是简单，高效和反应与各种富电子化合物的相容性。
• Compositions for repelling crawling insects
  申请人：——

  公开号：US20020094993A1

  公开（公告）日：2002-07-18

  The present invention relates to novel compositions, comprising a repellent and an additive, where the additive is selected from the group consisting of phenol, benzaldehyde, benzoic acid or derivatives thereof and is present in a ratio of from 10:100 to 200:100% by weight to the repellent, and to their use for repelling crawling harmful insects, in particular ants or cockroaches.

  本发明涉及新型组合物，包括一种驱虫剂和一种添加剂，其中所述添加剂选自苯酚、苯甲醛、苯甲酸或其衍生物组成的群体，并以10:100至200:100％重量的比例存在于驱虫剂中，以及其用于驱赶爬行有害昆虫，特别是蚂蚁或蟑螂。
• Benati, Luisa; Montevecchi, P. Carlo; Spagnolo, Piero, Journal of the Chemical Society. Perkin transactions I, 1985, p. 2261 - 2266
  作者：Benati, Luisa、Montevecchi, P. Carlo、Spagnolo, Piero

  DOI：——

  日期：——
• Silver Ion Mediated In Situ Synthesis of Mixed Diaryl Sulfides from Diaryl Disulfides
  作者：Pranjit Barman、Prasanta Gogoi、Sandhya Gogoi、Mukul Kalita

  DOI：10.1055/s-0032-1318482

  日期：——

  The AgNO3-mediated in situ scission of aromatic disulfides in the presence of electron-rich aromatic compounds results in the efficient synthesis of diaryl sulfides. Key features of this new methodology are high yields of aromatic and heteroaromatic sulfides, mild reaction conditions, simplicity, simple workup, and avoiding foul-smelling reactants like thiols.