4-(3-(pyrrol-1-yl)propionylamino)-2,2,6,6-tetramethylpiperidin-1-yloxy | 320350-40-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 4-(3-(pyrrol-1-yl)propionylamino)-2,2,6,6-tetramethylpiperidin-1-yloxy
• CAS: 320350-40-1
• 化学式: C₁₆H₂₆N₃O₂
• 分子量: 292.401
• InChiKey: KTEAHYHBBXDXIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  21
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-2-氰乙基吡咯 在 氢氧化钾 、 N,N'-二环己基碳二亚胺 作用下， 以 水 、 乙酸乙酯 为溶剂， 反应 1.0h， 生成 4-(3-(pyrrol-1-yl)propionylamino)-2,2,6,6-tetramethylpiperidin-1-yloxy
  参考文献：
  名称：

  New Approach to Rapid Generation and Screening of Diverse Catalytic Materials on Electrode Surfaces

  摘要：

  This paper describes a general approach to rapid generation and screening of catalytic materials on electrode surfaces. The properties of the corresponding polymers, including catalytic performance, can be modulated by varying the monomer feed ratios, monomer concentrations, and applied polymerization potential, Thus, the generation of the polymeric TEMPO (2,2,6,6-tetramethylpiperidin-1-yloxy) catalysts was performed by electrochemical copolymerization of 2,2'-bithiophene with the TEMPO catalyst precursors containing pyrrole side chains. A library of catalyst films was obtained over a wide range of bithiophene/pyrrole ratios upon repeated scanning of the applied potential from +0.5 to +1.4 V (vs Ag/AgCl). The resulting catalyst films were utilized in both chemical and electrochemical oxidation of primary alcohols to aldehydes.

  DOI：

  10.1021/ja002334u

文献信息

• New Approach to Rapid Generation and Screening of Diverse Catalytic Materials on Electrode Surfaces
  作者：Tung Siu、Shahla Yekta、Andrei K. Yudin

  DOI：10.1021/ja002334u

  日期：2000.12.1

  This paper describes a general approach to rapid generation and screening of catalytic materials on electrode surfaces. The properties of the corresponding polymers, including catalytic performance, can be modulated by varying the monomer feed ratios, monomer concentrations, and applied polymerization potential, Thus, the generation of the polymeric TEMPO (2,2,6,6-tetramethylpiperidin-1-yloxy) catalysts was performed by electrochemical copolymerization of 2,2'-bithiophene with the TEMPO catalyst precursors containing pyrrole side chains. A library of catalyst films was obtained over a wide range of bithiophene/pyrrole ratios upon repeated scanning of the applied potential from +0.5 to +1.4 V (vs Ag/AgCl). The resulting catalyst films were utilized in both chemical and electrochemical oxidation of primary alcohols to aldehydes.