2--5-(p-vinyl-phenyl)-1,3,4-oxadiazol | 21464-06-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2--5-(p-vinyl-phenyl)-1,3,4-oxadiazol
• 英文别名: 2-naphthalen-2-yl-5-(4-vinyl-phenyl)-[1,3,4]oxadiazole；2-(4-Ethenylphenyl)-5-naphthalen-2-yl-1,3,4-oxadiazole
• CAS: 21464-06-2
• 化学式: C₂₀H₁₄N₂O
• 分子量: 298.344
• InChiKey: AECRZIBJPDAJAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-<β-Naphthoyl>-2--hydrazin 在 三氯氧磷 作用下， 生成 2--5-(p-vinyl-phenyl)-1,3,4-oxadiazol
  参考文献：
  名称：

  Vinyl derivatives of 2, 5-diaryl-1, 3,4-oxadiazoles

  摘要：

  DOI：

  10.1007/bf00478067

文献信息

• PHOSPHORS AND PROCESS FOR PRODUCTION THEREOF, LUMINESCENT COMPOSITIONS, AND ORGANIC ELECTROLUMINESCENT DEVICES AND PROCESSES FOR PRODUCTION THEREOF
  申请人：JSR Corporation

  公开号：EP1516901A1

  公开（公告）日：2005-03-23

  Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof. A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1). [In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R1 and R2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R1 and R2 may be either the same or different, X1 represents a phenylene group or a carbonyloxy group, X2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]

  本发明公开了一种可通过湿法形成薄膜并提供具有高亮度的有机电致发光器件的磷光剂及其生产工艺，以及一种含有该磷光剂的发光组合物、一种具有含有该磷光剂的发光层的有机电致发光器件及其生产工艺。 根据本发明的磷光剂包括一种聚合物，其分子中具有由以下通式（1）表示的结构单元。 [通式（1）中，M 代表价数为 2 至 4 的金属原子，R1 和 R2 分别代表氢原子、卤素原子、环烷基、芳基和杂环基，且 R1 和 R2 可以相同或不同，X1 代表亚苯基或碳酰氧基，X2 代表亚烷基，L 代表有机配位体，p 为 1 至 3 的整数，q 为 0 或 1。］
• Light emitting polymer composition, and organic electroluminescence device and production process thereof
  申请人：JSR CORPORATION

  公开号：US20030116788A1

  公开（公告）日：2003-06-26

  Disclosed herein is a light emitting polymer composition which permits providing an organic electroluminescence device high in luminous efficiency and excellent in durability and forming a functional organic material layer with ease by the wet process. The light emitting polymer composition comprising a polymer component and a phosphorescent agent contained in the polymer component, wherein the polymer component is composed of a hole transporting component formed from 50 to 99 mol % of a hole transporting monomer and an electron transporting component formed from 50 to 1 mol % of an electron transporting monomer. The polymer component is a copolymer composed of 50 to 99 mol % of structural units derived from the hole transporting monomer and 50 to 1 mol % of structural units derived from the electron transporting monomer, or is composed of a hole transporting polymer obtained from the hole transporting monomer and an electron transporting polymer obtained from the electron transporting monomer, and a proportion of the hole transporting polymer to the electron transporting polymer is 50:50 to 99:1 in terms of a molar ratio reduced to the monomers. The light emitting polymer composition is used in an organic electroluminescence device and a production process thereof.

  本文公开了一种发光聚合物组合物，该组合物可提供发光效率高、耐用性好的有机电致发光器件，并可通过湿法工艺轻松形成功能性有机材料层。 该发光聚合物组合物包括聚合物成分和聚合物成分中所含的磷光剂，其中聚合物成分由 50 至 99 摩尔%的空穴传输单体形成的空穴传输成分和 50 至 1 摩尔%的电子传输单体形成的电子传输成分组成。该聚合物成分是由 50 至 99 摩尔%的空穴传输单体衍生的结构单元和 50 至 1 摩尔%的电子传输单体衍生的结构单元组成的共聚物，或者是由空穴传输单体获得的空穴传输聚合物和电子传输单体获得的电子传输聚合物组成的共聚物，并且空穴传输聚合物与电子传输聚合物的摩尔比为 50:50 至 99:1。该发光聚合物组合物可用于有机电致发光装置及其生产工艺中。
• Phosphors and process for production thereof, luminescent compositions, and organic electroluminescent devices and processes for production thereof
  申请人：Sakakibara Mitsuhiko

  公开号：US20050145830A1

  公开（公告）日：2005-07-07

  Disclosed herein are, a phosphorescent agent which can form a thin film by a wet method and provide an organic electroluminescence device having high luminance and production process thereof, and a luminescent composition containing the phosphorescent agent, an organic electroluminescence device having a luminescent layer containing the phosphorescent agent and production process thereof. A phosphorescent agent according to the present invention comprising a polymer having in its molecule a structural unit represented by the following general formula (1). [In the general formula (1), M represents a metal atom having a valence of 2 to 4, each of R 1 and R 2 represents a hydrogen atom, a halogen atom, a cycloalkyl group, an aryl group and a heterocycle group and R 1 and R 2 may be either the same or different, X 1 represents a phenylene group or a carbonyloxy group, X 2 represents an alkylene group, L represents an organic ligand, p is an integer of 1 to 3, and q is 0 or 1.]

  本发明公开了一种可通过湿法形成薄膜并提供具有高亮度的有机电致发光器件的磷光剂及其生产工艺，以及一种含有该磷光剂的发光组合物、一种具有含有该磷光剂的发光层的有机电致发光器件及其生产工艺。 根据本发明的磷光剂包括一种聚合物，其分子中具有由以下通式（1）表示的结构单元。 [在通式（1）中，M 代表价数为 2 至 4 的金属原子，R 1 和 R 2 代表氢原子、卤素原子、环烷基、芳基和杂环基，R 1 和 R 2 可以相同或不同，X 1 代表亚苯基或羰氧基，X 2 代表亚烷基，L 代表有机配体，p 是 1 到 3 的整数，q 是 0 或 1。］
• Light emitting polymer composition, and organic electroluminescene device and production process thereof
  申请人：JSR Corporation

  公开号：EP1311138B1

  公开（公告）日：2004-09-29
• US6451458B1
  申请人：——

  公开号：US6451458B1

  公开（公告）日：2002-09-17