2,4,7,9-Tetrakis(9,9-dimethylfluoren-2-yl)-1,10-phenanthroline | 676542-61-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: 2,4,7,9-Tetrakis(9,9-dimethylfluoren-2-yl)-1,10-phenanthroline
• CAS: 676542-61-3
• 化学式: C₇₂H₅₆N₂
• 分子量: 949.25
• InChiKey: ATNBNVZXPZPIEY-UHFFFAOYSA-N

物化性质

• 密度：
  1.194±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  19
• 重原子数：
  74
• 可旋转键数：
  4
• 环数：
  15.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4,7-Bis(9,9-dimethylfluoren-2-yl)-1,10-phenanthroline 、 2-碘-9,9-二甲基芴 在 正丁基锂 作用下， 以 乙醚 、 正己烷 、 甲苯 为溶剂， 反应 13.0h， 以73%的产率得到2,4,7,9-Tetrakis(9,9-dimethylfluoren-2-yl)-1,10-phenanthroline
  参考文献：
  名称：

  [EN] PHENANTHROLINE COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING SAME
  [FR] COMPOSE DE PHENANTHROLINE ET DISPOSITIF ELECTROLUMINESCENT ORGANIQUE COMPRENANT CE COMPOSE

  摘要：

  提供一种新的菲啰啉化合物，其通式表示为[I]：（其中R?1#191，R?2#191，R?3#191，R?4#191，R?5#191和R?6#191相同或不同，且每个均选自氢原子，未取代或取代的烷基，未取代或取代的芳基烷基，未取代或取代的芳基，未取代或取代的杂环基和卤素原子，Ar?1#191和Ar?2#191相同或不同，且每个均选自未取代或取代的芴基，未取代或取代的芴烯基，未取代或取代的苝基和未取代或取代的咔唑基）。还提供了使用该菲啰啉化合物的有机发光器件，其具有高效率和高亮度的光输出，并具有高长期耐久性。

  公开号：

  WO2004026870A1

文献信息

• PHENANTHROLINE COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING SAME
  申请人：Okajima Maki

  公开号：US20090218940A1

  公开（公告）日：2009-09-03

  A novel phenanthroline compound is provided which is represented by the general formula [I]: (wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and each is selected from a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aralkyl group, an unsubstituted or substituted aryl group, an unsubstituted or substituted heterocyclic group, and a halogen atom; and Ar 1 and Ar 2 are the same or different and each is selected from an unsubstituted or substituted fluorenyl group, an unsubstituted or substituted fluoranthenyl group, an unsubstituted or substituted perylenyl group, and an unsubstituted or substituted carbazolyl group). An organic light emitting device using the phenanthroline compound is also provided that has a light output with a high efficiency and a high luminance and has a high long-term durability.
• US7550594B2
  申请人：——

  公开号：US7550594B2

  公开（公告）日：2009-06-23
• US7982213B2
  申请人：——

  公开号：US7982213B2

  公开（公告）日：2011-07-19
• [EN] PHENANTHROLINE COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING SAME<br/>[FR] COMPOSE DE PHENANTHROLINE ET DISPOSITIF ELECTROLUMINESCENT ORGANIQUE COMPRENANT CE COMPOSE
  申请人：CANON KK

  公开号：WO2004026870A1

  公开（公告）日：2004-04-01

  A novel phenanthroline compound is provided which is represented by the general formula [I]: (wherein R?1#191, R?2#191, R?3#191, R?4#191, R?5#191 and R?6#191 are the same or different and each is selected from a hydrogen atom, an unsubstituted or substituted alkyl group, an unsubstituted or substituted aralkyl group, an unsubstituted or substituted aryl group, an unsubstituted or substituted heterocyclic group, and a halogen atom, and Ar?1#191 and Ar?2#191 are the same or different and each is selected from an unsubstituted or substituted fluorenyl group, an unsubstituted or substituted fluoranthenyl group, an unsubstituted or substituted perylenyl group, and an unsubstituted or substituted carbazolyl group). An organic light emitting device using the phenanthroline compound is also provided that has a light output with a high efficiency and a high luminance and has a high long-term durability.

  提供一种新的菲啰啉化合物，其通式表示为[I]：（其中R?1#191，R?2#191，R?3#191，R?4#191，R?5#191和R?6#191相同或不同，且每个均选自氢原子，未取代或取代的烷基，未取代或取代的芳基烷基，未取代或取代的芳基，未取代或取代的杂环基和卤素原子，Ar?1#191和Ar?2#191相同或不同，且每个均选自未取代或取代的芴基，未取代或取代的芴烯基，未取代或取代的苝基和未取代或取代的咔唑基）。还提供了使用该菲啰啉化合物的有机发光器件，其具有高效率和高亮度的光输出，并具有高长期耐久性。