2-(4,5-di-(2-cyanoethylthio)-1,3-dithiol-2-ylidene)-4,5-di-(2-cyanoethylthio)-1,3-dithiole | 84356-34-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二硫醇
• 英文名称: 2-(4,5-di-(2-cyanoethylthio)-1,3-dithiol-2-ylidene)-4,5-di-(2-cyanoethylthio)-1,3-dithiole
• 英文别名: 2-[4,5-Bis(sulfanyl)-1,3-dithiol-2-ylidene]-1,3-dithiole-4,5-dithiol
• CAS: 84356-34-3
• 化学式: C₆H₄S₈
• 分子量: 332.626
• InChiKey: BXAHRSQOIGUFJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105
• 氢给体数：
  4
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2-(4,5-di-(2-cyanoethylthio)-1,3-dithiol-2-ylidene)-4,5-di-(2-cyanoethylthio)-1,3-dithiole 、 3-氯丙基三乙氧基硅烷 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以0.88 g的产率得到3-[[2-[4,5-Bis(3-triethoxysilylpropylsulfanyl)-1,3-dithiol-2-ylidene]-5-(3-triethoxysilylpropylsulfanyl)-1,3-dithiol-4-yl]sulfanyl]propyl-triethoxysilane
  参考文献：
  名称：

  Auto-organization modulation of tetrasubstituted tetrathiafulvalenes (TTF) in silica based hybrid materials

  摘要：

  The effect of the interactions generated by the spacer group between the TTF core and the four triethoxysilane groups on the auto-organization of the organic bridging moieties in hybrid materials obtained by sol-gel chemistry has been investigated. The silica-based hybrid solids are highly polycondensed. They present different scales of organization (nanometric and micrometric) that are independent one from each other and are governed by the different parameters which control the kinetics of polycondensation. Their anisotropic organization is function of the interaction forces induced by the spacer, van der Waals, hydrogen bonding or both, during the hydrolytic condensation process. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.09.034
• 作为产物：
  描述：

  2,3,6,7-四(2-氰乙基硫代)四硫富瓦烯 在 甲醇 、 caesium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.58h， 生成 2-(4,5-di-(2-cyanoethylthio)-1,3-dithiol-2-ylidene)-4,5-di-(2-cyanoethylthio)-1,3-dithiole
  参考文献：
  名称：

  双（环戊二烯基）二硫代钼四硫富瓦烯络合物中有机-有机金属电泳之间的相互作用

  摘要：

  已知四硫富瓦烯（TTF）和双（环戊二烯基）二硫代钼钼配合物Cp 2 Mo（二硫代烯）配合物可作为良好的电子供体分子。为了研究两种电泳之间的相互作用，合成并表征了两种类型的复合物。第一种具有一个与一个TTF二硫代盐配体配位的Cp 2 Mo片段，第二种具有一个桥接两个Cp 2的TTF双（二硫代盐）莫碎片。这些配合物的电化学性质与每种单独的电泳模型的电化学性质的比较提供了它们相互影响的证据。所有这些络合物都具有很好的电子供体的作用，其第一氧化电位比四（甲硫基）TTF低430 mV。DFT计算表明，中性复合物的HOMO和阳离子的SOMO在整个TTF二硫代酸酯配体上是离域的。X射线晶体结构分析的中性和单氧化的Cp 2 Mo（dithiolene）（bismethylthio）TTF配合物与最高占据的前沿分子轨道的离域分配是一致的。紫外可见近红外光谱电化学研究证实了TTF二硫酸酯配体中的这种电子离域。

  DOI：

  10.1021/acs.inorgchem.5b00632

文献信息

• [EN] SULFUR-CONTAINING INORGANIC-ORGANIC HYBRID MATERIALS AND METHODS FOR MAKING THE SAME<br/>[FR] MATÉRIAUX HYBRIDES INORGANIQUES-ORGANIQUES CONTENANT DU SOUFRE ET LEURS PROCÉDÉS DE FABRICATION
  申请人：UNIV CHICAGO

  公开号：WO2021081172A1

  公开（公告）日：2021-04-29

  Coordination complexes of tetrathiafulvalene-based dithiolene linkers, such as tetrathiafulvalene-2,3,6,7-tetrathiolate (TTFtt), and their oxidation products are described. The coordination complexes can include metals such as tin or silicon. Also described are methods of using the coordination complexes in transmetallation reactions, e.g., to prepare sulfur coordination polymers, and sulfur coordination polymers doped with tetrathiafulvalene-based dithiolene linkers having different oxidation states.

  描述了基于四硫富瓦烯二硫辛联结物的配位配合物，例如四硫富瓦烯-2,3,6,7-四硫酸盐（TTFtt）及其氧化产物。这些配位配合物可以包括金属，如锡或硅。还描述了利用这些配位配合物进行金属交换反应的方法，例如用于制备硫配位聚合物，以及掺杂有具有不同氧化态的基于四硫富瓦烯二硫辛联结物的硫配位聚合物。
• Isolation and characterisation of a new monodithiolate gold(III) complex
  作者：Masaki Takahashi、Neil Robertson、Robin J.H. Clark、Allan E. Underhill

  DOI：10.1016/s0277-5387(98)00437-9

  日期：1999.4

  A monodithiolate gold complex (1), potassium[dichloro(1,3,5-trithiepin-6,7-dithiolato)aurate] was isolated in a 1:1 reaction of 1,3,5-trithiepin-6,7-dithiolato (ttdt) and potassium tetrachloroaurate. 1 was characterised by its elemental analysis, IR and Raman spectra.

  在1,3,5-三噻吩-6,7-二硫代拉托醇的1：1反应中分离出单二硫醇盐金络合物（1）[二氯（1,3,5-trithiepin-6,7-二硫代拉托氨基）钾盐] （ttdt）和四氯金酸钾。图1通过其元素分析，IR和拉曼光谱表征。
• CURABLE FLUORINATED RESIN COMPOSITION
  申请人：Asahi Glass Company, Limited

  公开号：EP2532709A1

  公开（公告）日：2012-12-12

  To provide a fluorinated curable resin composition which is excellent in thermal stability and thermal adhesive property. A fluorinated curable resin composition comprising a fluoropolymer (P) having a polymerizable double bond and a thiol compound (S), wherein the fluoropolymer (P) is a copolymer having repeating units derived from a fluoromonoene (a) and a fluorodiene (b) having a residual unsaturated side chain, and the content of the thiol compound (S) is from 0.01 to 1 part by mass per 100 parts by mass of the fluoropolymer (P).

  提供一种热稳定性和热粘合性优异的含氟固化树脂组合物。 一种含氟可固化树脂组合物，由具有可聚合双键的含氟聚合物 (P) 和硫醇化合物 (S) 组成，其中含氟聚合物 (P) 是一种共聚物，其重复单元来自具有残余不饱和侧链的氟单烯 (a) 和氟二烯 (b)，硫醇化合物 (S) 的含量为每 100 份含氟聚合物 (P) 0.01 至 1 份。
• FLUORINATED CURABLE RESIN COMPOSITION
  申请人：SUGIYAMA Norihide

  公开号：US20120292661A1

  公开（公告）日：2012-11-22

  To provide a fluorinated curable resin composition which is excellent in thermal stability and thermal adhesive property. A fluorinated curable resin composition comprising a fluoropolymer (P) having a polymerizable double bond and a thiol compound (S), wherein the fluoropolymer (P) is a copolymer having repeating units derived from a fluoromonoene (a) and a fluorodiene (b) having a residual unsaturated side chain, and the content of the thiol compound (S) is from 0.01 to 1 part by mass per 100 parts by mass of the fluoropolymer (P).
• SULFUR-CONTAINING INORGANIC-ORGANIC HYBRID MATERIALS AND METHODS FOR MAKING THE SAME
  申请人：The University of Chicago

  公开号：US20220411445A1

  公开（公告）日：2022-12-29

  Coordination complexes of tetrathiafulvalene-based dithiolene linkers, such as tetrathiafulvalene-2,3,6,7-tetrathiolate (TTFtt), and their oxidation products are described. The coordination complexes can include metals such as tin or silicon. Also described are methods of using the coordination complexes in transmetallation reactions, e.g., to prepare sulfur coordination polymers, and sulfur coordination polymers doped with tetrathiafulvalene-based dithiolene linkers having different oxidation states.