2,6-diamino-3,7-dicyanobenzo<1,2-b:4,5-b'>difuran

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 2,6-diamino-3,7-dicyanobenzo<1,2-b:4,5-b'>difuran
• 英文别名: 2,6-diamino-benzo[1,2-b;4,5-b']difuran-3,7-dicarbonitrile；2,6-diamino-3,7-dicyano-benzo[1,2-b:4,5-b']difuran；2,6-Diaminofuro[2,3-f]benzofuran-3,7-dicarbonitrile；2,6-diaminofuro[2,3-f][1]benzofuran-3,7-dicarbonitrile
• 化学式: C₁₂H₆N₄O₂
• 分子量: 238.205
• InChiKey: MEIAFCFJXTVGOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  126
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,6-diamino-3,7-dicyanobenzo<1,2-b:4,5-b'>difuran 、 3,4-bis(hexyloxy)thiophene-2-carboxaldehyde 在 三氟乙酸 作用下， 以 氯仿 为溶剂， 反应 10.0h， 以58%的产率得到2,6-N-di[(3’,4’-dihexyloxythiophene-2’-yl)carboxylimino]-benzo[1,2-b:4,5-b’]difuran-3,7-di-carbonitrile
  参考文献：
  名称：

  Extended benzodifuran–thiophene systems connected with azomethine junctions: synthesis and electronic properties

  摘要：

  The synthesis of extended benzodifuran-thiophene systems connected by azomethine junctions is described. The electronic properties of these systems, studied by UV-vis spectroscopy and cyclic voltammetry, are discussed in relation with the electron withdrawing groups grafted on the benzodifuran unit and the electron donor ability of the thiophene moieties. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2015.07.030
• 作为产物：
  描述：

  对苯二酚 、 丙二腈 以 水 为溶剂， 以92%的产率得到2,6-diamino-3,7-dicyanobenzo<1,2-b:4,5-b'>difuran
  参考文献：
  名称：

  Electro-Organic Synthesis of 2-Amino-3-cyano-benzofuran Derivatives Using Hydroquinones and Malononitrile

  摘要：

  [image omitted] In this work, electrochemical oxidation of hydroquinones has been studied in the presence of malononitrile as a nucleophile in aqueous solution using cyclic voltammetry and controlled potential coulometry. The results indicate that the quinones derived from hydroquinones participate in Michael addition and then intramolecular nucleophilic addition to yield benzofuran derivatives. The electrochemical synthesis of these new 2-amino-3-cyano-benzofuran derivatives has been performed successfully at a carbon-rod electrode in an undivided cell in good to excellent yields at room temperature.

  DOI：

  10.1080/00397911003629424

文献信息

• Napier, Russell J.; Shand, Charles A.; Thomson, Ronald H., Journal of Chemical Research, Miniprint, 1983, # 2, p. 480 - 497
  作者：Napier, Russell J.、Shand, Charles A.、Thomson, Ronald H.、Cheng, Lubai、Griffiths, John、Greenhalgh, Colin W.

  DOI：——

  日期：——