1,5-Dianisal-diaminonaphthalin | 60326-25-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,5-Dianisal-diaminonaphthalin
• 英文别名: N,N'-bis-(4-methoxy-benzylidene)-naphthalene-1,5-diyldiamine；N,N'-Bis-(4-methoxy-benzyliden)-naphthalin-1,5-diyldiamin；1.5-Bis-(4-methoxy-benzylidenamino)-naphthalin；N.N'-Dianisyliden-naphthylendiamin-(1.5)；N-(4-methoxybenzylidene)-N-{5-[(4-methoxybenzylidene)amino]-1-naphthyl}amine；1-(4-methoxyphenyl)-N-[5-[(4-methoxyphenyl)methylideneamino]naphthalen-1-yl]methanimine
• CAS: 60326-25-2
• 化学式: C₂₆H₂₂N₂O₂
• 分子量: 394.473
• InChiKey: IOJULEMVKXWTOZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,5-Dianisal-diaminonaphthalin 、 1,3-环己二酮 以 正丁醇 为溶剂， 反应 3.0h， 以45%的产率得到8,16-bis(4-methoxyphenyl)-3,4,8,10,11,12,13,16-octahydroacridino[4,3-c]acridine-1,9(2H,5H)-dione
  参考文献：
  名称：

  Synthesis of 8,16-diarylacridino[4,3-c]acridine-1,9-dione derivatives

  摘要：

  A number of new acridino[4,3-c]acridinedione derivatives have been synthesized for the first time by condensation of N (1),N (5)-bis(arylmethylidene)naphthalene-1,5-diamines with cyclic 1,3-diketones (cyclohexane-1,3-dione and dimedone). The product structure has been determined by two-dimensional NMR spectroscopy, and a probable reaction mechanism has been proposed.

  DOI：

  10.1134/s1070428016030155

文献信息

• Synthesis of 8,16-diarylacridino[4,3-c]acridine-1,9-dione derivatives
  作者：Yu. D. Zhikharko、N. G. Kozlov、L. I. Basalaeva

  DOI：10.1134/s1070428016030155

  日期：2016.3

  A number of new acridino[4,3-c]acridinedione derivatives have been synthesized for the first time by condensation of N (1),N (5)-bis(arylmethylidene)naphthalene-1,5-diamines with cyclic 1,3-diketones (cyclohexane-1,3-dione and dimedone). The product structure has been determined by two-dimensional NMR spectroscopy, and a probable reaction mechanism has been proposed.