3-(allyloxy)methyl-3-methyloxetane | 10196-40-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环丁烷
• 英文名称: 3-(allyloxy)methyl-3-methyloxetane
• 英文别名: 3-allyloxymethyl-3-methyl-oxetane；3-Methyl-3-allyloxymethyl-oxacyclobutan；3-(Allyloxymethyl)-3-methyloxetane；3-methyl-3-(prop-2-enoxymethyl)oxetane
• CAS: 10196-40-4
• 化学式: C₈H₁₄O₂
• 分子量: 142.198
• InChiKey: CDGGFIMPNCEPBA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-甲基-3-羟甲基氧杂环丁烷 、 3-溴丙烯 在 sodium hydroxide 、 四丁基氯化铵 作用下， 以 正己烷 为溶剂， 生成 3-(allyloxy)methyl-3-methyloxetane
  参考文献：
  名称：

  Fluorinated oxetane derivatives and production process thereof

  摘要：

  一种制备式(I)化合物的方法，包括将RfI的自由基加成到3-(烯丙氧基)甲基-3-烷氧基氧杂环戊烷(1)中，其中R为C1-3烷基，Rf为C1-18线性或支链氟烷基。式(I)化合物可用作制备各种含氟功能材料的中间体。

  公开号：

  US20030065199A1

文献信息

• 3-methyl oxetanemethanol derivatives and their use in perfume compositions
  申请人：International Flavors & Fragrances Inc.

  公开号：US07265231B2

  公开（公告）日：2007-09-04

  The present invention relates to new 3-methyl oxetanemethanol derivatives and their use as fragrance chemicals suitable for incorporation in fine fragrances, cosmetics, toiletries and related applications.

  本发明涉及新的3-甲基氧杂环甲醇衍生物及其作为适用于精细香水、化妆品、洗涤用品及相关应用的香料化学品的用途。
• 3-Methyl Oxetanemethanol Derivatives and Their Use in Perfume Compositions
  申请人：Levorse T. Anthony

  公开号：US20070265180A1

  公开（公告）日：2007-11-15

  The present invention relates to new 3-methyl oxetanemethanol derivatives and their use as fragrance chemicals suitable for incorporation in fine fragrances, cosmetics, toiletries and related applications.

  本发明涉及新的3-甲基氧杂环甲醇衍生物及其用作适合用于精细香料、化妆品、洗涤用品及相关应用的香料化学品。
• Photo-curable composition and photo-cured product
  申请人：JSR Corporation

  公开号：EP0965618A1

  公开（公告）日：1999-12-22

  Disclosed is a photo-curable composition comprising the following components (A) to (C): (A) hydrolyzable silane compound represented by the general formula (1) or a hydrolyzate thereof: (R1)pSi(X)4-p (1) wherein R1 is a non-hydrolyzable organic group having 1 to 12 carbon atoms, X is a hydrolyzable group, and p is an integer of 0 to 3; (B) photo acid generator; and (C) dehydrating agent. By such constitution, it is possible to provide a photo-curable composition which has a rapid photo-curable rate, is excellent in characteristics such as storage stability, heat resistance, weather-ability, scratch resistance and the like, and is applicable to base materials having low heat resistance such as plastics, as well as a cured product obtained therefrom.

  本发明公开了一种光固化组合物，该组合物包含以下成分(A)至(C)：(A)通式(1)表示的可水解硅烷化合物或其水解物：(R1)pSi(X)4-p (1)，其中 R1 是具有 1 至 12 个碳原子的不可水解有机基团，X 是可水解基团，p 是 0 至 3 的整数；(B)光酸发生器；以及(C)脱水剂。通过这样的构成，可以提供一种光固化组合物，它具有快速的光固化速率，在贮存稳定性、耐热性、耐候性、抗划伤性等方面具有优异的特性，适用于塑料等耐热性较低的基底材料，以及由此获得的固化产品。
• FLUORINATED OXETANE DERIVATIVES AND PRODUCTION PROCESS THEREOF
  申请人：Daikin Industries, Ltd.

  公开号：EP1270563A1

  公开（公告）日：2003-01-02

  A process for preparing compounds of formula (I) comprising radical addition of RfI to 3-(allyloxy)methyl-3-alkyloxetane (1) wherein R is C1-3 alkyl and Rf is C1-18 linear or branched fluoroalkyl. The compounds of formula (I) are useful as intermediates for preparing various fluorine-containing functional materials.

  一种制备式 (I) 化合物的工艺，包括 RfI 与 3-(烯丙氧基)甲基-3-烷氧基乙烷 (1) 的自由基加成反应 其中 R 为 C1-3 烷基，Rf 为 C1-18 直链或支链氟烷基。 式 (I) 化合物可用作制备各种含氟功能材料的中间体。
• POLYCARBOSILANE AND METHOD FOR PRODUCING SAME
  申请人：TOAGOSEI CO., LTD.

  公开号：EP1867674A1

  公开（公告）日：2007-12-19

  The objective of the present invention is to provide a polycarbosilane having excellent solubility in common organic solvents and a method for production thereof. The polycarbosilane of the present invention is a polymer which is represented by the following general formula (1) and has an oxetanyl group in a side chain. R1 is an alkyl group having no oxetanyl groups, aryl group having no oxetanyl groups, or an organic group having an oxetanyl group, R2 is an organic group having an oxetanyl group, R3 is an alkylene group, an arylene group, or an aralkylene group, and n is an integer of 5 to 200.

  本发明的目的是提供一种在普通有机溶剂中具有优异溶解性的聚碳硅烷及其生产方法。本发明的聚碳硅烷是由以下通式（1）表示的聚合物，其侧链中有一个氧杂环丁基。R1 是没有氧硫杂环丁烷基团的烷基、没有氧硫杂环丁烷基团的芳基或具有氧硫杂环丁烷基团的有机基团，R2 是具有氧硫杂环丁烷基团的有机基团，R3 是亚烷基、亚芳基或亚芳烷基，n 是 5 至 200 的整数。