2,7-Dichloroxanthen-9-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并吡喃
• 英文名称: 2,7-Dichloroxanthen-9-one
• 化学式: C₁₃H₆Cl₂O₂
• 分子量: 265.09
• InChiKey: UDNXCJZLOZSVSS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,7-dichloro-9-(chloromethylidene)xanthene 以0%的产率得到
  参考文献：
  名称：

  Martin Ned H., Clary Robert T., Fudala Louise D., Hyde Raymond G., Jackso+, J. E. Mitchell Sci. Soc., 108 (1992) N 3, S 102-110

  摘要：

  DOI：

文献信息

• ORGANIC LIGHT-EMITTING DEVICE
  申请人：Horiuchi Takayuki

  公开号：US20130037791A1

  公开（公告）日：2013-02-14

  An organic light-emitting device that achieves highly efficient emission and low-voltage operation is provided. The organic light-emitting device contains a 9H-xanthen-9-one derivative.

  提供了一种实现高效发射和低电压操作的有机发光器件。该有机发光器件包含9H-黄色素-9-酮衍生物。
• Photosensitive compositions containing carbonylic halides as activators
  申请人：Dynachem Corporation

  公开号：EP0005379A2

  公开（公告）日：1979-11-14

  Compositions containing a polymerizable, curable or crosslinkable component. a photoinitiator, a colorformer capable of changing color upon contact with a suitable activator and a latent activator containing an organic halide will become insoluble and change color under the influence of actinic radiation. The organic halide is a carbonylic compound such as an aliphatic or cycloaliphatic ketone or an ester or amide of a dicarboxylic acid. The compositions are useful to make resists used in the electronics industry to manufacture printed circuits.

  含有可聚合、可固化或可交联成分、光引发剂、与适当活化剂接触后能变色的着色剂和含有有机卤化物的潜在活化剂的组合物，在光辐射的影响下会变得不溶解并变色。 有机卤化物是一种羰基化合物，如脂肪族或环脂族酮或二羧酸的酯或酰胺。 这些组合物可用于制造电子工业中用于制造印刷电路的抗蚀剂。
• FLUORESCENT PROBE
  申请人：Nagano, Tetsuo

  公开号：EP1553408A1

  公开（公告）日：2005-07-13

  A fluorescent probe which is represented by the following formula (I): (wherein, R1 and R2 represent hydrogen atom, or a substituent for trapping proton, a metal ion, or an active oxygen species, or the like; R3 represents a monovalent substituent; R4 and R5 represent hydrogen atom or a halogen atom; R6 represents hydrogen atom, an alkylcarbonyl group, or an alkylcarbonyloxymethyl group, provided that a combination of R1, R2, and R3 provides (1)substantially high electron density of the benzene ring to which said groups bind, so that the compound represented by the formula (I) is substantially no fluorescent before the trapping of proton, or the like, and (2) substantially reduced electron density of the benzene ring to which said groups bind, so that a compound after the trapping, which is derived from the compound represented by the formula (I) is substantially highly fluorescent after the trapping of proton or the like). A fluorescent probe having an excellent fluorescence property is provided.

  由下式（I）表示的荧光探针： (其中，R1 和 R2 代表氢原子，或用于捕获质子的取代基、金属离子或活性氧等；R3 代表一价取代基；R4 和 R5 代表氢原子或卤素原子；R6 代表氢原子、烷基羰基或烷基羰氧甲基，条件是 R1、R2 和 R3 的组合可提供 (1)与所述基团结合的苯环的高电子密度，从而使式 (I) 所代表的化合物在捕获质子之前基本上没有荧光、或类似物，以及 (2) 所述基团所结合的苯环的电子密度大大降低，因此由式 (I) 所代表的化合物诱捕质子后衍生的化合物在诱捕质子或类似物后基本上具有高荧光性）。本发明提供了一种具有优异荧光特性的荧光探针。
• Fluorescent probe
  申请人：Nagano Tetsuo

  公开号：US20060030054A1

  公开（公告）日：2006-02-09

  A fluorescent probe which is represented by the following formula (I): (wherein, R 1 and R 2 represent hydrogen atom, or a substituent for trapping proton, a metal ion, or an active oxygen species, or the like; R 3 represents a monovalent substituent; R 4 and R 5 represent hydrogen atom or a halogen atom; R 6 represents hydrogen atom, an alkylcarbonyl group, or an alkylcarbonyloxymethyl group, provided that a combination of R 1 , R 2 , and R 3 provides (1) substantially high electron density of the benzene ring to which said groups bind, so that the compound represented by the formula (I) is substantially no fluorescent before the trapping of proton, or the like, and (2) substantially reduced electron density of the benzene ring to which said groups bind, so that a compound after the trapping, which is derived from the compound represented by the formula (I) is substantially highly fluorescent after the trapping of proton or the like). A fluorescent probe having an excellent fluorescence property is provided.

  由下式（I）表示的荧光探针： (其中，R 1 和 R 2 代表氢原子，或代表用于捕获质子的取代基、金属离子或活性氧等；R 3 代表一价取代基；R 4 和 R 5 代表氢原子或卤素原子；R 6 代表氢原子、烷基羰基或烷基羰氧甲基，条件是 R 1 , R 2 和 R 3 提供(1)所述基团结合的苯环电子密度高，因此式(I)代表的化合物在捕获质子或类似物之前基本上无荧光，以及(2)所述基团结合的苯环电子密度低，因此捕获质子或类似物后，由式(I)代表的化合物衍生的化合物在捕获质子或类似物后基本上具有高荧光。）本发明提供了一种具有优异荧光特性的荧光探针。
• KIMURA MICHIO; OKABAYASHI ICHIZO, CHEM. AND PHARM. BULL., 35,(1987) N 1, 136-141
  作者：KIMURA MICHIO、 OKABAYASHI ICHIZO

  DOI：——

  日期：——