6-氯-1,3,5-三嗪-2,4(1H,3H)-二酮钠盐 | 32998-00-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 6-氯-1,3,5-三嗪-2,4(1H,3H)-二酮钠盐
• 英文名称: 2-chloro-4,6-dihydroxy-1,3,5-triazine monosodium salt
• 英文别名: 1,3,5-Triazine-2,4(1H,3H)-dione, 6-chloro-, monosodium salt；sodium;4-chloro-6-oxo-1H-1,3,5-triazin-2-olate
• CAS: 32998-00-8
• 化学式: C₃HClN₃O₂*Na
• 分子量: 169.503
• InChiKey: GTZITCVVOATWCB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -4.26
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  59.5
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2933699090

反应信息

• 作为反应物：
  描述：

  6-氯-1,3,5-三嗪-2,4(1H,3H)-二酮钠盐 、 (2S,5R)-2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-5-aminomethyl-1,4-dioxane 在 三乙胺 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2,4-dihydroxy-6-{[[(2S,5R)-2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,4-dioxan-5-yl]methyl]amino}-1,3,5-triazine
  参考文献：
  名称：

  合成由 homo-1,4-dioxane 糖类似物和取代的 1,3,5-triazine 碱基等价物组成的新型 homo-N-核苷类似物。

  摘要：

  由酒石酸二甲酯对映选择性合成 1,3,5-三嗪同型-N-核苷类似物，其中含有 1,4-二恶烷部分取代天然核苷中的糖单元。核苷类似物中的三嗪杂环在 2,4-三嗪位置被 NH(2)、OH 和 Cl 的组合进一步取代。

  DOI：

  10.3390/molecules13123092
• 作为产物：
  描述：

  三聚氯氰 在 sodium hydroxide 、 水 作用下， 生成 6-氯-1,3,5-三嗪-2,4(1H,3H)-二酮钠盐
  参考文献：
  名称：

  合成由 homo-1,4-dioxane 糖类似物和取代的 1,3,5-triazine 碱基等价物组成的新型 homo-N-核苷类似物。

  摘要：

  由酒石酸二甲酯对映选择性合成 1,3,5-三嗪同型-N-核苷类似物，其中含有 1,4-二恶烷部分取代天然核苷中的糖单元。核苷类似物中的三嗪杂环在 2,4-三嗪位置被 NH(2)、OH 和 Cl 的组合进一步取代。

  DOI：

  10.3390/molecules13123092

文献信息

• WO2006/111467
  申请人：——

  公开号：——

  公开（公告）日：——
• Kinetics and products of ozonation of C.I. Reactive Red 195 in a semi-batch reactor
  作者：Rui Zhang、Dong-Xing Yuan、Bao-Min Liu

  DOI：10.1016/j.cclet.2014.10.024

  日期：2015.1

  Textile wastewater shows great threats to the environment if not well pretreated before discharge. A promising technique, ozonation, was applied to remove the color in dye solutions containing C.I. Reactive Red 195 (RR195) in a semi-batch reactor. The decolorization of RR195 by the ozone process followed pseudo-first-order kinetics. Several factors which influenced the efficiency of decolorization were studied and the reaction rate constant (k) obtained with different operational parameters was compared. Our results showed that RR195 was more easily degraded in acidic than in alkaline conditions. The dyeing auxiliaries (sodium carbonate and sodium chloride) that acted as radical scavengers could enhance the decolorization process, and the ozonation time for total color removal lengthened if the initial dye concentration was higher. The analysis of the ozonation products was performed by liquid chromatography tandem mass spectrometer and a possible degradation pathway was predicted according to the ozonation products and structure of RR195. Our results indicated that ozonation was effective in the color removal of dyes, but further treatment might be necessary since the ozonation products are high toxic. (C) 2014 Dong-Xing Yuan. Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. All rights reserved.
• Synthesis of Novel Homo-N-Nucleoside Analogs Composed of a Homo-1,4-Dioxane Sugar Analog and Substituted 1,3,5-Triazine Base Equivalents
  作者：Qiang Yu、Dirk Schwidom、Alexander Exner、Per Carlsen

  DOI：10.3390/molecules13123092

  日期：——

  Enantioselective syntheses from dimethyl tartrate of 1,3,5-triazine homo-N-nucleoside analogs, containing a 1,4-dioxane moiety replacing the sugar unit in natural nucleosides, were accomplished. The triazine heterocycle in the nucleoside analogs was further substituted with combinations of NH(2), OH and Cl in the 2,4-triazine positions.

  由酒石酸二甲酯对映选择性合成 1,3,5-三嗪同型-N-核苷类似物，其中含有 1,4-二恶烷部分取代天然核苷中的糖单元。核苷类似物中的三嗪杂环在 2,4-三嗪位置被 NH(2)、OH 和 Cl 的组合进一步取代。