11-phenylbenzofuro[3,2-b]carbazole | 1015076-90-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 11-phenylbenzofuro[3,2-b]carbazole
• 英文别名: Ph-BFC；11-Phenylbenzofuro[3,2-b]carbazole；11-phenyl-[1]benzofuro[3,2-b]carbazole
• CAS: 1015076-90-0
• 化学式: C₂₄H₁₅NO
• 分子量: 333.389
• InChiKey: JIWHBSJIAKPXQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  26
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(trifluoromethansulfonyloxy)-3-[2-(trifluoromethansulfonyloxy)phenyl]-dibenzofuran 、 苯胺 在 potassium phosphate 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 2-二环己基磷-2',6'-二异丙氧基-1,1'-联苯 作用下， 以 甲苯 为溶剂， 反应 72.0h， 以97%的产率得到11-phenylbenzofuro[3,2-b]carbazole
  参考文献：
  名称：

  Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing Both Pyrrole and Furan Rings

  摘要：

  Unsymmetrical heteroacenes, 11-phenylbenzofuro[3;2-b]carbazole (Ph-BFC) and its alkoxylated derivatives, were readily synthesized by palladium-catalyzed double N-arylation of arylamines. They characteristically form antiparallel cofacial pi-stacking arrangements, which may result from their unsymmetrical structures. Their physical properties show their potential for application as active layers in organic field-effect transistors.

  DOI：

  10.1021/ol703110g

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：EP3124488A1

  公开（公告）日：2017-02-01

  Novel compounds that contain azadibenzofuran, azadibenzothiophene, and azadibenzoselenophene with fused rings that can be used as a host material in phosphorescent OLEDs is disclosed.

  本发明公开了含有偶氮二苯并呋喃、偶氮二苯并噻吩和偶氮二苯并硒吩的具有融合环的新型化合物，这些化合物可用作磷光 OLED 的主材料。
• Organic light-emitting device
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10020459B2

  公开（公告）日：2018-07-10

  An organic light-emitting device includes: a first electrode, a second electrode facing the first electrode, and an organic layer between the first electrode and the second electrode, the organic layer including: an emission layer, an electron transport region between the second electrode and the emission layer, and a mixed layer between the emission layer and the electron transport region, the mixed layer including a first material and a second material, the first material and the second material being selected from a pyrrolidine-based compound and a C10-C30 polycyclicaromatic hydrocarbon-based compound, and a triplet energy EgT1 of at least one selected from the first material and the second material being 2.2 eV or greater.

  一种有机发光器件包括：第一电极、面向第一电极的第二电极以及位于第一电极和第二电极之间的有机层，有机层包括：发射层、位于第二电极和发射层之间的电子传输区域以及位于发射层和电子传输区域之间的混合层：发射层，第二电极和发射层之间的电子传输区，以及发射层和电子传输区之间的混合层，混合层包括第一材料和第二材料，第一材料和第二材料选自吡咯烷基化合物和 C10-C30 多环芳烃基化合物，以及选自第一材料和第二材料的至少一种材料的三重能 EgT1 为 2.2 eV 或更高。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20150325801A1

  公开（公告）日：2015-11-12

  An organic light-emitting device includes: a first electrode, a second electrode facing the first electrode, and an organic layer between the first electrode and the second electrode, the organic layer including: an emission layer, an electron transport region between the second electrode and the emission layer, and a mixed layer between the emission layer and the electron transport region, the mixed layer including a first material and a second material, the first material and the second material being selected from a pyrrolidine-based compound and a C 10 -C 30 polycyclicaromatic hydrocarbon-based compound, and a triplet energy Eg T1 of at least one selected from the first material and the second material being 2.2 eV or greater.
• ORGANIC ELECTROLUMINESCENT ELEMENT AND ELECTRONIC DEVICE
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20160211466A1

  公开（公告）日：2016-07-21

  An organic electroluminescence device includes: an anode; an emitting layer; and a cathode, the emitting layer containing a first material and a second material represented by a formula (21) below. The first material has a singlet energy larger than a singlet energy of the second material.
• ORGANIC COMPOUND, ELECTROLUMINESCENT MATERIAL, AND APPLICATION THEREOF
  申请人：SHANGHAI TIANMA AM-OLED CO., LTD.

  公开号：US20210147442A1

  公开（公告）日：2021-05-20

  Provided are an organic compound, an electroluminescent material and an application thereof. The organic compound has a structure represented by Formula I. With the design of the spiro parent structure and the introduction of specific substituents, the organic compound can prevent materials from stacking and reduce the crystallinity of the molecule. The design of the spiro structure and substituents make the organic material have a high triplet state energy level Ti, and the nitrogen heterocycle and its linking groups make the organic compound have characteristics of good electron and hole transport performances. The organic compound has suitable HOMO and LUMO energy levels, facilitating the coordination of adjacent layers in terms of energy level. The organic compound also has advantages of high glass-transition temperature and good molecular thermal stability. Therefore, the organic compound can effectively improve the light emitting efficiency and lifetime of the device.