(E)-methyl 2-methyl-5-trimethoxysilyl-2-hexenoate | 1433725-00-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (E)-methyl 2-methyl-5-trimethoxysilyl-2-hexenoate
• 英文别名: methyl (E)-2-methyl-5-trimethoxysilylpent-2-enoate
• CAS: 1433725-00-8
• 化学式: C₁₀H₂₀O₅Si
• 分子量: 248.351
• InChiKey: XGTGWVMABZEMHY-VQHVLOKHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.37
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  54
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  乙烯基三甲氧基硅烷 、 甲基丙烯酸甲酯 在 [Ru(η⁶-naphthalene)(rac-η⁴-bicyclo[3.3.1]-nona-2,6-diene)] 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 生成 (E)-methyl 2-methyl-5-trimethoxysilyl-2-hexenoate 、 (Z)-methyl 2-methyl-5-trimethoxysilyl-2-hexenoate 、 (Z)-methyl 2-methyl-4-trimethoxysilyl-2-pentenoate
  参考文献：
  名称：

  Asymmetric Cross-Dimerization between Methyl Methacrylate and Substituted Alkene by Ru(0)–Bicyclononadiene Complex

  摘要：

  New Ru(0)-naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,5)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer In 74% yield In 80% ee.

  DOI：

  10.1021/ol400963d

文献信息

• Asymmetric Cross-Dimerization between Methyl Methacrylate and Substituted Alkene by Ru(0)–Bicyclononadiene Complex
  作者：Yuki Hiroi、Nobuyuki Komine、Sanshiro Komiya、Masafumi Hirano

  DOI：10.1021/ol400963d

  日期：2013.5.17

  New Ru(0)-naphthalene complexes containing a bicyclononadiene ligand catalyze the linear cross-dimerization between methyl methacrylate and substituted alkenes by an oxidative coupling mechanism. The chiral (S,S)-2-methylbicyclo[3.3.1]nona-2,6-diene complex (S,5)-1b catalyzes asymmetric linear cross-dimerization between methyl methacrylate and 2,5-dihydrofuran to give the cross-dimer In 74% yield In 80% ee.