methyl naphthalen-1-yl cyclohexane-1,2-dicarboxylate | 1236063-06-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: methyl naphthalen-1-yl cyclohexane-1,2-dicarboxylate
• 英文别名: 1-O-methyl 2-O-naphthalen-1-yl cyclohexane-1,2-dicarboxylate
• CAS: 1236063-06-1
• 化学式: C₁₉H₂₀O₄
• 分子量: 312.365
• InChiKey: SDROUMGBQVXOGX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-萘基三甲氧基硅烷 、 六氢苯酐 在 silver fluoride 、 copper(I) bromide 作用下， 以 甲苯 为溶剂， 反应 30.0h， 以63%的产率得到methyl naphthalen-1-yl cyclohexane-1,2-dicarboxylate
  参考文献：
  名称：

  Copper-Catalyzed Sequential Alkyl/Aryl or Vinyl Esterification of Dicarboxylic Acid Anhydrides with Alkoxysilanes

  摘要：

  A copper(I)-catalyzed bis-esterification of cyclic anhydrides with aryl and vinyl alkoxysilanes is described, in which the alkoxy and aryl (or vinyl) esters of dicarboxylic acids were prepared in one pot with moderate to good yields. Notably, vinyl trimethoxysilanes also worked well with this procedure.

  DOI：

  10.1021/jo100926a

文献信息

• Copper-Catalyzed Sequential Alkyl/Aryl or Vinyl Esterification of Dicarboxylic Acid Anhydrides with Alkoxysilanes
  作者：Fang Luo、Changduo Pan、Pengcheng Qian、Jiang Cheng

  DOI：10.1021/jo100926a

  日期：2010.8.6

  A copper(I)-catalyzed bis-esterification of cyclic anhydrides with aryl and vinyl alkoxysilanes is described, in which the alkoxy and aryl (or vinyl) esters of dicarboxylic acids were prepared in one pot with moderate to good yields. Notably, vinyl trimethoxysilanes also worked well with this procedure.