2-hydrazono-1,3-dithiane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二噻烷
• 英文名称: 2-hydrazono-1,3-dithiane
• 英文别名: 2-Hydrazono-1,3-dithiane；1,3-dithian-2-ylidenehydrazine
• 化学式: C₄H₈N₂S₂
• 分子量: 148.253
• InChiKey: KGYRUVINCSNRGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  89
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二茂铁甲醛 、 2-hydrazono-1,3-dithiane 以 乙醇 为溶剂， 生成 2-ferrocenylmethylidenehydrazono-1,3-dithiane
  参考文献：
  名称：

  Crystal structures of 2-ferrocenylmethylidenehydrazono-1,3-dithiane and 2-ferrocenylmethylidenehydrazono-1,3-dithiepane

  摘要：

  Two compounds of 2-ferrocenylmethylidenehydrazono-1,3-dithiane (1) and 2-ferrocenylmethylidenehydrazono-1,3-dithiepane (2) are synthesized and their single crystal structures are determined by the X-ray diffraction method. Compound 1 belongs to the orthorhombic Pca2(1) space group with the cell parameters: a = 13.989(4) , b = 5.785(2) , c = 18.231(5) , V = 1475.4(7) (3); while compound 2 crystallizes in a monoclinic symmetry, P2(1)/c space group with a = 15.320(2) , b = 5.8028(6) , c = 36.584(4) , beta = 91.932(1)A degrees and V = 3250.4(6) A(3).

  DOI：

  10.1134/s0022476614030196
• 作为产物：
  描述：

  二硫化碳 、 1,3-二溴丙烷 在 potassium hydroxide 、 肼 作用下， 生成 2-hydrazono-1,3-dithiane
  参考文献：
  名称：

  Crystal structures of 2-ferrocenylmethylidenehydrazono-1,3-dithiane and 2-ferrocenylmethylidenehydrazono-1,3-dithiepane

  摘要：

  Two compounds of 2-ferrocenylmethylidenehydrazono-1,3-dithiane (1) and 2-ferrocenylmethylidenehydrazono-1,3-dithiepane (2) are synthesized and their single crystal structures are determined by the X-ray diffraction method. Compound 1 belongs to the orthorhombic Pca2(1) space group with the cell parameters: a = 13.989(4) , b = 5.785(2) , c = 18.231(5) , V = 1475.4(7) (3); while compound 2 crystallizes in a monoclinic symmetry, P2(1)/c space group with a = 15.320(2) , b = 5.8028(6) , c = 36.584(4) , beta = 91.932(1)A degrees and V = 3250.4(6) A(3).

  DOI：

  10.1134/s0022476614030196