3-(4-Isopropoxy-phenyl)-4-methyl-pentanoic acid

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 苯丙酸
• 英文名称: 3-(4-Isopropoxy-phenyl)-4-methyl-pentanoic acid
• 英文别名: 4-methyl-3-(4-propan-2-yloxyphenyl)pentanoic acid
• 化学式: C₁₅H₂₂O₃
• 分子量: 250.33
• InChiKey: OWEMFIYUYVNSFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• RECYCLABLE METATHESIS CATALYSTS
  申请人：Trustees of Boston College

  公开号：EP1313559A2

  公开（公告）日：2003-05-28
• EP1313559A4
  申请人：——

  公开号：EP1313559A4

  公开（公告）日：2004-02-04
• [EN] RECYCLABLE METATHESIS CATALYSTS<br/>[FR] CATALYSEURS DE METATHESE RECYCLABLES
  申请人：TRUSTEES BOSTON COLLEGE

  公开号：WO2002014376A2

  公开（公告）日：2002-02-21

  Hyghly active, recoverable and recyclable transition metal-based metathesis catalysts and their organometallic complexes including dendrimeric complexes are disclosed, including a Ru complex bearing a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and styrenyl ether ligand. The heterocyclic ligand significantly enhances the catalytic activity, and the styrenyl ether allows for the easy recovery of the Ru complex. Derivatized catalysts capable of being immobilized on substrate surfaces are also disclosed. The present catalysts can be used to catalyze ring-closing metathesis (RCM), ring-opening (ROM) and cross metatheses (CM) reactions, and promote the efficient formation of various trisubstituted olefins at ambient temperature in high yield.