4,5,6-triphenyl-1,2,3-triazine | 39672-37-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 4,5,6-triphenyl-1,2,3-triazine
• 英文别名: 1,2,3-Triazine, 4,5,6-triphenyl-；4,5,6-triphenyltriazine
• CAS: 39672-37-2
• 化学式: C₂₁H₁₅N₃
• 分子量: 309.37
• InChiKey: GGUFVZFOCZNPEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4,5,6-triphenyl-1,2,3-triazine 在 diiron nonacarbonyl 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以80%的产率得到3,4,5-三苯基吡唑
  参考文献：
  名称：

  Nonacarbonyldiiron-Induced Reaction of 3-Azido-1,2,3-triphenylcyclopropene and 4,5,6-Triphenyl-1,2,3-triazine

  摘要：

  [Fe2(CO)9]诱导的3-叠氮-1,2,3-三苯基环丙烯（1）发生氮分子消除和C-C键断裂反应，生成苯甲腈、二苯乙炔、2,3-二苯基茚-1-酮和1,2,3-三苯基丙烯-1-酮。1的异构体4,5,6-三苯基-1,2,3-三嗪的类似反应中，N-N键发生还原断裂，高产率地生成3,4,5-三苯基吡唑。

  DOI：

  10.1246/bcsj.60.3062
• 作为产物：
  描述：

  2-Methyl-4,6-diphenyl-2,5-dihydro-[1,2,3]triazine 在 lead(IV) acetate 、 溴 、 碘 作用下， 以 乙醚 为溶剂， 反应 3.17h， 生成 4,5,6-triphenyl-1,2,3-triazine
  参考文献：
  名称：

  The Reactions of 2-Methyl-1,2,3-triazinium Iodides and Related Compounds.

  摘要：

  2-甲基-1, 2, 3-三嗪镑离子2与各种亲核试剂反应，形成了相应的2, 5-二氢加合物。当2与过氧化钾反应时，它被二聚为5, 5'-双(2-甲基-2, 5-二氢三嗪基)。2, 5-二氢-1, 2, 3-三嗪在与过氧化物反应时也会形成二聚体。这些反应揭示了超氧化物与三嗪衍生物之间独特的双重反应性。

  DOI：

  10.1248/cpb.40.2283

文献信息

• SULPHUR-CONTAINING AND SULPHONATED AROMATIC PERFLUOROALKANE MONOMER
  申请人：Fedurco Milan

  公开号：US20130197110A1

  公开（公告）日：2013-08-01

  A sulphur-containing and sulphonated aromatic perfluoroalkane monomer is provided that can be used for the manufacture of a polymer membrane for a PEM-type fuel cell. The perfluoroalkane monomer is a functionalized polymer that has a structure corresponding to a formula (I): E 1 -Ar 1 —X 1 —(CF 2 ) n —X 2 —Ar 2 -E 2 (I) in which: n is in a range from 1 to 20; X 1 and X 2 , which are identical or different, represent S, SO, or SO 2 ; Ar 1 , Ar 2 , which are identical or different, represent a phenylene group, at least one of Ar 1 and Ar 2 bearing a sulphonic (—SO 3 H) group or a sulphonate (—SO 3 M) group, in which M represents an alkali metal cation; and E 1 and E 2 , which are identical or different, represent an electrophilic group such as a halogen, specifically fluorine or chlorine.

  提供一种含硫和磺化芳香全氟烷单体，可用于制造用于PEM型燃料电池的聚合物膜。全氟烷单体是一种具有结构对应于式(I)的功能化聚合物：E1-Ar1—X1—(CF2)n—X2—Ar2-E2(I)，其中：n在1到20的范围内；X1和X2（相同或不同）代表S、SO或SO2；Ar1、Ar2（相同或不同）代表苯基，Ar1和Ar2中至少一个带有磺酸基（—SO3H）或磺酸盐基（—SO3M），其中M代表碱金属阳离子；E1和E2（相同或不同）代表亲电性基团，如卤素，特别是氟或氯。
• SULPHUR-CONTAINING TRIAZINE MONOMER THAT CAN BE USED FOR THE SYNTHESIS OF A POLYMER MEMBRANE FOR A FUEL CELL
  申请人：Fedurco Milan

  公开号：US20130184428A1

  公开（公告）日：2013-07-18

  A sulphur-containing triazine monomer is provided that can be used in the synthesis of a polymer membrane for a PEM-type fuel cell. The sulphur-containing triazine monomer has a structure corresponding to a formula (I): in which: Tz represents a 1,3,5-triazine nucleus; X 1 and X 2 , which are identical or different, represent S, SO, or SO 2 ; Ar 1 , Ar 2 , Ar 4 and Ar 5 , which are identical or different, represent a substituted or unsubstituted phenylene group; Ar 3 represents a substituted or unsubstituted phenyl group; and Z 1 and Z 2 , which are identical or different, are selected from a group that includes halogens, hydroxyl, alkoxyl, thiol, carboxyl, carboxylates, amine, sulphonamide, acyl chlorides, sulphonyl chlorides, sulphonyl fluorides, isocyanates, and combinations thereof.

  提供一种含硫三嗪单体，可用于合成用于PEM型燃料电池的聚合物膜。含硫三嗪单体具有与以下公式（I）相对应的结构：其中：Tz代表1,3,5-三嗪核；X1和X2，相同或不同，代表S、SO或SO2；Ar1、Ar2、Ar4和Ar5，相同或不同，代表取代或未取代的苯基团；Ar3代表取代或未取代的苯基团；Z1和Z2，相同或不同，选自包括卤素、羟基、烷氧基、硫醇、羧基、羧酸盐、胺基、磺酰胺、酰氯、磺酰氯、磺酰氟、异氰酸酯及其组合的群体。
• Heteroaryl substituted hydroxyphenyltriazine uv-absorbers
  申请人：——

  公开号：US20040013619A1

  公开（公告）日：2004-01-22

  The present invention provides compounds having the formula (1) in which each of the radicals R 1 , R 2 , R 3 and R 4 , independently, represent hydrogen, hydroxy, halogen, C 1 -C 20 -alkyl, C 1 -C 20 -alkoxy, CN or COOR 5 , in which R 5 is C 1 -C 20 -alkyl and Z represents a heterocyclic residue selected from the 2H-benzo[1,2-d]triazol-2-yl, 2H-naphtho[1,2-d]triazol-2-yl, benzimidazol-2-yl, benzoxazol-2-yl and benzofuran-2-yl moieties, optionally substituted by C 1 -C 4 -alkyl, C 1 -C 4 -alkoxy, halogen or NHCOC 1 -C 4 -alkyl, a process for their preparation, new intermediate benzoxazinones useful for their preparation and use of the compounds of formula (1) as UV-absorbers which have improved absorption spectrum characteristics, superior resistance to exposure to UV light and excellent thermal stability, relative to known triphenyltriazine compounds.

  本发明提供了具有以下式（1）的化合物，其中R1、R2、R3和R4中的每个基团独立地代表氢、羟基、卤素、C1-C20-烷基、C1-C20-烷氧基、CN或COOR5，其中R5是C1-C20-烷基，Z代表从2H-苯并［1,2-d］三唑-2-基、2H-萘［1,2-d］三唑-2-基、苯并咪唑-2-基、苯并噁唑-2-基和苯并呋喃-2-基残基中选取的杂环残基，可选择地经C1-C4-烷基、C1-C4-烷氧基、卤素或NHCOC1-C4-烷基取代，以及其制备方法，用于其制备的新中间体苯并噁唑酮，以及将式（1）化合物用作具有改善吸收光谱特性、优越的抗紫外光暴露能力和优异的热稳定性的UV吸收剂的用途，相对于已知的三苯基三嗪化合物。
• INK COMPOSITION FOR ORGANIC LIGHT-EMITTING DEVICE, ORGANIC LIGHT-EMITTING DEVICE INCLUDING FILM FORMED BY USING THE INK COMPOSITION, AND METHOD OF MANUFACTURING THE ORGANIC LIGHT-EMITTING DEVICE
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20180019411A1

  公开（公告）日：2018-01-18

  An ink composition for an organic light-emitting device, the ink composition including a luminescent host material and a solvent, wherein the luminescent host material includes at least one compound represented by Formula (1), and wherein the solvent includes at least one selected from an aromatic ether, an aromatic ester, and an aromatic ketone: wherein, in Formula (1), groups and variables are the same as described in the specification.

  一种用于有机发光器件的墨水组合物，该墨水组合物包括发光主体材料和溶剂，其中发光主体材料包括至少一种由式（1）表示的化合物，溶剂包括至少一种选自芳香醚、芳香酯和芳香酮的物质：在式（1）中，基团和变量与规范中描述的相同。
• COMPOSITION FOR ORGANIC ELECTRONIC DEVICES
  申请人：Merck Patent GmbH

  公开号：US20200231578A1

  公开（公告）日：2020-07-23

  The present invention relates to a composition which comprises an electron-transporting host and a hole-transporting host, to the use thereof in electronic devices and to electronic devices containing this composition. The electron-transporting host is particularly preferably selected from the class of the triazine-dibenzofuran-carbazole systems or the class of the triazine-dibenzothiophene-carbazole systems. The hole-transporting host is preferably selected from the class of the biscarbazoles.

  本发明涉及一种包括电子传输主机和空穴传输主机的组合物，以及其在电子设备中的使用，以及含有该组合物的电子设备。电子传输主机特别优选自三嗪-二苯并呋喃-咔唑系统或三嗪-二苯并噻吩-咔唑系统类中选择。空穴传输主机优选自双咔唑类中选择。