potassium;trifluoromethanesulfinate

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: potassium;trifluoromethanesulfinate
• 化学式: CF3KO2S
• 分子量: 172.17
• InChiKey: YJPOHGDCIPEPET-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.61
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  59.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1-bromo-3-phenylprop-2-yne 、 potassium;trifluoromethanesulfinate 生成 3-phenylprop-2-ynyl trifluoromethanesulfinate
  参考文献：
  名称：

  HANACK M.; MASSA F. W., TETRAHEDRON LETT., 1981, 22, NO 6, 557-558

  摘要：

  DOI：

文献信息

• Method for preparing isoprenoid cyclopropane 1,1-dicarboxylates and
  申请人：E. R. Squibb & Sons, Inc.

  公开号：US05144080A1

  公开（公告）日：1992-09-01

  A process is provided for preparing isoprenoid cyclopropane 1,1-dicarboxylates and derivatives thereof including the corresponding monocarboxylate, monocarboxylic acid and alcohol derivatives thereof, all of which are useful in preparing squalene synthetase inhibitors which inhibit cholesterol biosynthesis, and also useful in preparing pyrethrin insecticides.

  提供了一种制备异戊二烯基环丙烷-1,1-二羧酸酯及其衍生物的方法，包括相应的单羧酸酯、单羧酸和醇衍生物，所有这些化合物在制备角鲨烷合酶抑制剂方面有用，可抑制胆固醇生物合成，并且在制备拟除虫菊酯类杀虫剂方面也有用。
• Method for preparing isoprenoid cyclopropane 1,1-dicarboxylates
  申请人：E. R. Squibb & Sons, Inc.

  公开号：US05157146A1

  公开（公告）日：1992-10-20

  A process is provided for preparing isoprenoid cyclopropane 1,1-dicarboxylates which are useful in preparing squalene synthetase inhibitors which inhibit cholesterol biosynthesis, and also useful in preparing pyrethrin insecticides.

  提供了一种制备异戊二烯基环丙烷-1,1-二羧酸酯的过程，该过程可用于制备鱼肝油合成酶抑制剂，抑制胆固醇生物合成，并可用于制备拟除虫菊酯类杀虫剂。
• Pyrazle derivative, production process thereof, and pest control agent containing the same as ative ingredient
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20030060471A1

  公开（公告）日：2003-03-27

  The invention provides a novel pest control agent having a high systemic activity and a high safety with reduced adverse influences on the environment neighboring the place to which the agent is applied, and a process for producing the same. Namely, the present invention relates to a novel 1-aryl-3-cyano-5-heteroarylalkylaminopyrazole derivative represented by the following general formula (1) and a process for producing the same, and a pest control agent containing the same as an active ingredient. 1 (wherein X represents N or C-halogen, R 1 represents an alkyl group, an alkenyl group, an alkynyl group, or a haloalkyl group, R 2 represents hydrogen atom, an alkyl group, or an acyl group, R 3 represents hydrogen atom or an alkyl group, A represents any one of the groups represented by A-1 to A-4, R 4 represents hydrogen atom, an alkyl group, a halogen atom, and n represents 0, 1, or 2, provided that R 1 is a haloalkyl group except a perhaloalkyl group when A is A-1 and n is 0, and that n is not 0 when A is A-4.).

  本发明提供了一种新型杀虫剂，具有高度的系统活性和高度的安全性，对施用该剂剂量周围的环境影响减少，并提供了一种制备该杀虫剂的方法。具体而言，本发明涉及一种新型1-芳基-3-氰基-5-杂环烷基氨基吡唑衍生物，其通式如下（1），以及其制备方法和含有其作为活性成分的杀虫剂。其中，X代表N或C-卤素，R1代表烷基、烯基、炔基或卤代烷基，R2代表氢原子、烷基或酰基，R3代表氢原子或烷基，A代表A-1到A-4中的任意一种基团，R4代表氢原子、烷基、卤原子，n代表0、1或2，但当A为A-1且n为0时，R1为卤代烷基除外，当A为A-4时，n不为0。
• Process for the Sulfinylation of a Pyrazole Derivative
  申请人：Sukopp Martin

  公开号：US20100004307A1

  公开（公告）日：2010-01-07

  The present invention relates to a process for the sulfinylation of a pyrazole derivative, characterized in that 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazole-3-carbonitrile (II) is reacted with a sulfinylating agent S in the presence of at least one amine acid complex wherein the amine(s) are selected from secondary and/or tertiary amines and the acid(s) are selected from hydrofluoric, hydrochloric, hydrobromic and hydroiodic acid and sulfonic acid derivatives, and with the addition of a halogenating agent, wherein S is [CF 3 S(O)] 2 O; or CF 3 S(O)X wherein X means fluoro, chloro, bromo, iodo, a hydroxy group, or an alkaline or alkaline earth metal salt of the hydroxy group; or mixtures thereof, wherein the temperature of the reaction mixture at no time exceeds 39° C.

  本发明涉及一种吡唑衍生物的磺酰化过程，其特征在于在至少一个胺酸复合物的存在下，将5-氨基-1-[2,6-二氯-4-(三氟甲基)苯基]-1H-吡唑-3-羧腈(II)与磺酰化试剂S反应，其中胺(s)选择自二级和/或三级胺，酸(s)选择自氢氟酸、氢氯酸、氢溴酸、氢碘酸和磺酸衍生物，并加入卤代试剂，其中S为[CF3S(O)]2O；或CF3S(O)X，其中X表示氟、氯、溴、碘、羟基或羟基的碱金属或碱土金属盐；或其混合物，反应混合物的温度在任何时候均不超过39℃。
• Pyrazole derivative, production process thereof, and pest control agent containing the same as active ingredient
  申请人：Okui Shuko

  公开号：US06849633B2

  公开（公告）日：2005-02-01

  The invention provides a novel pest control agent having a high systemic activity and a high safety with reduced adverse influences on the environment neighboring the place to which the agent is applied, and a process for producing the same. Namely, the present invention relates to a novel 1-aryl-3-cyano-5-heteroarylalkylaminopyrazole derivative represented by the following general formula (1) and a process for producing the same, and a pest control agent containing the same as an active ingredient. (wherein X represents N or C-halogen, R 1 represents an alkyl group, an alkenyl group, an alkynyl group, or a haloalkyl group, R 2 represents hydrogen atom, an alkyl group, or an acyl group, R 3 represents hydrogen atom or an alkyl group, A represents any one of the groups represented by A-1 to A-4, R 4 represents hydrogen atom, an alkyl group, a halogen atom, and n represents 0, 1, or 2, provided that R 1 is a haloalkyl group except a perhaloalkyl group when A is A-1 and n is 0, and that n is not 0 when A is A-4.).

  本发明提供了一种新型的杀虫剂，具有高度的系统活性和高度的安全性，对施用剂量周围环境的不良影响降低，并提供了其生产方法。具体来说，本发明涉及一种新型的1-芳基-3-氰基-5-杂环烷基胺基吡唑衍生物，其通式如下（1），以及其生产方法和包含其作为活性成分的杀虫剂。（其中，X代表N或C-卤素，R1代表烷基、烯基、炔基或卤代烷基，R2代表氢原子、烷基或酰基，R3代表氢原子或烷基，A代表由A-1到A-4表示的任何一组，R4代表氢原子、烷基、卤素原子，n代表0、1或2，但当A为A-1且n为0时，R1为卤代烷基除外，当A为A-4时，n不为0。）