2,13-dinitro-8-phenyl-benzofuro[2,3-c]benzofuro[3,2-g]carbazole | 1361314-65-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 2,13-dinitro-8-phenyl-benzofuro[2,3-c]benzofuro[3,2-g]carbazole
• 英文别名: 6,24-Dinitro-15-phenyl-10,20-dioxa-15-azaheptacyclo[14.11.0.02,14.03,11.04,9.019,27.021,26]heptacosa-1(16),2(14),3(11),4(9),5,7,12,17,19(27),21(26),22,24-dodecaene；6,24-dinitro-15-phenyl-10,20-dioxa-15-azaheptacyclo[14.11.0.02,14.03,11.04,9.019,27.021,26]heptacosa-1(16),2(14),3(11),4(9),5,7,12,17,19(27),21(26),22,24-dodecaene
• CAS: 1361314-65-9
• 化学式: C₃₀H₁₅N₃O₆
• 分子量: 513.466
• InChiKey: BLTNSZDJOLLOKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  39
• 可旋转键数：
  1
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  123
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,1'-bis(8-nitro-dibenzofuran-2-ol) 在 potassium phosphate 、 tris-(dibenzylideneacetone)dipalladium(0) 、 三乙胺 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 邻二甲苯 、 N,N-二甲基甲酰胺 为溶剂， 反应 45.0h， 生成 2,13-dinitro-8-phenyl-benzofuro[2,3-c]benzofuro[3,2-g]carbazole
  参考文献：
  名称：

  Synthesis of Functionalized Dioxa-aza[7]helicenes Using Palladium Catalyzed Arylations

  摘要：

  Despite the recent reports on transition-metal catalyzed cycloisomerization strategies toward helicenes, the amount of palladium catalyzed routes remains rather scarce. Within this letter the successful preparation and characterization of novel dioxa-aza[7]helicenes using palladium mediated coupling reactions is presented.

  DOI：

  10.1021/ol300236t

文献信息

• Synthesis of Functionalized Dioxa-aza[7]helicenes Using Palladium Catalyzed Arylations
  作者：Hans Kelgtermans、Liliana Dobrzańska、Luc Van Meervelt、Wim Dehaen

  DOI：10.1021/ol300236t

  日期：2012.3.16

  Despite the recent reports on transition-metal catalyzed cycloisomerization strategies toward helicenes, the amount of palladium catalyzed routes remains rather scarce. Within this letter the successful preparation and characterization of novel dioxa-aza[7]helicenes using palladium mediated coupling reactions is presented.