1,1,2-trifluorocyclohexane | 119910-98-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 1,1,2-trifluorocyclohexane
• CAS: 119910-98-4
• 化学式: C₆H₉F₃
• 分子量: 138.133
• InChiKey: FPPBYJBOHUMXJN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-氟环己酮 在 sulfur tetrafluoride 、 水 作用下， 反应 20.0h， 以91%的产率得到1,1,2-trifluorocyclohexane
  参考文献：
  名称：

  Zefirov, N. S.; Samoshin, V. V.; Mursakulov, I. G., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 7, p. 1286 - 1298

  摘要：

  DOI：

文献信息

• vic-Difluorination of Fluoroalkenes with Xenon Difluoride: The Effect of Fluorine Substituents on the Reaction of Alkenes with Xenon Difluoride
  作者：Masanori Tamura、Heng-dao Quan、Akira Sekiya

  DOI：10.1002/(sici)1099-0690(199911)1999:11<3151::aid-ejoc3151>3.0.co;2-f

  日期：1999.11

  Vic-Difluorination proceeds by the reaction of fluoroalkenes with xenon difluoride to afford the corresponding fluorinated compounds. From the reaction with polyfluoroalkenes, the products are obtained in high to excellent yields. In this reaction, the fluorine atom substituent of alkene stabilizes the cation intermediate and suppresses side-reactions such as rearrangement.

  通过氟代烯烃与二氟化氙的反应进行维克二氟化，得到相应的氟化化合物。从与多氟烯烃的反应中，以高至优异的产率获得了产物。在该反应中，烯烃的氟原子取代基使阳离子中间体稳定并抑制副反应如重排。
• Substituted 1-(Azolin-2-yl)-Amino-1,2-Heterocyclyl-Ethane Compounds For Combating Pests
  申请人：Kordes Markus

  公开号：US20100041700A1

  公开（公告）日：2010-02-18

  The present invention relates to 1-(Azolin-2-yl)-amino-1,2-heterocyclyl-ethane compounds, which are useful for combating insects, arachnids and nematodes. The present invention also relates to methods for combating animal pests and to compositions for combating animal pests. It has been found that animal pests can be combated by 1-(Azolin-2-yl)-amino-1,2-heterocyclyl-ethane compounds of the general formula (I): wherein A is a radical of the formulae A 1 or A 2 : and wherein X is sulfur, oxygen or NR 7 , and Het A , Het B and R 1 to R 7 are defined as in the description.

  本发明涉及1-(Azolin-2-yl)-amino-1,2-杂环基-乙烷化合物，其可用于防治昆虫、蜘蛛和线虫。本发明还涉及用于防治动物害虫的方法和用于防治动物害虫的组合物。发现可以通过通式(I)的1-(Azolin-2-yl)-amino-1,2-杂环基-乙烷化合物来防治动物害虫，其中A是式A1或A2的基团：X是硫、氧或NR7，而HetA、HetB和R1到R7如描述中所定义。
• NONAQUEOUS SOLVENT AND NONAQUEOUS ELECTROLYTIC SOLUTION FOR ELECTRICAL STORAGE DEVICE AND NONAQUEOUS ELECTRICAL STORAGE DEVICE, LITHIUM SECONDARY BATTERY AND ELECTRIC DOUBLE LAYER CAPACITOR USING THE SAME
  申请人：Hasegawa Masaki

  公开号：US20120321964A1

  公开（公告）日：2012-12-20

  A nonaqueous solvent for an electrical storage device disclosed in the present application includes fluorine-containing cyclic saturated hydrocarbon having a structure represented by the following general formula (1) in which one or two substituents R are introduced into a cyclopentane ring; and a compound having a relative dielectric constant of 25 or higher (in general formula (1), R is represented by C n X 2n+1 where n is an integer of 1 or greater, at least one of (2n+1) pieces of X's is F, and the other X's are H).

  本申请所披露的用于电储存设备的非水溶剂包括具有以下一般式（1）所表示的含氟环状饱和烃，其中在环戊烷环中引入一个或两个取代基R;以及具有相对介电常数为25或更高的化合物（在一般式（1）中，R由CnX2n+1表示，其中n是大于等于1的整数，(2n+1)个X中至少有一个是F，其余的X是H）。
• ZEFIROV, N. S.;SAMOSHIN, V. V.;MURSAKULOV, I. G.;PASHINNIK, V. E.;POVOLOT+, ZH. ORGAN. XIMII, 24,(1988) N 7, 1428-1442
  作者：ZEFIROV, N. S.、SAMOSHIN, V. V.、MURSAKULOV, I. G.、PASHINNIK, V. E.、POVOLOT+

  DOI：——

  日期：——
• TAGGANTS, METHOD FOR FORMING A TAGGANT, AND A METHOD FOR DETECTING AN OBJECT
  申请人：Harrup Mason K.

  公开号：US20110100091A1

  公开（公告）日：2011-05-05

  A taggant comprising at least one perfluorocarbon compound surrounded by a polyphosphazene compound. The polyphosphazene compound has the chemical structure: wherein G 1 and G 2 are pendant groups having different polarities, m is an integer greater than or equal to 100, and each of A and B is independently selected from hydrogen, an alkyl, an alkene, an alkoxide, a polyether, a polythioether, a siloxane, and —X(CH 2 ) n Y 1 (CH 2 )p 1 Y 2 (CH 2 )p 2 . . . Y i (CH 2 )p i CH 3 , where n ranges from 1 to 6, X and Y are independently selected from oxygen, sulfur, selenium, tellurium, and polonium, and p 1 through p i range from 1 to 6. Cyclic polyphosphazene compounds lacking the A and B groups are also disclosed, as are methods of forming the taggant and of detecting an object.