Chloro(hexan-2-yl)dimethylsilane | 204859-33-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Chloro(hexan-2-yl)dimethylsilane
• 英文别名: chloro-hexan-2-yl-dimethylsilane
• CAS: 204859-33-6
• 化学式: C₈H₁₉ClSi
• 分子量: 178.777
• InChiKey: VDBGLIUSJYGBOL-UHFFFAOYSA-N

物化性质

• 沸点：
  181.0±9.0 °C(Predicted)
• 密度：
  0.859±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.01
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-己烯 、 二甲基一氯硅烷 在 Ni(Bu₃P)2(NCS)2 作用下， 反应 4.0h， 生成 二甲基己基氯硅烷 、 己基二甲基-硅烷 、 、 Chloro(hexan-2-yl)dimethylsilane
  参考文献：
  名称：

  摘要：

  According to X-ray diffraction data, the nickel complex [Ni(Bu3P)(2)(NCS)(2)] has a square-planar structure with the two phosphine ligands trans to each other and the thiocyanate ligand coordinated by the nitrogen atom. The IR and H-1, C-13, and P-31 NMR data show that the same structure is preserved in solutions. The catalytic activity of the complex in hydrosilylation of 1-hexene with chlorohydrosilanes HSiMe3-nCln varies in the series HSiCl3 > HSiMeCl2 > HSiMe2Cl. The reactions of the complex with hydrosilanes involve substitution of the anionic ligand and formation of silyl complexes.

  DOI：

  10.1023/a:1023426519100

文献信息

• ——
  作者：N. K. Skvortsov

  DOI：10.1023/a:1023426519100

  日期：——

  According to X-ray diffraction data, the nickel complex [Ni(Bu3P)(2)(NCS)(2)] has a square-planar structure with the two phosphine ligands trans to each other and the thiocyanate ligand coordinated by the nitrogen atom. The IR and H-1, C-13, and P-31 NMR data show that the same structure is preserved in solutions. The catalytic activity of the complex in hydrosilylation of 1-hexene with chlorohydrosilanes HSiMe3-nCln varies in the series HSiCl3 > HSiMeCl2 > HSiMe2Cl. The reactions of the complex with hydrosilanes involve substitution of the anionic ligand and formation of silyl complexes.