Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,4,6-trimethyl- | 202277-49-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,4,6-trimethyl-
• 英文别名: 1-N,2-N-bis(2,4,6-trimethylphenyl)acenaphthylene-1,2-diimine
• CAS: 202277-49-4
• 化学式: C₃₀H₂₈N₂
• 分子量: 416.6
• InChiKey: UIZYDLQUJRTNDL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  32
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  24.7
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• Method for Aerobic Oxidative Coupling of Thiophenes with a Ligand-Supported Palladium Catalyst
  申请人：Wisconsin Alumni Research Foundation

  公开号：US20190210993A1

  公开（公告）日：2019-07-11

  An oxidative homocoupling method of synthesizing certain 2,2′-bithiophenes from thiophenes using oxygen as the terminal oxidant is disclosed. In non-limiting examples, the method uses oxygen along with a catalytic system that includes palladium, an assistive ligand, and a non-palladium metal additive to catalyze one of the following reactions: Associated catalytic systems and compositions are also disclosed.

  披露了一种利用氧气作为末端氧化剂，从噻吩合成特定的2,2′-双噻吩的氧化性自偶联方法。在非限制性的示例中，该方法使用氧气以及包括钯、辅助配体和非钯金属添加剂的催化系统来催化以下反应之一：同时还披露了相关的催化系统和组合物。
• Method for aerobic oxidative coupling of thiophenes with a ligand-supported palladium catalyst
  申请人：Wisconsin Alumni Research Foundation

  公开号：US10858334B2

  公开（公告）日：2020-12-08

  An oxidative homocoupling method of synthesizing certain 2,2′-bithiophenes from thiophenes using oxygen as the terminal oxidant is disclosed. In non-limiting examples, the method uses oxygen along with a catalytic system that includes palladium, an assistive ligand, and a non-palladium metal additive to catalyze one of the following reactions: Associated catalytic systems and compositions are also disclosed.

  本发明公开了一种以氧为末端氧化剂从噻吩合成某些2,2′-噻吩的氧化均偶联方法。在非限制性实例中，该方法使用氧气和包括钯、辅助配体和非钯金属添加剂的催化体系来催化下列反应之一： 还公开了相关的催化体系和组合物。