申请人:Mitsui Chemicals, Inc.
公开号:EP3270192A1
公开(公告)日:2018-01-17
In the present invention, there is provided a hydrophilic monolayer film that is excellent in antifogging properties, antifouling properties, the durability of antifogging properties and antifouling properties, and smoothness and that has an antireflective function or a surface structure that serves as a polarizer. There is also provided a method for easily producing such a monolayer film. The monolayer film that is to be produced has a surface structure with multiple protrusions and depressions. The distance between the peaks of adjoining protrusions among such multiple protrusions is in the range of 1 nm to 800 nm. The monolayer film is formed of a crosslinked resin produced by curing of a polymerizable composition that contains a compound having a specific hydrophilic group and a functional group with a polymerizable carbon-carbon double bond and a compound having two or more (meth)acryloyl groups. A gradient of the concentration of hydrophilic groups (Sa2/Da2) in the monolayer film is not less than 1.1 wherein Sa is the concentration of at least one type of hydrophilic groups selected from anionic hydrophilic groups, cationic hydrophilic groups, and a hydroxyl group at the top layer, and Da is the depth concentration of the hydrophilic groups at 1/2 of the thickness of the monolayer film.
本发明提供了一种亲水单层膜,它在防雾性能、防污性能、防雾性能和防污性能的耐久性以及平滑性方面都非常出色,并且具有防反射功能或可用作偏振器的表面结构。此外,还提供了一种易于生产这种单层薄膜的方法。要生产的单层薄膜具有多突起和凹陷的表面结构。在这些多个突起中,相邻突起的峰值之间的距离在 1 纳米到 800 纳米之间。单层膜由可聚合组合物固化产生的交联树脂形成,该组合物包含具有特定亲水基团和具有可聚合碳碳双键的官能团的化合物以及具有两个或两个以上(甲基)丙烯酰基的化合物。单层膜中亲水基团的浓度梯度(Sa2/Da2)不小于 1.1,其中 Sa 是选自阴离子亲水基团、阳离子亲水基团和羟基的至少一种亲水基团在顶层的浓度,Da 是亲水基团在单层膜厚度 1/2 处的深度浓度。