2,2-dioctyl-1,3-dioxa-2-stannolane | 69657-84-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: 2,2-dioctyl-1,3-dioxa-2-stannolane
• 英文别名: 1,1-Dioctylstanna-2,5-dioxacyclopentane；2,2-dioctyl-1,3,2-dioxastannolane
• CAS: 69657-84-7
• 化学式: C₁₈H₃₈O₂Sn
• 分子量: 405.209
• InChiKey: CYSABLZFFBXPON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  21
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,2-dioctyl-1,3-dioxa-2-stannolane 、 borane tetrahydrofuran 以 环己烷 为溶剂， 以85%的产率得到dioctylstannane
  参考文献：
  名称：

  Une méthode simple et efficace de préparation des dihydrures organotanniques

  摘要：

  A new and efficient method of preparation of R(2)SnH(2) is proposed. Organodioxastannolanes were used as starting materials, these compounds being easily obtained by azeotropic distillation of water from a solution of diorganotin oxides and 1,2 diols in cyclohexane. Their reduction by commercial BH3/THF complex gave raw dialkyltin dihydrides with excellent yields and high purity degrees.

  DOI：

  10.1016/0022-328x(94)05356-g
• 作为产物：
  描述：

  氧化二辛基锡 、 乙二醇 在 甲苯 作用下， 以 甲苯 为溶剂， 反应 30.5h， 以to give 1,1-dioctylstanna-2,5-dioxacyclopentane, 2.19 g (97.6% yield)的产率得到2,2-dioctyl-1,3-dioxa-2-stannolane
  参考文献：
  名称：

  Process for producing &bgr;-butyrolactone homopolymer or copolymer

  摘要：

  本发明的目的是提供一种高分子量的β-丁内酯均聚物或共聚物的制备方法，该方法具有生物降解性，可被人体吸收，是一种有用的功能性聚合物材料，并且具有优异的物理特性，同时产率高且生产效率好。该目的通过以下制备本发明的均聚物或共聚物的方法来实现，该方法包括以下步骤：在酸去除和脱水处理之前，将单独的β-丁内酯或与其他内酯混合物进行环开聚合，其中所述的β-丁内酯与以下化合物的存在下进行，所述化合物由以下公式（1）和/或公式（2）表示：其中R1和R2以及R4至R7独立地表示含有1至12个碳原子的烷基，该烷基可能具有分支链，或者含有5至7个碳原子的环烷基，或者苯基或萘基，该苯基或萘基可能具有取代基，R3表示含有2至12个碳原子的烷基，该烷基可能具有取代基，环戊-1,2-亚基或环己-1,2-亚基，n为1至10的整数。

  公开号：

  US06545112B2

文献信息

• PROCESS FOR PRODUCING B-BUTYROLACTONE HOMOPOLYMER OR COPOLYMER
  申请人：——

  公开号：US20020052458A1

  公开（公告）日：2002-05-02

  The object of the invention is to provides a process in which a high-molecular-weight &bgr;-butyrolactone homopolymer or copolymer being biodegradable, absorbable into the living body, useful as a functional polymeric material and superior in physical characteristics is produced with high yield and good productivity. This object is solved by a process for producing the homopolymer or copolymer of the invention, which comprises ring-opening polymerization of sole &bgr;-butyrolactone subjected previously to acid removal and dehydration treatment, or of said &bgr;-butyrolactone with other lactones, in the presence of a tin compound represented by the following formula (1) and/or formula (2): 1 wherein R 1 and R 2 and R 4 to R 7 independently represent an alkyl group containing 1 to 12 carbon atoms which may have a branched chain, or a cycloalkyl group containing 5 to 7 carbon atoms, or a phenyl or naphthyl group which may have a substituent group, R 3 represents an alkylene group containing 2 to 12 carbon atoms which may have a substituent group, a cyclopentane-1,2-ylene group or a cyclohexane-1,2-ylene group, and n is an integer of 1 to 10.

  本发明的目的是提供一种高分子量的β-丁内酯均聚物或共聚物的制备方法，该聚物具有生物降解性，可吸收进入生物体内，可用作功能性聚合物材料，并且物理特性优良，且产量高且生产效率好。本发明的目的通过以下制备该发明的均聚物或共聚物的方法来解决：在预先去除酸和脱水处理的单一β-丁内酯或与其他内酯混合的β-丁内酯存在下，进行开环聚合反应，反应中存在以下式（1）和/或式（2）所表示的锡化合物：其中R1、R2和R4到R7独立地表示含1至12个碳原子的烷基，可以是支链的，或者含5至7个碳原子的环烷基，或者含有取代基的苯基或萘基，R3表示含有2至12个碳原子的烷基，可以是含有取代基的环戊-1,2-亚基或环己-1,2-亚基，n为1至10的整数。
• Une méthode simple et efficace de préparation des dihydrures organotanniques
  作者：H. Deleuze、B. Maillard

  DOI：10.1016/0022-328x(94)05356-g

  日期：1995.3

  A new and efficient method of preparation of R(2)SnH(2) is proposed. Organodioxastannolanes were used as starting materials, these compounds being easily obtained by azeotropic distillation of water from a solution of diorganotin oxides and 1,2 diols in cyclohexane. Their reduction by commercial BH3/THF complex gave raw dialkyltin dihydrides with excellent yields and high purity degrees.
• Process for producing &bgr;-butyrolactone homopolymer or copolymer
  申请人：Takasago International Corporation

  公开号：US06545112B2

  公开（公告）日：2003-04-08

  The object of the invention is to provides a process in which a high-molecular-weight &bgr;-butyrolactone homopolymer or copolymer being biodegradable, absorbable into the living body, useful as a functional polymeric material and superior in physical characteristics is produced with high yield and good productivity. This object is solved by a process for producing the homopolymer or copolymer of the invention, which comprises ring-opening polymerization of sole &bgr;-butyrolactone subjected previously to acid removal and dehydration treatment, or of said &bgr;-butyrolactone with other lactones, in the presence of a tin compound represented by the following formula (1) and/or formula (2): wherein R1 and R2 and R4 to R7 independently represent an alkyl group containing 1 to 12 carbon atoms which may have a branched chain, or a cycloalkyl group containing 5 to 7 carbon atoms, or a phenyl or naphthyl group which may have a substituent group, R3 represents an alkylene group containing 2 to 12 carbon atoms which may have a substituent group, a cyclopentane-1,2-ylene group or a cyclohexane-1,2-ylene group, and n is an integer of 1 to 10.

  本发明的目的是提供一种高分子量的β-丁内酯均聚物或共聚物的制备方法，该方法具有生物降解性，可被人体吸收，是一种有用的功能性聚合物材料，并且具有优异的物理特性，同时产率高且生产效率好。该目的通过以下制备本发明的均聚物或共聚物的方法来实现，该方法包括以下步骤：在酸去除和脱水处理之前，将单独的β-丁内酯或与其他内酯混合物进行环开聚合，其中所述的β-丁内酯与以下化合物的存在下进行，所述化合物由以下公式（1）和/或公式（2）表示：其中R1和R2以及R4至R7独立地表示含有1至12个碳原子的烷基，该烷基可能具有分支链，或者含有5至7个碳原子的环烷基，或者苯基或萘基，该苯基或萘基可能具有取代基，R3表示含有2至12个碳原子的烷基，该烷基可能具有取代基，环戊-1,2-亚基或环己-1,2-亚基，n为1至10的整数。